[1] V GEORGAKILAS, J N TIWARI, K C KEMP et al. Noncovalent functionalization of graphene and graphene oxide for energy materials, biosensing, catalytic, and ciomedical applications. Chemical Reviews, 116, 5464-5519(2016).

[2] W HABRAKEN, P HABIBOVIC, M EPPLE et al. Calcium phosphates in biomedical applications: materials for the future?. Materials Today, 19, 69-87(2016).

[3] K L LIN, C T WU, J CHANG. Advances in synthesis of calcium phosphate crystals with controlled size and shape. Acta Biomaterialia, 10, 4071-4102(2014).

[4] X L WANG, Z M REN, J CHANG. Synthesis and orientation of Fe-doped hydroxyapatite in high magnetic field. Journal of Inorganic Materials, 33, 75-80(2018).

[5] B ZHANG, C A YANG, P SHI. Synthesis of graphene/ hydroxyapatite composite bioceramics via plasma Activated sintering,. Journal of Inorganic Materials, 33, 1355-1359(2018).

[6] C T WU, J CHANG. Silicate bioceramics for bone tissue regeneration. Journal of Inorganic Materials, 28, 29-39(2013).

[7] S DONG, Y CHEN, L YU et al. Magnetic hyperthermia- synergistic H₂O₂ self-sufficient catalytic suppression of osteosarcoma with enhanced bone-regeneration bioactivity by 3D-printing composite scaffolds. Advanced Functional Materials, 30, 1907071-1-15(2019).

[8] Z Y SHI, Q LI, S C TANG et al. Surface modification on property of mesoporous calcium magnesium silicate/polyetheretherketone composites. Journal of Inorganic Materials, 33, 67-74(2018).

[9] F BAI, Z WANG, J LU et al. The correlation between the internal structure and vascularization of controllable porous bioceramic aterials in vivo: a quantitative study. Tissue Engineering Part A, 16, 3791-3803(2010).

[10] K L LIN, J CHANG, Y ZENG et al. Preparation of macroporous calcium silicate ceramics. Materials Letters, 58, 2109-2113(2004).

[11] F BAINO, E FIUME, J BARBERI et al. Processing methods for making porous bioactive glass-based scaffolds-a state-of-the-art review. International Journal of Applied Ceramic Technology, 16, 1762-1796(2019).

[12] C XIN, X QI, M ZHU et al. Hydroxyapatite whisker-reinforced composite scaffolds through 3D printing for bone repair. Journal of Inorganic Materials, 32, 837-844(2017).

[13] H MA, C FENG, J CHANG et al. 3D-printed bioceramic scaffolds: from bone tissue engineering to tumor therapy. Acta Biomaterialia, 79, 37-59(2018).

[14] ERLACH T C VON, S BERTAZZO, M A WOZNIAK et al. Cell-geometry-dependent changes in plasma membrane order direct stem cell signalling and fate. Nature Materials, 17, 237-242(2018).

[15] J ROGOWSKA-TYLMAN, J LOCS, I SALMA et al. In vivo and in vitro study of a novel nanohydroxyapatite sonocoated scaffolds for enhanced bone regeneration. Materials Science & Engineering: C, 99, 669-684(2019).

[16] B W YANG, J H YIN, Y CHEN et al. 2D-black-phosphorus- reinforced 3D-printed scaffolds: a stepwise countermeasure for osteosarcoma. Advanced Materials, 30, 1705611-1-12(2018).

[17] Y L ZHANG, D ZHAI, M C XU et al. 3D-printed bioceramic scaffolds with antibacterial and osteogenic activity. Biofabrication, 9, 025037-1-12(2017).

[18] X ZHANG, H LI, J LIU et al. Amorphous carbon modification on implant surface: a general strategy to enhance osteogenic differentiation for diverse biomaterials via FAK/ERK1/2 signaling pathways. Journal of Materials Chemistry B, 7, 2518-2533(2019).

[19] M TOURI, F MOZTARZADEH, N A A OSMAN et al. 3D- printed biphasic calcium phosphate scaffolds coated with an oxygen generating system for enhancing engineered tissue survival. Materials Science and Engineering: C, 84, 236-242(2018).

[20] C WANG, K LIN, J CHANG et al. Osteogenesis and angiogenesis induced by porous beta-CaSiO₃/PDLGA composite scaffold via activation of AMPK/ERK1/2 and PI3K/Akt pathways. Biomaterials, 34, 64-77(2013).

[21] K LIN, L XIA, J GAN et al. Tailoring the nanostructured surfaces of hydroxyapatite bioceramics to promote protein adsorption, osteoblast growth, and osteogenic differentiation. ACS Applied Materials & Interfaces, 5, 8008-8017(2013).

[22] C ZHAO, L XIA, D ZHAI et al. Designing ordered micropatterned hydroxyapatite bioceramics to promote the growth and osteogenic differentiation of bone marrow stromal cells. Journal of Materials Chemistry B, 3, 968-976(2015).

[23] L MAO, J LIU, J ZHAO et al. Effect of micro-nano-hybrid structured hydroxyapatite bioceramics on osteogenic and cementogenic differentiation of human periodontal ligament stem cell via Wnt signaling pathway. International Journal of Nanomedicine, 10, 7031-7044(2015).

[24] L XIA, K LIN, X JIANG et al. Effect of nano-structured bioceramic surface on osteogenic differentiation of adipose derived stem cells. Biomaterials, 35, 8514-8527(2014).

[25] X WANG, Y ZHOU, L XIA et al. Fabrication of nano-structured calcium silicate coatings with enhanced stability, bioactivity and osteogenic and angiogenic activity. Colloids and Surfaces B-Biointerfaces, 126, 358-366(2015).

[26] L XIA, Y XIE, B FANG et al. In situ modulation of crystallinity and nano-structures to enhance the stability and osseointegration of hydroxyapatite coatings on Ti-6Al-4V implants. Chemical Engineering Journal, 347, 711-720(2018).

[27] L XIA, N ZHANG, X WANG et al. The synergetic effect of nano-structures and silicon-substitution on the properties of hydroxyapatite scaffolds for bone regeneration. Journal of Materials Chemistry B, 4, 3313-3323(2016).

[28] C J DENG, R C LIN, M ZHANG et al. Micro/nanometer- structured scaffolds for regeneration of both cartilage and subchondral bone. Advanced Functional Materials, 29, 1806068-15(2019).

[29] C YANG, X Y WANG, B MA et al. 3D-printed bioactive Ca₃SiO₅ bone cement scaffolds with nano surface structure for bone regeneration. ACS Applied Materials & Interfaces, 9, 5757-5767(2017).

[30] X C WANG, T LI, H S MA et al. A 3D-printed scaffold with MoS₂ nanosheets for tumor therapy and tissue regeneration. NPG Asia Materials, 9, e376-1-14(2017).

[31] L XIA, K LIN, X JIANG et al. Enhanced osteogenesis through nano-structured surface design of macroporous hydroxyapatite bioceramic scaffolds via activation of ERK and p38 MAPK signaling pathways. Journal of Materials Chemistry B, 1, 5403-5416(2013).

[32] S DONG, Y-N ZHANG, J WANG et al. A novel multifunctional carbon aerogel coated platform for osteosarcoma therapy and enhanced bone regeneration. Journal of Materials Chemistry B, 8, 368-379(2020).

[33] C WANG, K LIN, J CHANG et al. The stimulation of osteogenic differentiation of mesenchymal stem cells and vascular endothelial growth factor secretion of endothelial cells by beta-CaSiO₃/beta- Ca₃(PO₄)(2) scaffolds. Journal of Biomedical Materials Research Part A, 102, 2096-2104(2014).

[34] F WITTE, V KAESE, H HAFERKAMP et al. In vivo corrosion of four magnesium alloys and the associated bone response. Biomaterials, 26, 3557-3563(2005).

[35] S YOSHIZAWA, A BROWN, A BARCHOWSKY et al. Magnesium ion stimulation of bone marrow stromal cells enhances osteogenic activity, simulating the effect of magnesium alloy degradation. Acta Biomaterialia, 10, 2834-2842(2014).

[36] L XIA, Z YIN, L MAO et al. Akermanite bioceramics promote osteogenesis,angiogenesis and suppress osteoclastogenesis for osteoporotic bone regeneration. Scientific Reports, 6, 22005- 1-17(2016).

[37] N AMIN, C C T CLARK, M TAGHIZADEH et al. Zinc supplements and bone health: the role of the RANKL-RANK axis as a therapeutic target. Journal of Trace Elements in Medicine and Biology(2019). https://www.ncbi.nlm.nih.gov/pubmed/32634767

[38] Y Q QIAO, W J ZHANG, P TIAN et al. Stimulation of bone growth following zinc incorporation into biomaterials. Biomaterials, 35, 6882-6897(2014).

[39] K L LIN, L G XIA, H Y LI et al. Enhanced osteoporotic bone regeneration by strontium-substituted calcium silicate bioactive ceramics. Biomaterials, 34, 10028-10042(2013).

[40] W LIU, T WANG, C YANG et al. Alkaline biodegradable implants for osteoporotic bone defects-importance of microenvironment pH. Osteoporosis International, 27, 93-104(2016).

[41] X GUO, S WEI, M LU et al. Dose-dependent effects of strontium ranelate on ovariectomy rat bone marrow mesenchymal stem cells and human umbilical vein endothelial cells. International Journal of Biological Sciences, 12, 1511-1522(2016).

[42] X GUO, S WEI, M LU et al. RNA-Seq investigation and in vivo study the effect of strontium ranelate on ovariectomized rat via the involvement of ROCK1. Artificial Cells Nanomedicine and Biotechnology, 46, S629-S641(2018).

[43] K LIN, X WANG, N ZHANG et al. Strontium (Sr) strengthens the silicon (Si) upon osteoblast proliferation, osteogenic differentiation and angiogenic factor expression. Journal of Materials Chemistry B, 4, 3632-3638(2016).

[44] C Y WANG, B CHEN, W WANG et al. Strontium released bi-lineage scaffolds with immunomodulatory properties induce a pro-regenerative environment for osteochondral regeneration. Materials Science & Engineering: C, 103, 109833-1-12(2019).

[45] X ZHANG, H LI, C LIN et al. Synergetic topography and chemistry cues guiding osteogenic differentiation in bone marrow stromal cells through ERK1/2 and p38 MAPK signaling pathway. Biomaterials Science, 6, 418-430(2018).

[46] G FIELDING, S BOSE. SiO₂ and ZnO dopants in three- dimensionally printed tricalcium phosphate bone tissue engineering scaffolds enhance osteogenesis and angiogenesis in vivo. Acta Biomaterialia, 9, 9137-9148(2013).

[47] C WU, D ZHAI, H MA et al. Stimulation of osteogenic and angiogenic ability of cells on polymers by pulsed laser deposition of uniform akermanite-glass nanolayer. Acta Biomaterialia, 10, 3295-3306(2014).

[48] N KONG, K LIN, H LI et al. Synergy effects of copper and silicon ions on stimulation of vascularization by copper-doped calcium silicate. Journal of Materials Chemistry B, 2, 1100-1110(2014).

[49] M C SHI, Z T CHEN, S FARNAGHI et al. Copper-doped mesoporous silica nanospheres, a promising immunomodulatory agent for inducing osteogenesis. Acta Biomaterialia, 30, 334-344(2016).

[50] J Y LI, D ZHAI, F LV et al. Preparation of copper-containing bioactive glass/eggshell membrane nanocomposites for improving angiogenesis, antibacterial activity and wound healing. Acta Biomaterialia, 36, 254-266(2016).

[51] H LI, J Y LI, J JIANG et al. An osteogenesis/angiogenesis- stimulation artificial ligament for anterior cruciate ligament reconstruction. Acta Biomaterialia, 54, 399-410(2017).

[52] Y H ZHOU, S W HAN, L XIAO et al. Accelerated host angiogenesis and immune responses by ion release from mesoporous bioactive glass. Journal of Materials Chemistry B, 6, 3274-3284(2018).

[53] R C LIN, C J DENG, X X LI et al. Copper-incorporated bioactive glass-ceramics inducing anti-inflammatory phenotype and regeneration of cartilage/bone interface. Theranostics, 9, 6300-6313(2019).

[54] W T DANG, X Y WANG, J Y LI et al. 3D printing of Mo- containing scaffolds with activated anabolic responses and bi-lineage bioactivities. Theranostics, 8, 4372-4392(2018).

[55] Y Q LIU, T LI, H S MA et al. 3D-printed scaffolds with bioactive elements-induced photothermal effect for bone tumor therapy. Acta Biomaterialia, 73, 531-546(2018).

[56] S MEININGER, S MANDAL, A KUMAR et al. Strength reliability and in vitro degradation of three-dimensional powder printed strontium-substituted magnesium phosphate scaffolds. Acta Biomaterialia, 31, 401-411(2016).

[57] S MEININGER, C MOSEKE, K SPATZ et al. Effect of strontium substitution on the material properties and osteogenic potential of 3D powder printed magnesium phosphate scaffolds. Materials Science and Engineering: C, 98, 1145-1158(2019).

[58] J XIE, H SHAO, D HE et al. Ultrahigh strength of three- dimensional printed diluted magnesium doping wollastonite porous scaffolds. MRS Communications, 5, 631-639(2015).

[59] X KE, L ZHANG, X YANG et al. Low-melt bioactive glass- reinforced 3D printing akermanite porous cages with highly improved mechanical properties for lumbar spinal fusion. J Tissue Eng. Regen. Med., 12, 1149-1162(2018).

[60] S Y FU, B YU, H F DING et al. Zirconia incorporation in 3D printed beta-Ca₂SiO₄ scaffolds on their physicochemical and biological property. Journal of Inorganic Materials, 34, 444-454(2019).

[61] F ZHANG, J CHANG, J LU et al. Bioinspired structure of bioceramics for bone regeneration in load-bearing sites. Acta Biomaterialia, 3, 896-904(2007).

[62] C FENG, W ZHANG, C DENG et al. 3D Printing of lotus root-like biomimetic materials for cell delivery and tissue regeneration. Advanced Science, 4, 1700401-1-9(2017).

[63] T ALMELA, I M BROOK, K KHOSHROO et al. Simulation of cortico-cancellous bone structure by 3D printing of bilayer calcium phosphate-based scaffolds. Bioprinting, 6, 1-7(2017).

[64] L JUNG-BIN, M WOO-YOUL, K YOUNG-HAG et al. Porous calcium phosphate ceramic scaffolds with tailored pore orientations and mechanical properties using lithography-based ceramic 3D printing technique. Materials, 11, 1711-1718.

[65] G S MATHARU, J DANIEL, H ZIAEE et al. Failure of a novel ceramic-on-ceramic hip resurfacing prosthesis. Journal of Arthroplasty, 30, 416-418(2015).

[66] P MANNY, P JAVAD, P F SHARKEY et al. Causes of failure of ceramic-on-ceramic and metal-on-metal hip arthroplasties. Clinical Orthopaedics & Related Research, 470, 382-387(2012).

[67] L ZHAO, C T WU, K L LIN et al. The effect of poly(lactic-co- glycolic acid)(PLGA) coating on the mechanical, biodegradable, bioactive properties and drug release of porous calcium silicate scaffolds. Bio-medical Materials and Engineering, 22, 289-300(2012).

[68] CHEN LI, FANRONG AI, XINXIN MIAO et al. “The return of ceramic implants”: rose stem inspired dual layered modification of ceramic scaffolds with improved mechanical and anti-infective properties. Materials Science and Engineering: C, 93, 873-879(2018).

[69] B S KIM, S S YANG, H PARK et al. Improvement of mechanical strength and osteogenic potential of calcium sulfate-based hydroxyapatite 3-dimensional printed scaffolds by epsilon- polycarbonate coating. Journal of. Biomaterials Science-Polymer Edition, 28, 1256-1270(2017).

[70] P DíAZ-RODRíGUEZ, P GONZáLEZ, J SERRA et al. Key parameters in blood-surface interactions of 3D bioinspired ceramic materials. Materials Science and Engineering: C, 41, 232-239(2014).

[71] P S LIENEMANN, M P LUTOLF, E MARTIN. Biomimetic hydrogels for controlled biomolecule delivery to augment bone regeneration. Advanced Drug Delivery Reviews, 64, 1078-1089(2012).

[72] M LI, Y CHENG, Y F ZHENG et al. Surface characteristics and corrosion behaviour of WE43 magnesium alloy coated by SiC film. Applied Surface Science., 258, 3074-3081(2012).

[73] Y YANG, Y LAI, Q ZHANG et al. A novel electrochemical strategy for improving blood compatibility of titanium-based biomaterials. Colloids & Surfaces B Biointerfaces, 79, 309-313(2010).

[74] L ZHAO, K L LIN, M L ZHANG et al. The influences of poly(lactic-co-glycolic acid) (PLGA) coating on the biodegradability, bioactivity, and biocompatibility of calcium silicate bioceramics. Journal of Materials Science, 46, 4986-4993(2011).

[75] T WEI, X DANG-SHENG. Bioinspired superhydrophobic progress and recent advances of its functional application. Journal of Inorganic Materials, 34, 1133-1144(2019).

[76] Y ARIMA, H IWATA. Effect of wettability and surface functional groups on protein adsorption and cell adhesion using well-defined mixed self-assembled monolayers. Biomaterials, 28, 3074-3082(2007).

[77] Y Q TENG, Y Q ZHANG, L P HENG et al. Conductive polymer porous film with tunable wettability and adhesion. Materials, 8, 1817-1830(2015).

[78] Z CHEN, D ZHANG, E PENG et al. 3D-printed ceramic structures with in situ grown whiskers for effective oil/water separation. Chemical Engineering Journal, 373, 1223-1232(2019).

[79] Y SONG, K LIN, S HE et al. Nano-biphasic calcium phosphate/polyvinyl alcohol composites with enhanced bioactivity for bone repair via low-temperature three-dimensional printing and loading with platelet-rich fibrin. International Journal of Nanomedicine, 13, 505-523(2018).

[80] R TROMBETTA, J A INZANA, E M SCHWARZ et al. 3D printing of calcium phosphate ceramics for bone tissue engineering and drug delivery. Annals of Biomedical Engineering, 45, 1-22(2017).

[81] S BOSE, S VAHABZADEH, A BANDYOPADHYAY. Bone tissue engineering using 3D printing. Materials Today, 16, 496-504(2013).

[82] Y L ZHANG, D ZHAI, M C XU et al. 3D-printed bioceramic scaffolds with a Fe₃O₄/graphene oxide nanocomposite interface for hyperthermia therapy of bone tumor cells. Journal of Materials Chemistry B, 4, 2874-2886(2016).

[83] P M C TORRES, S I VIEIRA, A R CERQUEIRA et al. Effects of Mn-doping on the structure and biological properties of β-tricalcium phosphate. Journal of Inorganic Biochemistry, 136, 57-66(2014).

[84] Z MIN, Z SHICHANG, X CHEN et al. 3D-printed dimethyloxallyl glycine delivery scaffolds to improve angiogenesis and osteogenesis. Biomater. Sci., 3, 1236-1244(2015).

[85] P DIAZ-RODRIGUEZ, M SANCHEZ, M LANDIN. Drug-loaded biomimetic ceramics for tissue engineering. Pharmaceutics, 10, 272-1-20(2018).

[86] R MEIßNER, L BERTOL, M A U REHMAN et al. Bioprinted 3D calcium phosphate scaffolds with gentamicin releasing capability. Ceramics International, 45, 7090-7094(2019).

[87] T LI, D ZHAI, B MA et al. 3D printing of hot dog-like biomaterials with hierarchical architecture and distinct bioactivity. Advanced Science, 6, 1901146-8(2019).

[88] J-J SONG, B CHEN, K-L LIN. Core-shell structured hydroxyapatite/mesoporous silica nanoparticle: preparation and application in drug delivery. Journal of Inorganic Materials, 33, 623-628(2018).

[89] G CHEN, I ROY, C YANG et al. Nanochemistry and nanomedicine for nanoparticle-based diagnostics and therapy. Chemical Reviews, 116, 2826-2885(2016).

[90] F ZHEN, C YAN, C CUI et al. Near infrared fluorescent peptide nanoparticles for enhancing esophageal cancer therapeutic efficacy. Nature Communications, 9, 2605-1-11(2018).

[91] S WANG, Y CHEN, X LI et al. Injectable 2D MoS₂-integrated drug delivering implant for highly efficient NIR-triggered synergistic tumor hyperthermia. Advanced Materials, 27, 7117-7122(2015).

[92] D R CHANDRAWATI, D J Y H CHANG, D E REINATORRES et al. Localized and controlled delivery of nitric oxide to the conventional outflow pathway via enzyme biocatalysis: toward therapy for glaucoma. Advanced Materials, 29, 1604932-1-7(2017).

[93] B BADGWELL, M BLUM, J ESTRELLA et al. Personalised therapy for localised gastric and gastro-oesophageal adenocarcinoma. Lancet Oncology, 17, 1628-1629(2016).

[94] B W YANG, Z GU, Y CHEN. Nanomedicine-augmented cancer-localized treatment by 3D theranostic implants. Journal of Biomedical Nanotechnology, 13, 871-890(2017).

[95] H MA, C JIANG, D ZHAI et al. A bifunctional biomaterial with photothermal effect for tumor therapy and bone regeneration. Advanced Functional Materials, 26, 1197-1208(2016).

[96] P WU, D W GRAINGER. Drug/device combinations for local drug therapies and infection prophylaxis. Biomaterials, 27, 2450-2467(2006).

[97] KUMAR C ARIJIT, C RUCHIRA, B TARAKDAS. Mechanism of antibacterial activity of copper nanoparticles. Nanotechnology, 25, 135101-1-13(2014).

[98] A M SCHRAND, M F RAHMAN, S M HUSSAIN et al. Metal-based nanoparticles and their toxicity assessment. Wiley Interdisciplinary Reviews: Nanomedicine and Nanobiotechnology, 2, 544-568(2010).

[99] F LIAO, J Q MA, H G GE. Preparation, characterization and antimicrobial activity of core-satellite Ag/PDA@SiO₂@CoFe₂O₄ magnetic composites. Journal of Inorganic Materials, 32, 523-528(2017).

[100] Y L LIU, R L WANG, N LI et al. Preparation of zinc oxide mesocrystal filler and the properties of dental composite resins. Journal of Inorganic Materials, 34, 1077-1084(2019).

[101] Q WANG, P F TANG, X GE et al. Experimental and simulation studies of strontium/zinc-codoped hydroxyapatite porous scaffolds with excellent osteoinductivity and antibacterial activity. Applied Surface Science, 462, 118-126(2018).

[102] S P VALAPPIL, M COOMBES, L WRIGHT et al. Role of gallium and silver from phosphate-based glasses on in vitro dual species oral biofilm models of porphyromonas gingivalis and Streptococcus gordonii. Acta Biomaterialia, 8, 1957-1965(2012).

[103] Y F GOH, A Z ALSHEMARY, M AKRAM et al. In-vitro characterization of antibacterial bioactive glass containing ceria. Ceramics International, 40, 729-737(2014).

[104] X CHATZISTAVROU, J C FENNO, D FAULK et al. Fabrication and characterization of bioactive and antibacterial composites for dental applications. Acta Biomaterialia, 10, 3723-3732(2014).

[105] D S BRAUER, N KARPUKHINA, G KEDIA et al. Bactericidal strontium-releasing injectable bone cements based on bioactive glasses. Journal of the Royal Society Interface, 10, 20120647-1-8(2013).

[106] Y WU, L XIA, Y ZHOU et al. Evaluation of osteogenesis and angiogenesis of icariin loaded on micro/nano hybrid structured hydroxyapatite granules as a local drug delivery system for femoral defect repair. Journal of Materials Chemistry B, 3, 4871-4883(2015).

[107] Y ZHOU, Y WU, W MA et al. The effect of quercetin delivery system on osteogenesis and angiogenesis under osteoporotic conditions. Journal of Materials Chemistry B, 5, 612-625(2017).

[108] F M ZHANG, J CHANG, K L LIN et al. Preparation, mechanical properties and in vitro degradability of wollastonite/tricalcium phosphate macroporous scaffolds from nanocomposite powders. Journal of Materials Science-Materials in. Medicine, 19, 167-173(2008).

[109] F ZHANG, K LIN, J CHANG et al. Spark plasma sintering of macroporous calcium phosphate scaffolds from nanocrystalline powders. Journal of The European Ceramic Society, 28, 539-545(2008).