Haoming DING1、2、3, Mian LI1、3, Youbing LI1、3, Ke CHEN1、3, Yukun XIAO1、3, Jie ZHOU4, Quanzheng TAO4, Rosen Johanna4, Hang YIN5, Yuelei BAI5, Bikun ZHANG6, Zhimei SUN6, Junjie WANG7, Yiming ZHANG1、3, Zhenying HUANG8, Peigen ZHANG9, Zhengming SUN9, Meikang HAN10, Shuang ZHAO11, Chenxu WANG11, and Qing HUANG1、3、*
Author Affiliations
11. Ningbo Institute of Materials Technology and Engineering, Chinese Academy of Sciences, Ningbo 315201, China22. University of Chinese Academy of Sciences, Beijing 101408, China33. Qianwan Institute of CHiTECH, Ningbo 315336, China44. Department of Physics, Chemistry and Biology (IFM), Linköping University, Linköping SE-58183, Sweden55. National Key Laboratory of Science and Technology on Advanced Composites in Special Environments and Center for Composite Materials and Structures, Harbin Institute of Technology, Harbin 150001, China66. School of Materials Science and Engineering, Beihang University, Beijing 100191, China77. School of Materials Science and Engineering, Northwestern Polytechnic University, Xi’an 710072, China88. School of Mechanical, Electronic and Control Engineering, Beijing Jiaotong University, Beijing 100044, China99. School of Materials Science and Engineering, Southeast University, Nanjing 211189, China1010. Institute of Optoelectronics and Shanghai Frontiers Science Research Base of Intelligent Optoelectronics and Perception, Fudan University, Shanghai 200433, China1111. State Key Laboratory of Nuclear Physics and Technology, Peking University, Beijing 100871, Chinashow less
DOI: 10.15541/jim20230123
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Haoming DING, Mian LI, Youbing LI, Ke CHEN, Yukun XIAO, Jie ZHOU, Quanzheng TAO, Rosen Johanna, Hang YIN, Yuelei BAI, Bikun ZHANG, Zhimei SUN, Junjie WANG, Yiming ZHANG, Zhenying HUANG, Peigen ZHANG, Zhengming SUN, Meikang HAN, Shuang ZHAO, Chenxu WANG, Qing HUANG. Progress in Structural Tailoring and Properties of Ternary Layered Ceramics[J]. Journal of Inorganic Materials, 2023, 38(8): 845
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1. Non-exhaustive chronicle of ternary layered materials
2. Atomic and structural regulation of MAX phases
3. Different methods for the synthesis of MXene
4. Structural editing of MAX phases and MXene aided by chemical scissors
5. Crystal structure and physical properties of novel chalcogenide MAX phases
6. Preparation of single crystal MAX phases
7. Heat capacity and anisotropic thermal conductivity in Cr
2AlC single crystals at high temperatures
[110] 8.
i-MAX phases and its derived two
-dimensional product of
i-MXene
[50] 9. MAB phases, i-MAB phases and o-MAB phases
10. Two-dimensional products derived from MAB phases through chemical etching
11. Experimentally measured unilateral notched beam fracture toughness as a function of the weakest to strongest chemical bond stiffness ratio
kmin/
kmax for some typical ternary layered compounds (MAX and MAB phases)
[138] 12. Theoretical calculation of MAB phases
13. Members and atomic structures of all reported orth- and hex-MBenes
[163] 14. Discovery of ternary MAX phases
15. Theoretical study of quaternary MAB phases
16. Structure mapping based on the selected characteristic quantities of electron concentration and atomic sizes
[36] 17. MAX-reinforced metal matrix composites
18. SEM images of a Sn whisker alternately cultivated in air and vacuum
[259] 19. SEM images of fractured Zr
2InC surface and an In whisker
[243] 20. Microstructure of Sn whiskers/Ti
2SnC interface
[266] 21. (a) Electrical conductivity of different MXene films and (b) conductivity-dependent electromagnetic interference shielding effectiveness of different MXenes
[282] 22. Defect generation and microstructural transformation in MAX phase materials under irradiation
23. MAX phase irradiation temperature effect
24. Phase transformation and amorphization caused by irradiation of MAX phases
[302] 25. STEM micrographs of (Mo
2/3RE
1/3)
2GaC
i-MAX phase along (a) [100] and (b) [010] zone axis
[120] | M′4/3 | M″2/3 | A | X | Ref. |
|---|
| Mo4/3 | Sc2/3/Y2/3 | Al | C | [50,118] | | W4/3 | Sc2/3/Y2/3 | Al | C | [123] | | Mn4/3 | Sc2/3 | Ga | C | [124] | | Cr4/3 | Sc2/3/Y2/3/Zr2/3 | Al | C | [125-126] | | Cr4/3 | Sc2/3 | Ga | C | [16,124] | | V4/3 | Sc2/3/Zr2/3 | Al | C | [118,127] | | Mo4/3 | Sc2/3/Y2/3 | Ga | C | [128] | | Mo4/3 | Ce2/3/Pr2/3/Nd2/3/Sm2/3/Gd2/3/Tb2/3/Dy2/3/Ho2/3/Er2/3/Tm2/3/Lu2/3 | Al | C | [119] | | Mo4/3 | Gd2/3/Tb2/3/Dy2/3/Ho2/3/Er2/3/Tm2/3/Yb2/3/Lu2/3 | Ga | C | [120] | | W4/3 | Gd2/3/Tb2/3/Dy2/3/Ho2/3/Er2/3/Tm2/3/Lu2/3 | Al | C | [121] | | Cr4/3 | Gd2/3/Tb2/3/Dy2/3/Ho2/3/Er2/3/Tm2/3/Lu2/3 | Al | C | [122] |
|
Table 1. List of synthesized i-MAX phases
| MAB phase | M type | A type | Ref. | MAB phase | M type | A type | Ref. |
|---|
| Orthorhombic M2A2B2 | Ti | Al | [160-161] | Orthorhombic M3AB4 | Sc | Al | [160-161] | | Hf | Ti | | V | Zr | | Nb | Hf | | Ta | V | | Tc | Nb | | Cr | Ta | | Mn | Mo | | Orthorhombic M2AB2 | Sc | Al | [160-161] | W | | Ti | Mn | | Zr | Fe | | Hf | Orthorhombic M4AB6 | Sc | Al | [160-161] | | V | Ti | | Nb | Zr | | W | Hf | | Tc | V | | Rh | Nb | | Ni | Ta | | Co | Mo | | Orthorhombic M3A2B2 | Sc | Al | [160-161] | Hexagonal M2AB2 | Ti | Sn | [52] | | Ti | Hf | In | [162] | | Zr | Sn | | Hf | Zr | In | | Cr | Pb | | Mn | Tl | | Tc | Hexagonal M3AB4 | Hf | In | [162] | | Fe | Sn | | Ni | P | | | | | Zr | Cd | | | | | Pb |
|
Table 2. Stable MAB phases by theoretical prediction
| MAB phase | B/GPa
| G/GPa
| E/GPa
| ¯ν/GPa
| Ref. |
|---|
| Mn2AlB2 | 239 | 169 | 411 | 0.21 | [160] | | Fe2AlB2 | 209 | 133 | 329 | 0.24 | | Co2AlB2 | 216 | 92 | 242 | 0.31 | | TiAlB | 145 | 116 | 274 | 0.18 | | VAlB | 173 | 133 | 317 | 0.19 | | NbAlB | 180 | 130 | 315 | 0.21 | | TaAlB | 192 | 138 | 333 | 0.21 | | CrAlB | 189 | 140 | 338 | 0.20 | | MnAlB | 167 | 101 | 252 | 0.25 | | TcAlB | 220 | 114 | 292 | 0.28 | | Sc2AlB2 | 238 | 142 | 356 | 0.25 | | Ti2AlB2 | 170 | 150 | 347 | 0.16 | | Zr2AlB2 | 152 | 112 | 270 | 0.20 | | Hf2AlB2 | 168 | 132 | 314 | 0.19 | | V2AlB2 | 195 | 129 | 317 | 0.23 | | Nb2AlB2 | 199 | 110 | 279 | 0.27 | | Cr2AlB2 | 229 | 177 | 422 | 0.19 | | Mo2AlB2 | 238 | 142 | 356 | 0.25 | | W2AlB2 | 262 | 139 | 354 | 0.28 | | Tc2AlB2 | 260 | 132 | 339 | 0.28 | | Ni2AlB2 | 200 | 91 | 237 | 0.30 | | MoAlB | 213 | 146 | 357 | 0.22 | [164] | | WAlB | 232 | 146 | 362 | 0.24 | | Mn2AlB2 | 222 | 161 | 388 | 0.21 | [165] | | Fe2AlB2 | 210 | 132 | 329 | 0.24 | [165] | | Co2AlB2 | 241 | 101 | 266 | 0.31 | [166] | | Zr3CdB4 | — | 82 | 202 | 0.37 | [167] | | Hf3PB4 | — | 180 | 407 | 0.19 | [168] |
|
Table 3. Theoretical mechanical properties of several MAB-phases, including bulk modulus (B), shear modulus (G), Young’s modulus (E), and Poisson ratio (ν)
