• Laser & Optoelectronics Progress
  • Vol. 56, Issue 14, 143001 (2019)
Zijun Wu, Jingqi Lu*, Jian Huang, and Dewei Cheng
Author Affiliations
  • School of Science, Wuhan University of Technology, Wuhan, Hubei 430070, China
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    DOI: 10.3788/LOP56.143001 Cite this Article Set citation alerts
    Zijun Wu, Jingqi Lu, Jian Huang, Dewei Cheng. Pb Detection in Paint Coatings Through Combined Laser-Induced Breakdown Spectroscopy and CARS Variable Screening[J]. Laser & Optoelectronics Progress, 2019, 56(14): 143001 Copy Citation Text show less
    Diagram of LIBS experimental setup
    Fig. 1. Diagram of LIBS experimental setup
    Characteristic spectra of lead in paint coatings at 308-417 nm
    Fig. 2. Characteristic spectra of lead in paint coatings at 308-417 nm
    Calibration curve of 405.78 nm analytical line of Pb I
    Fig. 3. Calibration curve of 405.78 nm analytical line of Pb I
    Prediction results of multiple linear regression model for correction set
    Fig. 4. Prediction results of multiple linear regression model for correction set
    Screening results of wavelength variables by CARS algorithm. (a) Trend of variable number of wavelength; (b) trend of RMSECV; (c) trend of regression coefficients of various wavelength variables
    Fig. 5. Screening results of wavelength variables by CARS algorithm. (a) Trend of variable number of wavelength; (b) trend of RMSECV; (c) trend of regression coefficients of various wavelength variables
    Distribution of wavelength variables screened by CARS algorithm
    Fig. 6. Distribution of wavelength variables screened by CARS algorithm
    Prediction results of CARS-PLS model for correction set
    Fig. 7. Prediction results of CARS-PLS model for correction set
    Sample numberReference content /%
    1#0.014
    2#0.015
    3#0.027
    4#0.036
    5#0.042
    6#0.055
    7#0.11
    8#0.15
    9#0.17
    10#0.24
    Table 1. Reference content of lead in paint coating samples
    PredictsetReferencecontent /%Univariate calibrationMLRALL-PLSCARS-PLS
    Predictedcontend /%Relativeerror /%Predictedcontend /%Relativeerror /%Predictedcontend /%Relativeerror /%Predictedcontend /%Relativeerror /%
    4#0.0360.03211.10.040311.90.031711.90.03651.4
    7#0.110.09315.50.10861.30.11999.00.11161.5
    Table 2. Prediction result of each analysis model for sample of prediction set
    Zijun Wu, Jingqi Lu, Jian Huang, Dewei Cheng. Pb Detection in Paint Coatings Through Combined Laser-Induced Breakdown Spectroscopy and CARS Variable Screening[J]. Laser & Optoelectronics Progress, 2019, 56(14): 143001
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