Analysis of Material and Source of Archaic Jade From the Tomb of Marquis Yi of Zeng in Suizhou, Hubei Province

Ji-fu LIU; Ming-xing YANG; Yue SU; Yue LIU

doi:10.3964/j.issn.1000-0593(2022)01-0215-07

Journals >Spectroscopy and Spectral Analysis >Volume 42 >Issue 1 >Page 215 > Article

Spectroscopy and Spectral Analysis
Vol. 42, Issue 1, 215 (2022)

Analysis of Material and Source of Archaic Jade From the Tomb of Marquis Yi of Zeng in Suizhou, Hubei Province

Ji-fu LIU^1、*, Ming-xing YANG^{1、1; *;}, Yue SU^1、1;, and Yue LIU^2、2;

Author Affiliations

¹1. Gemmological Institute, China University of Geosciences (Wuhan), Wuhan 430074, China

²2. Yangzhou Jade Product Quality Supervision and Inspection Center, Yangzhou 225000, China

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DOI: 10.3964/j.issn.1000-0593(2022)01-0215-07 Cite this Article

Ji-fu LIU, Ming-xing YANG, Yue SU, Yue LIU. Analysis of Material and Source of Archaic Jade From the Tomb of Marquis Yi of Zeng in Suizhou, Hubei Province[J]. Spectroscopy and Spectral Analysis, 2022, 42(1): 215 Copy Citation Text

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Some archaic jade from the tomb of Marquis Yi of Zeng(a): No soak-induced color tremolite; (b): Light soak-induced color tremolite; (c): Medium soak-induced color tremolite; (d): Severe soak-induced color tremolite; (e): Marble; (f): Mica jade; (g): Crystal; (h): Fluorite; (i): Quartzite

Fig. 1. Some archaic jade from the tomb of Marquis Yi of Zeng
(a): No soak-induced color tremolite; (b): Light soak-induced color tremolite; (c): Medium soak-induced color tremolite; (d): Severe soak-induced color tremolite; (e): Marble; (f): Mica jade; (g): Crystal; (h): Fluorite; (i): Quartzite

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Fig. 2. Infrared spectra of different categories archaic jade infrared spectrogram

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Fig. 3. Some samples with origin information
(a)—(d): Retaining the epidermal characteristics of gobi materials; (e)—(f): With weathered skin

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样品类别	颜色	光泽	沁色	表面受沁程度	比重
透闪石类	以白、青白、灰白为主, 有少量青黄色、青色、青花的玉器	油脂光泽-弱油脂光泽	白色、褐色	无-重度受沁	2.80~3.10(通常2.95)
大理岩类	白色、褐色	土状光泽	白色、褐色	严重受沁	2.60~2.90
云母质类	青灰色、青黄色、浅褐色	蜡状光泽	褐黄色、浅褐色	极轻微-轻微受沁	2.70~2.90
石英质类	褐红色	油脂光泽	未受沁	-	2.60
萤石类	灰白色	弱玻璃光泽	未受沁	-	3.16
水晶类	无色	玻璃光泽	未受沁	-	2.63~2.65

Table 1. Basic gemological characteristics of archaic jades

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材质	峰位	标准谱峰	归属指派
透闪石	1 144, 1 039, 997, 924	1 137, 1 040, 997, 921	O—Si—O, Si—O—Si的反对称伸缩振动及O—Si—O对称伸缩振动
	761, 687	762, 687	Si—O—Si对称伸缩振动
	510, 461, 419	538, 513, 467	Si—O的弯曲振动和M—O的晶格振动
大理岩	1 538	1 450	C—O键的不对称伸缩振动
大理岩	897, 729	892, 726	C—O键的弯曲振动
云母	1 080, 1 037	1 022	Si—O—Si的伸缩振动
	930, 835	935, 833, 803	Al—O^-面外振动(830附近), OH的摆动(950~800)
	748	754	Al—O—Si面内振动(750附近)
	537, 482	533, 479, 412	Si—O的弯曲振动(530附近), OH的平移振动(520~400)
石英岩	1 180, 1 147	1 168, 1 086	Si—O—Si反对称伸缩振动
石英岩	803, 785, 695, 541, 498	798, 779, 695, 515, 462	Si—O键对称伸缩振动
水晶	1 184, 1 147	1 170, 1 085	Si—O—Si反对称伸缩振动
水晶	804, 786, 696, 543, 498	798, 779, 695, 519, 462	Si—O键对称伸缩振动

Table 2. Attribution of infrared spectrum peaks of the unearthed jade

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	编号	SiO₂/%	MgO/%	CaO/%	FeO/%	Al/10^-6	Mn/10^-6	Na/10^-6	K/10^-6	Ti/10^-6	Mg/Mg+Fe
	E.243	58.2	22.6	16.3	2.0	4 344	1 651	745	1 051	56	0.92
透闪石	W.C.7: 7	59.4	24.2	15.3	0.7	2 738	302	607	672	138	0.97
	E.48	58.7	25.2	14.8	0.9	3 020	768	694	211	17	0.97
	编号	SiO₂/%	MgO/%	CaO/%	FeO/%	Al₂O₃/%	Mn/10^-6	Na/10^-6	K/10^-6	Ti/10^-6	CaO:MgO
	E.75-13	1.6	15.7	38.7	0.1	1.375	209	780	623	207	2.46
大理岩	N.344-2	1.7	16.2	38.1	0.1	1.720	171	639	917	210	2.35
	W.C.6:3	2.1	15.2	38.7	0.1	0.916	113	341	1097	246	2.54
	编号	SiO₂/%	MgO/%	CaO/%	FeO/%	Al₂O₃/%	K₂O/%	Mn/10^-6	Na/10^-6	Ti/10^-6	P/10^-6
	N.341	62.7	3.7	2.2	1.9	8.6	15.9	1 020	1 292	966	779
云母质	W.C.2:6	78.5	2.3	0.9	0.5	4.4	5.3	99	834	3 825	544
	E.C.8:6	61.2	3.3	0.2	4.2	8.8	14.5	342	1 110	1 813	276
	编号	SiO₂/%	MgO/%	CaO/%	FeO/%	Al/10^-6	Mn/10^-6	Na/10^-6	K/10^-6	Ti/10^-6	P/10^-6
石英岩	E.C.11:266	96.4	2.1	0.3	0.4	3 283	62	665	2 563	1 003	1 353
	编号	SiO₂/%	MgO/%	CaO/%	FeO/%	Al/10^-6	Mn/10^-6	Na/10^-6	K/10^-6	Ti/10^-6
萤石	N.361	1.0	0.7	97.9	0.1	1 116	32	271	1 141	307
	编号	SiO₂/%	MgO/%	CaO/%	FeO/%	Al/10^-6	Mn/10^-6	Na/10^-6	K/10^-6	Ti/10^-6	P/10^-6
水晶	E.C.2:7	98.5	1.3	0.0	0.0	1 880	11	436	59	3	254

Table 3. Main chemical components of some archaic jade samples

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出土位置		材质	数量
东室	东室主内棺	透闪石质玉	175
	东室主内棺	石英岩	1
	东室主外棺	透闪石质玉	8
	东室外棺内底西侧	透闪石质玉	3
	东室陪葬棺	透闪石质玉	16
		云母质玉	1
		水晶	2
	东室殉狗棺	大理岩	2
	东室	透闪石质玉	22
		云母质玉	1
		大理岩	34
	东壁外采集	透闪石质玉	1
西室	西室陪葬棺	透闪石质玉	34
		云母质玉	5
		大理岩	3
	西室椁室内	透闪石质玉	2
	西室	透闪石质玉	1
北室		透闪石质玉	2
		云母质玉	1
		大理岩	4
		萤石	1

Table 4. The excavated location, material and quantity statistics of the test samples

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