Scientific Research on Warring States Ink Unearthed From Jiangling Jiudian Tomb in Hubei Province

Na YAO; Zi-fan CHEN; Xiong ZHAO; Shu-ya WEI

doi:10.3964/j.issn.1000-0593(2021)11-3418-06

Journals >Spectroscopy and Spectral Analysis >Volume 41 >Issue 11 >Page 3418 > Article

Spectroscopy and Spectral Analysis
Vol. 41, Issue 11, 3418 (2021)

Scientific Research on Warring States Ink Unearthed From Jiangling Jiudian Tomb in Hubei Province

Na YAO^1、1;, Zi-fan CHEN^2、2;, Xiong ZHAO^2、2;, and Shu-ya WEI^{1、1; *;}

Author Affiliations

¹1. Institute of Cultural Heritage and History of Science & Technology, University of Science and Technology Beijing, Beijing 100083, China

²2. Hubei Provincial Museum, Wuhan 430077, China

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DOI: 10.3964/j.issn.1000-0593(2021)11-3418-06 Cite this Article

Na YAO, Zi-fan CHEN, Xiong ZHAO, Shu-ya WEI. Scientific Research on Warring States Ink Unearthed From Jiangling Jiudian Tomb in Hubei Province[J]. Spectroscopy and Spectral Analysis, 2021, 41(11): 3418 Copy Citation Text

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Fig. 1. A set of writing tools excavated in the tomb of Jiudian village, Jiangling County and presented in the Hubei Museum

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Fig. 2. The ancient ink discovered in the tomb of Jiudian village, Jiangling County and presented in the Hubei Museum

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Fig. 3. FTIR spectra of lamp soot ink (LM), pine wood ink (PM) and ancient ink (GM)

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Fig. 4. The morphologies of lamp soot ink (a), pine wood ink (b) and ancient ink (c) by using Transmission Electron Microscope (×50 000)

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Fig. 5. The particle size and size distribution of pine wood ink, lamp soot ink and ancient ink

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Fig. 6. The chromatograms(TIC) obtained by Py-GC/MS analysis of ancient ink discovered in Jiudian village, Jiangling County

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Fig. 7. The select ion chromatogram (SIM) of ancient ink discovered in Jiudian village by using Py-GC/MS

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Fig. 8. The chemical structures of several marker compounds

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类别	古墨	现代参考墨
样品	江陵九店战国墨	松烟墨	油烟墨
来源	湖北省博物馆	江西	安徽绩溪

Table 1. Samples used in this study

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峰	保留时间	峰面积/%	主要离子	化合物
1	2.47	1.43	51, 78, (104)	苯乙烯
Cam	14.76	1.02	55, 81, (95), 108, 152	樟脑
Nap	15.93	1.26	51, 102, (128)	萘
2	16.42	0.66	(55), 69, 97, 168	1-十二烷醇
3	19.61	1.44	115, (142)	1-甲基萘
E1	23.18	3.12	93, 105, (119), 161, 204	α-柏木烯
E2	23.4	1.97	69, 93, 133, (161), 204	β雪松烯
E3	24.94	1.72	105, 119, (132), 145, 202	花侧柏烯
E4	28.22	4.76	69, 95, (150), 161, 204	雪松醇
S1	32.2	3.57	76, 89, 152, (178)	菲
4	32.77	8.03	(77), 121, 214	1,2-二苯氧基-乙烷
5	33.54	1.3	(58), 85, 124, 250	6,10,14-三甲基-2-十五酮
6	34.8	1.91	(192)	3-甲基菲
7	35.3	2.13	95, (192)	2-甲基蒽
8	36.28	0.92	101, 150, (204)	2-苯基萘
S2	38.53	2.92	88, 101, (202)	荧蒽
S3	39.1	2.82	88, 101, (202)	芘
T1	40.9	1.43	189, 204, (219), 234	惹烯
9	42.85	6.32	(179), 261, 343	未知
T2	43.12	0.32	(239), 299, 314	脱氢松香酸甲酯
S4	45.13	1.37	101, 113, (228), 229	三亚苯
S5	50.52	2.6	113, 125, (252)	苯并[k]荧蒽
10	52.03	0.44	239, 321, 403, (485)	未知
11	55.79	0.18	138, (276)	苯并[ghi]苝

Table 2. Pyrolysis compounds of ancient ink discovered in Jiudian village, Jiangling County by Py-GC/MS

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PAHs	样品
PAHs	PM	LM	CB	GM
S1 area(%) (m/z 178)	13.9	14.5	71.4	26.8
S2 area(%) (m/z 202)	27.0	34.3	9.8	22.0
S3 area(%) (m/z 202)	28.9	34.7	9.1	21.2
S4 area(%) (m/z 228)	10.0	3.8	0.0	10.3
S5 area(%) (m/z 252)	20.2	12.5	9.5	19.6

Table 3. The relative contents of the main PAHs in the modern pine wood ink (PM), lamp soot ink (LM), carbon black (CB) in literature and ancient ink (GM) in Jiudian village, Jiangling County by Py-GC/MS analysis in SIM mode

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