• Journal of Inorganic Materials
  • Vol. 34, Issue 8, 827 (2019)
Si-Han LI, Chao ZHANG, Chen-Liang WU, He-Feng ZHANG, and Xin-Huan YAN*
Author Affiliations
  • State Key Laboratory Breeding Base of Green Chemistry-Synthesis Technology, College of Chemical Engineering, Zhejiang University of Technology, Hangzhou 310014, China
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    DOI: 10.15541/jim20180523 Cite this Article
    Si-Han LI, Chao ZHANG, Chen-Liang WU, He-Feng ZHANG, Xin-Huan YAN. Pd/CeO2/γ-Al2O3 Catalyst with Low Loading for Catalytic Oxidation of VOCs[J]. Journal of Inorganic Materials, 2019, 34(8): 827 Copy Citation Text show less
    Catalytic oxidation of VOCs(a) toluene, (b) acetone, (c) ethyl acetate over Pd/γ-Al2O3 and Pd/CeO2/γ-Al2O3
    1. Catalytic oxidation of VOCs(a) toluene, (b) acetone, (c) ethyl acetate over Pd/γ-Al2O3 and Pd/CeO2/γ-Al2O3
    Catalytic oxidation of toluene over Pd/CeO2/γ-Al2O3 at various GHSVs
    2. Catalytic oxidation of toluene over Pd/CeO2/γ-Al2O3 at various GHSVs
    Stability tests for toluene oxidation with time-on- stream over Pd/CeO2/γ-Al2O3
    3. Stability tests for toluene oxidation with time-on- stream over Pd/CeO2/γ-Al2O3
    Effect of water vapor on toluene conversion over the Pd/Al2O3 and Pd/Ce2O/Al2O3 catalyst under the conditions of toluene concentration = 1×10-3, water vapor concentration = 5.0vol% and GHSV = 18000 mL/(g·h)
    4. Effect of water vapor on toluene conversion over the Pd/Al2O3 and Pd/Ce2O/Al2O3 catalyst under the conditions of toluene concentration = 1×10-3, water vapor concentration = 5.0vol% and GHSV = 18000 mL/(g·h)
    XRD patterns of (a) γ-Al2O3, (b) Pd/γ-Al2O3 and (c) Pd/CeO2/γ-Al2O3
    5. XRD patterns of (a) γ-Al2O3, (b) Pd/γ-Al2O3 and (c) Pd/CeO2/γ-Al2O3
    TEM images and Pd NPs size distribution of (a) Pd/γ-Al2O3 and (b) Pd/CeO2/γ-Al2O3
    6. TEM images and Pd NPs size distribution of (a) Pd/γ-Al2O3 and (b) Pd/CeO2/γ-Al2O3
    XPS spectra of (a) Pd 3d and (b) Ce 3d for Pd/γ-Al2O3 and Pd/CeO2/γ-Al2O3
    7. XPS spectra of (a) Pd 3d and (b) Ce 3d for Pd/γ-Al2O3 and Pd/CeO2/γ-Al2O3
    H2-TPR profiles of (a) Pd/γ-Al2O3 and (b) Pd/CeO2/γ- Al2O3
    8. H2-TPR profiles of (a) Pd/γ-Al2O3 and (b) Pd/CeO2/γ- Al2O3
    SampleSurface area/(m2·g-1)Pore size/nmPore volume/(cm3·g-1)
    γ-Al2O33575.130.53
    Pd/γ-Al2O33455.070.52
    Pd/CeO2/γ-Al2O33395.020.49
    Table 1. Physical structure parameters of Al2O3, Pd/Al2O3 and Pd/CeO2/Al2O3
    CatalystRelative content/wt%
    PdPdOCe3+Ce4+
    Pd/γ-Al2O334.265.8
    Pd/CeO2/γ-Al2O3010014.585.5
    Table 2. XPS results of Pd/γ-Al2O3 and Pd/CeO2/γ-Al2O3
    Si-Han LI, Chao ZHANG, Chen-Liang WU, He-Feng ZHANG, Xin-Huan YAN. Pd/CeO2/γ-Al2O3 Catalyst with Low Loading for Catalytic Oxidation of VOCs[J]. Journal of Inorganic Materials, 2019, 34(8): 827
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