Author Affiliations
11. Key Laboratory of Inorganic Functional Material and Device, Shanghai Institute of Ceramics, Chinese Academy of Sciences, Shanghai 200050, China22. School of Materials and Chemistry, University of Shanghai for Science and Technology, Shanghai 200093, Chinashow less
1. Photos of SBLn glasses melted at 1600 ℃ for 2 h (a) andXRD patterns of glass and partial crystallization SBLn glass (b)
2. Glass forming areas of SBLn glass system
3. Infrared spectra of SBLn glass in the wavelength range of 400-1400 cm-1
4. Differential thermal analysis of SBLn glass
5. XRD pattern of SBLn glass heated at 750-1200 ℃ for 2 h
6. XRD patterns of SBLn glass sintered at 1150 ℃ for 2 h
7. Sintering curves (a) and density curves (b) of SBLn glass (b) sintered at 800-1200 ℃ for 2 h
8. SEM images of SBLn glass sintered at 1150 ℃ for 2 h
9. Elemental distributions of SBEr glass-ceramic sintered at 1150 ℃ for 2 h
10. Thermal expansion curves of SBLn glass-ceramics sintered at 1150 ℃ for 2 h (a) and histogram of SBLn thermal expansion coefficients and softening points (b)
11. DC resistivity variated with temperature of SBLn glass-ceramics sintered at 1150 ℃ for 2 h
Rare earth ions | Cation field strength, CFS |
---|
Ba2+ | 1.41 | La3+ | 2.82 | Sm3+ | 3.23 | Er3+ | 3.87 | Yb3+ | 3.98 |
|
Table 1. Cation field strength of rare earth
Sample | SiO2 | BaO | La2O
| Sm2O3 | Er2O3 | | Yb2O3 |
---|
SBLa | 50 | 45 | 5 | | | | | SBSm | 50 | 45 | | 5 | | | | SBEr | 50 | 45 | | | 5 | | | SBYb | 50 | 45 | | | | | 5 |
|
Table 2. Composition of BaO-SiO2-Ln2O3 (%, in mol)
Peak position/cm-1 | Chemical bond type | Ref. |
---|
460-510 | Si-O-Si and O-Si-O bending vibration modes | [13⇓-15] | 720-820 | Si-O-Si symmetric stretching of bridging oxygen | [13⇓-15] | 830-940 | Si-O− stretching with two non-bridging oxygens | [13⇓-15] | 1050-1100 | Si-O-Si anti-symmetric stretching of bridging oxygen within the tetrahedra | [13⇓-15] |
|
Table 3. Corresponding vibration mode and chemical bond type of FT-IR spectra for SBLn
Sample | Tg/℃
| Tx/℃
| Tp1/℃
| Tp2/℃
| ΔT/℃
|
---|
SBLa | 755.0 | 850.3 | 873.4 | 900.1 | 95.3 | SBSm | 784.0 | 891.7 | 918.0 | 968.2 | 97.7 | SBEr | 794.8 | 894.8 | 923.4 | 982.5 | 100.0 | SBYb | 814.8 | 920.6 | 959.3 | 1046.6 | 105.6 |
|
Table 4. Differential thermal analysis data of SBLn glass