• Journal of Inorganic Materials
  • Vol. 38, Issue 10, 1207 (2023)
Yanguo YANG1、2, Haishen REN1、*, Daihua HE2, and Huixing LIN1、2、*
Author Affiliations
  • 11. Key Laboratory of Inorganic Functional Material and Device, Shanghai Institute of Ceramics, Chinese Academy of Sciences, Shanghai 200050, China
  • 22. School of Materials and Chemistry, University of Shanghai for Science and Technology, Shanghai 200093, China
  • show less
    DOI: 10.15541/jim20230044 Cite this Article
    Yanguo YANG, Haishen REN, Daihua HE, Huixing LIN. Effect of Cation Field Strength on Structure and High-temperature Properties of BaO-SiO2-Ln2O3 Glass-ceramic [J]. Journal of Inorganic Materials, 2023, 38(10): 1207 Copy Citation Text show less
    Photos of SBLn glasses melted at 1600 ℃ for 2 h (a) andXRD patterns of glass and partial crystallization SBLn glass (b)
    1. Photos of SBLn glasses melted at 1600 ℃ for 2 h (a) andXRD patterns of glass and partial crystallization SBLn glass (b)
    Glass forming areas of SBLn glass system
    2. Glass forming areas of SBLn glass system
    Infrared spectra of SBLn glass in the wavelength range of 400-1400 cm-1
    3. Infrared spectra of SBLn glass in the wavelength range of 400-1400 cm-1
    Differential thermal analysis of SBLn glass
    4. Differential thermal analysis of SBLn glass
    XRD pattern of SBLn glass heated at 750-1200 ℃ for 2 h
    5. XRD pattern of SBLn glass heated at 750-1200 ℃ for 2 h
    XRD patterns of SBLn glass sintered at 1150 ℃ for 2 h
    6. XRD patterns of SBLn glass sintered at 1150 ℃ for 2 h
    Sintering curves (a) and density curves (b) of SBLn glass (b) sintered at 800-1200 ℃ for 2 h
    7. Sintering curves (a) and density curves (b) of SBLn glass (b) sintered at 800-1200 ℃ for 2 h
    SEM images of SBLn glass sintered at 1150 ℃ for 2 h
    8. SEM images of SBLn glass sintered at 1150 ℃ for 2 h
    Elemental distributions of SBEr glass-ceramic sintered at 1150 ℃ for 2 h
    9. Elemental distributions of SBEr glass-ceramic sintered at 1150 ℃ for 2 h
    Thermal expansion curves of SBLn glass-ceramics sintered at 1150 ℃ for 2 h (a) and histogram of SBLn thermal expansion coefficients and softening points (b)
    10. Thermal expansion curves of SBLn glass-ceramics sintered at 1150 ℃ for 2 h (a) and histogram of SBLn thermal expansion coefficients and softening points (b)
    DC resistivity variated with temperature of SBLn glass-ceramics sintered at 1150 ℃ for 2 h
    11. DC resistivity variated with temperature of SBLn glass-ceramics sintered at 1150 ℃ for 2 h
    Rare earth ionsCation field strength, CFS
    Ba2+1.41
    La3+2.82
    Sm3+3.23
    Er3+3.87
    Yb3+3.98
    Table 1. Cation field strength of rare earth
    SampleSiO2BaOLa2O Sm2O3Er2O3Yb2O3
    SBLa50455
    SBSm50455
    SBEr50455
    SBYb50455
    Table 2. Composition of BaO-SiO2-Ln2O3 (%, in mol)
    Peak position/cm-1Chemical bond typeRef.
    460-510Si-O-Si and O-Si-O bending vibration modes[13-15]
    720-820Si-O-Si symmetric stretching of bridging oxygen[13-15]
    830-940Si-O stretching with two non-bridging oxygens[13-15]
    1050-1100Si-O-Si anti-symmetric stretching of bridging oxygen within the tetrahedra[13-15]
    Table 3. Corresponding vibration mode and chemical bond type of FT-IR spectra for SBLn
    SampleTg/℃ Tx/℃ Tp1/℃ Tp2/℃ ΔT/℃
    SBLa755.0850.3873.4900.195.3
    SBSm784.0891.7918.0968.297.7
    SBEr794.8894.8923.4982.5100.0
    SBYb814.8920.6959.31046.6105.6
    Table 4. Differential thermal analysis data of SBLn glass
    Yanguo YANG, Haishen REN, Daihua HE, Huixing LIN. Effect of Cation Field Strength on Structure and High-temperature Properties of BaO-SiO2-Ln2O3 Glass-ceramic [J]. Journal of Inorganic Materials, 2023, 38(10): 1207
    Download Citation