Author Affiliations
11. School of Chemical and Environmental Engineering, China University of Mining and Technology, Beijing 100083, China22. Institute of Agricultural Resources and Regional Planning, Chinese Academy of Agricultural Sciences/Key Laboratory of Plant Nutrition and Fertilizer, Ministry of Agriculture and Rural Affairs, Beijing 100081, China33. Anhui Province Key Laboratory of Farmland Ecological Conservation and Pollution Prevention, School of Resources and Environment/Anhui Agricultural University, Hefei 230036, Chinashow less
Fig. 1. FTIR spectra of samples
(a): CAU3, et al; (b): SAU3, et al
Fig. 2. The XPS full spectra of samples
(a): U1, CAU3, CA; (b): U1, SAU3, SA
Fig. 3. XPS C(1s) peak fitting spectra of samples
(a): U1, CAU3, CA; (b): U1, SAU3, SA
Fig. 4. XPS O(1s) peak fitting spectra of samples
(a): U1, CAU3, CA; (b): U1, SAU3, SA
Fig. 5. XPS N(1s) peak fitting spectra of samples
(a): U1 and CAU3; (b): U1 and SAU3
Fig. 6. Total ion chromatogrom of U1 (a), CAU3(b), SAU3 (c) samples in positive mode
Fig. 7. MS spectra of sample characteristic peaks
(a): The MS spectrum for all samples with retention time of 1.09 min was shown; (b) MS spectrum for CAU3 with retention time of 8.40 min shown; (c), (d): MS spectra for SAU3 with retention time of 8.40, 9.53 min shown, respectively
样品 | 各形态碳占总碳的比例 |
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N—CO—N | —CX | —C—O | —Caron | —Caroma | O=C—O |
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CAU3 | 27.17 | 16.85 | 25.85 | 30.13 | 0 | | SAU3 | 30.17 | 29.97 | 0 | 15.71 | 24.45 | | CA | 0 | 0 | 17.09 | 40.02 | 0 | 42.89 | SA | 0 | 0 | 0 | 52.01 | 40.01 | 7.98 | U1 | 100.00 | 0 | 0 | 0 | 0 | |
|
Table 1. Surface carbon atoms content in fertilizerand the contribution of carbon species to C(1s) peak (%)
样品 | 各形态氧占总氧的比例 |
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C=O | C—OH |
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CAU3 | 54.94 | 45.06 | SAU3 | 61.86 | 38.14 | CA | 44.72 | 55.28 | SA | 59.91 | 40.09 | U1 | 100.00 | 0 |
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Table 2. Surface oxygen atoms content in fertilizerand the contribution of oxygenspecies to O(1s) peak (%)
样品 | 各形态氮占总氮的比例 |
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N—CO—N | —NX |
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CAU3 | 57.62 | 42.38 | SAU3 | 53.36 | 46.64 | U1 | 100.00 | 0 |
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Table 3. Surface nitrogen atoms content in fertilizer and the contribution of nitrogen species to N(1s) peak (%)