• Spectroscopy and Spectral Analysis
  • Vol. 41, Issue 10, 3129 (2021)
Ying-qiang ZHANG1、*, Shui-qin ZHANG2、2;, Li-yan WANG1、1; *;, Liang YUAN2、2;, Yan-ting LI2、2;, Qi-zhong XIONG3、3;, Zhi-an LIN2、2;, and Bing-qiang ZHAO2、2; *;
Author Affiliations
  • 11. School of Chemical and Environmental Engineering, China University of Mining and Technology, Beijing 100083, China
  • 22. Institute of Agricultural Resources and Regional Planning, Chinese Academy of Agricultural Sciences/Key Laboratory of Plant Nutrition and Fertilizer, Ministry of Agriculture and Rural Affairs, Beijing 100081, China
  • 33. Anhui Province Key Laboratory of Farmland Ecological Conservation and Pollution Prevention, School of Resources and Environment/Anhui Agricultural University, Hefei 230036, China
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    DOI: 10.3964/j.issn.1000-0593(2021)10-3129-08 Cite this Article
    Ying-qiang ZHANG, Shui-qin ZHANG, Li-yan WANG, Liang YUAN, Yan-ting LI, Qi-zhong XIONG, Zhi-an LIN, Bing-qiang ZHAO. Multispectral Structural Characterization of Low-Molecular-Weight Organic Acids Modified Urea[J]. Spectroscopy and Spectral Analysis, 2021, 41(10): 3129 Copy Citation Text show less
    FTIR spectra of samples(a): CAU3, et al; (b): SAU3, et al
    Fig. 1. FTIR spectra of samples
    (a): CAU3, et al; (b): SAU3, et al
    The XPS full spectra of samples(a): U1, CAU3, CA; (b): U1, SAU3, SA
    Fig. 2. The XPS full spectra of samples
    (a): U1, CAU3, CA; (b): U1, SAU3, SA
    XPS C(1s) peak fitting spectra of samples(a): U1, CAU3, CA; (b): U1, SAU3, SA
    Fig. 3. XPS C(1s) peak fitting spectra of samples
    (a): U1, CAU3, CA; (b): U1, SAU3, SA
    XPS O(1s) peak fitting spectra of samples(a): U1, CAU3, CA; (b): U1, SAU3, SA
    Fig. 4. XPS O(1s) peak fitting spectra of samples
    (a): U1, CAU3, CA; (b): U1, SAU3, SA
    XPS N(1s) peak fitting spectra of samples(a): U1 and CAU3; (b): U1 and SAU3
    Fig. 5. XPS N(1s) peak fitting spectra of samples
    (a): U1 and CAU3; (b): U1 and SAU3
    Total ion chromatogrom of U1 (a), CAU3(b), SAU3 (c) samples in positive mode
    Fig. 6. Total ion chromatogrom of U1 (a), CAU3(b), SAU3 (c) samples in positive mode
    MS spectra of sample characteristic peaks(a): The MS spectrum for all samples with retention time of 1.09 min was shown; (b) MS spectrum for CAU3 with retention time of 8.40 min shown; (c), (d): MS spectra for SAU3 with retention time of 8.40, 9.53 min shown, respectively
    Fig. 7. MS spectra of sample characteristic peaks
    (a): The MS spectrum for all samples with retention time of 1.09 min was shown; (b) MS spectrum for CAU3 with retention time of 8.40 min shown; (c), (d): MS spectra for SAU3 with retention time of 8.40, 9.53 min shown, respectively
    样品各形态碳占总碳的比例
    N—CO—N—CX—C—O—Caron—CaromaO=C—O
    CAU327.1716.8525.8530.130
    SAU330.1729.97015.7124.45
    CA0017.0940.02042.89
    SA00052.0140.017.98
    U1100.000000
    Table 1. Surface carbon atoms content in fertilizerand the contribution of carbon species to C(1s) peak (%)
    样品各形态氧占总氧的比例
    C=OC—OH
    CAU354.9445.06
    SAU361.8638.14
    CA44.7255.28
    SA59.9140.09
    U1100.000
    Table 2. Surface oxygen atoms content in fertilizerand the contribution of oxygenspecies to O(1s) peak (%)
    样品各形态氮占总氮的比例
    N—CO—N—NX
    CAU357.6242.38
    SAU353.3646.64
    U1100.000
    Table 3. Surface nitrogen atoms content in fertilizer and the contribution of nitrogen species to N(1s) peak (%)
    Ying-qiang ZHANG, Shui-qin ZHANG, Li-yan WANG, Liang YUAN, Yan-ting LI, Qi-zhong XIONG, Zhi-an LIN, Bing-qiang ZHAO. Multispectral Structural Characterization of Low-Molecular-Weight Organic Acids Modified Urea[J]. Spectroscopy and Spectral Analysis, 2021, 41(10): 3129
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