• Laser & Optoelectronics Progress
  • Vol. 56, Issue 19, 193003 (2019)
Li Xu1、2, Zhirong Zhang1、2、3、*, Fengzhong Dong1、2、3, Pengshuai Sun1, Hua Xia1, Runqing Yu1, Zhe Li1, and Qiming Xu4
Author Affiliations
  • 1Key Laboratory of Photon-Devices and Materials Anhui Institute of Optics and Fine Mechanics, Chinese Academy of Sciences, Hefei, Anhui 230031, China
  • 2School of Environmental Science and Optoelectronic Technology University of Science and Technology of China Hefei, Anhui 230026, China
  • 3Key Laboratory of Environmental Optics & Technology Anhui Institute of Optics and Fine Mechanics, Chinese Academy of Sciences Hefei, Anhui 230031, China
  • 4College of Engineering, Taiwan Yunlin University of Science and Technology, Yunlin, Taiwan 64002, China
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    DOI: 10.3788/LOP56.193003 Cite this Article Set citation alerts
    Li Xu, Zhirong Zhang, Fengzhong Dong, Pengshuai Sun, Hua Xia, Runqing Yu, Zhe Li, Qiming Xu. Analytical Method of Spectral Overlapping Interference Using Laser Absorption Spectroscopy[J]. Laser & Optoelectronics Progress, 2019, 56(19): 193003 Copy Citation Text show less
    Schematic of experiment for laser absorption spectroscopy
    Fig. 1. Schematic of experiment for laser absorption spectroscopy
    Picture of experimental device for laser absorption spectroscopy
    Fig. 2. Picture of experimental device for laser absorption spectroscopy
    Absorption lines of NH3, CO2, and H2O when thermodynamic temperature is 296 K. (a) NH3; (b) CO2; (c) H2O
    Fig. 3. Absorption lines of NH3, CO2, and H2O when thermodynamic temperature is 296 K. (a) NH3; (b) CO2; (c) H2O
    Simulated absorption spectrum of NH3 standard gas with volume fraction of 1.9×10-5
    Fig. 4. Simulated absorption spectrum of NH3 standard gas with volume fraction of 1.9×10-5
    Simulated absorption spectra under different pressures of NH3 with volume fraction of 1.9×10-5. (a) 0.5 atm; (b) 0.25 atm; (c) 0.1 atm
    Fig. 5. Simulated absorption spectra under different pressures of NH3 with volume fraction of 1.9×10-5. (a) 0.5 atm; (b) 0.25 atm; (c) 0.1 atm
    Absorption spectra of NH3 with volume fraction of 1.9×10-5 under different pressures
    Fig. 6. Absorption spectra of NH3 with volume fraction of 1.9×10-5 under different pressures
    Simulated absorption spectra of CH4 with volume fraction of 10-4 under different pressures. (a) 0.1 atm; (b) 0.2 atm; (c) 0.3 atm; (a) 1.0 atm
    Fig. 7. Simulated absorption spectra of CH4 with volume fraction of 10-4 under different pressures. (a) 0.1 atm; (b) 0.2 atm; (c) 0.3 atm; (a) 1.0 atm
    Experimentally measured absorption spectra of CH4 with volume fraction of 10-4 under different pressures
    Fig. 8. Experimentally measured absorption spectra of CH4 with volume fraction of 10-4 under different pressures
    Measured absorption spectrum of NH3 with volume fraction of 1.9×10-5 when pressure is 0.18 atm
    Fig. 9. Measured absorption spectrum of NH3 with volume fraction of 1.9×10-5 when pressure is 0.18 atm
    Fitting of NH3 concentration and its absorbance when pressure is 0.18 atm
    Fig. 10. Fitting of NH3 concentration and its absorbance when pressure is 0.18 atm
    Wave number /cm-1Spectral line intensity /(10-21cm-1·molecule-1·cm2)
    6528.76851.174
    6528.77321.174
    6528.89981.350
    6529.19011.230
    Table 1. Absorption line intensity of NH3 standard gas near 6528.8 cm-1 from HITRAN 2012 dataset
    Wave number /cm-1Spectral line intensity /(10-22cm-1·molecule-1·cm2)
    6046.94257.877
    6046.95169.277
    6046.96351.455
    Table 2. Absorption line intensity of CH4 near 6046.9 cm-1 from HITRAN 2012 dataset
    Volume fraction /10-6Maximum absorbance
    50.00165
    190.00746
    500.01640
    900.02924
    1050.03437
    Table 3. Maximum absorbance of NH3 with different concentrations under pressure of 0.18 atm
    Li Xu, Zhirong Zhang, Fengzhong Dong, Pengshuai Sun, Hua Xia, Runqing Yu, Zhe Li, Qiming Xu. Analytical Method of Spectral Overlapping Interference Using Laser Absorption Spectroscopy[J]. Laser & Optoelectronics Progress, 2019, 56(19): 193003
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