• Chinese Optics Letters
  • Vol. 16, Issue 9, 091901 (2018)
A. A. Lyapin1、*, S. V. Gushchin1, A. S. Ermakov1, S. V. Kuznetsov2, P. A. Ryabochkina1, V. Yu. Proydakova2, V. V. Voronov2, P. P. Fedorov2, and M. V. Chernov1
Author Affiliations
  • 1National Research Ogarev Mordovia State University, Saransk 430005, Mordovia, Russia
  • 2Prokhorov General Physics Institute of the Russian Academy of Sciences, Moscow 119991, Russia
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    DOI: 10.3788/COL201816.091901 Cite this Article Set citation alerts
    A. A. Lyapin, S. V. Gushchin, A. S. Ermakov, S. V. Kuznetsov, P. A. Ryabochkina, V. Yu. Proydakova, V. V. Voronov, P. P. Fedorov, M. V. Chernov. Mechanisms and absolute quantum yield of upconversion luminescence of fluoride phosphors[J]. Chinese Optics Letters, 2018, 16(9): 091901 Copy Citation Text show less
    UCL spectra of SrF2:Er (14.2 mol.%) in the visible and near-infrared spectral ranges.
    Fig. 1. UCL spectra of SrF2:Er (14.2 mol.%) in the visible and near-infrared spectral ranges.
    Absorption transition, luminescence transitions, and UC mechanisms of Er3+ ions in SrF2:Er.
    Fig. 2. Absorption transition, luminescence transitions, and UC mechanisms of Er3+ ions in SrF2:Er.
    Luminescence rise and decay from (a) H29/2, (b) H211/2, (c) S43/2, (d) F49/2, (e) G411/2, F45/2, F47/2 levels of Er3+ ions in SrF2:Er.
    Fig. 3. Luminescence rise and decay from (a) H29/2, (b) H211/2, (c) S43/2, (d) F49/2, (e) G411/2, F45/2, F47/2 levels of Er3+ ions in SrF2:Er.
    P-dependent UCL at the (a) S43/2→I415/2 and (b) F49/2→I415/2 transitions of Er3+ ions. The diagram is in a double logarithmic scale.
    Fig. 4. P-dependent UCL at the (a) S43/2I415/2 and (b) F49/2I415/2 transitions of Er3+ ions. The diagram is in a double logarithmic scale.
    (a) Spectral power of the UCL of SrF2:Er. (b) The CIE chromaticity diagram of SrF2:Er. The excitation power density is 63 W/cm2.
    Fig. 5. (a) Spectral power of the UCL of SrF2:Er. (b) The CIE chromaticity diagram of SrF2:Er. The excitation power density is 63W/cm2.
    Er3+concentration(mol.%)P (W/cm2)ΦUC(%)xyT (K)
    1.6250.34970.35484838
    630.34630.34704936
    3.4250.020.34980.35994858
    630.090.35150.36434814
    6.0250.100.35070.37224892
    630.160.35860.38884692
    8.8250.140.35270.42074961
    630.170.36390.42684695
    14.2250.170.36020.47954922
    630.280.36650.47534782
    18.3250.060.35460.41184887
    630.090.36270.39244589
    21.3250.030.34610.37655041
    630.040.35330.37124783
    Table 1. Quantum Yields, Chromaticity Coordinates x, y and Color Temperature T of SrF2:Er Phosphors
    A. A. Lyapin, S. V. Gushchin, A. S. Ermakov, S. V. Kuznetsov, P. A. Ryabochkina, V. Yu. Proydakova, V. V. Voronov, P. P. Fedorov, M. V. Chernov. Mechanisms and absolute quantum yield of upconversion luminescence of fluoride phosphors[J]. Chinese Optics Letters, 2018, 16(9): 091901
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