• Spectroscopy and Spectral Analysis
  • Vol. 42, Issue 2, 446 (2022)
Jiong YANG1、1; 2;, Zhi-li QIU1、1; 4; *;, Bo SUN3、3;, Xian-zi GU5、5;, Yue-feng ZHANG1、1;, Ming-kui GAO3、3;, Dong-zhou BAI1、1;, and Ming-jia CHEN1、1;
Author Affiliations
  • 11. Guangdong Key Laboratory of Geodynamic and Geological Hazards, Guangdong Key Laboratory of Geological Process and Mineral Resources Exploration, School of Earth Sciences and Engineering, Sun Yat-sen University, Guangzhou 510275, China
  • 33. Institution of Archaeology and Cultural Relic, Shandong Provence, Ji'nan 250012, China
  • 55. Shanghai Museum, Shanghai 200003, China
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    DOI: 10.3964/j.issn.1000-0593(2022)02-0446-08 Cite this Article
    Jiong YANG, Zhi-li QIU, Bo SUN, Xian-zi GU, Yue-feng ZHANG, Ming-kui GAO, Dong-zhou BAI, Ming-jia CHEN. Nondestructive Testing and Origin Traceability of Serpentine Jade From Dawenkou Culture Based on p-FTIR and p-XRF[J]. Spectroscopy and Spectral Analysis, 2022, 42(2): 446 Copy Citation Text show less
    Photos of representative samples(a), (b), (d), (e), (h): Unearthed serpentine jades; (c), (f): Taishan jade materials; (g): Unearthed ancient jade, 50×(reflected light); (i): Microphoto of magnetite in Taishan serpentine jade by reflected light
    Fig. 1. Photos of representative samples
    (a), (b), (d), (e), (h): Unearthed serpentine jades; (c), (f): Taishan jade materials; (g): Unearthed ancient jade, 50×(reflected light); (i): Microphoto of magnetite in Taishan serpentine jade by reflected light
    Infrared spectra of serpentine jade unearthed from Dawenkou culture (p-FTIR)(a): Ultrabasic type serpentine jades unearthed from Dawenkou site; (b): Dolomite type serpentine jade unearthed from Dawenkou culture;(c): Ultrabasic type serpentine Jades unearthed from the other Dawenkou culture sites; (d): Taishan jades
    Fig. 2. Infrared spectra of serpentine jade unearthed from Dawenkou culture (p-FTIR)
    (a): Ultrabasic type serpentine jades unearthed from Dawenkou site; (b): Dolomite type serpentine jade unearthed from Dawenkou culture;(c): Ultrabasic type serpentine Jades unearthed from the other Dawenkou culture sites; (d): Taishan jades
    Distribution of Cr-Cr/Ni values of serpentine jade from different producing (The data source is consistent with table 3 )
    Fig. 3. Distribution of Cr-Cr/Ni values of serpentine jade from different producing (The data source is consistent with table 3 )
    The position of unearthed serpentine jade and Taishan jade mine4: Yedian site at Zou county; 5: Dawenkou site in Taian city;13: Lingyanghe site at Jv county; 14: Dazhucun site at Jv county;21: Donghaiyu site in Rizhao city
    Fig. 4. The position of unearthed serpentine jade and Taishan jade mine
    4: Yedian site at Zou county; 5: Dawenkou site in Taian city;13: Lingyanghe site at Jv county; 14: Dazhucun site at Jv county;21: Donghaiyu site in Rizhao city
    序号编号遗址地器形矿物学基本特征
    1B型环泰安大汶口石环(玉镯)白色, 粒状变晶结构, 隐晶质结构, 质地细腻, 主要矿物蛇纹石, 黑色磁铁矿呈侵染状分布
    2M2004:1泰安大汶口石环(玉镯)白色, 隐晶质结构, 质地细腻
    3M1005:3泰安大汶口玉璜, 残灰黑色, 不透明, 柱状变晶结构, 主要矿物蛇纹石, 可见黑色磁铁矿, 磁性明显
    4M1006:4泰安大汶口石环(玉镯)灰白-灰绿色, 带蓝色色调, 隐晶质结构, 主要矿物蛇纹石
    5M1013:12泰安大汶口石环(玉镯)原色暗黑色, 表面白色, 柱状变晶结构, 主要矿物蛇纹石, 可见多条黑色磁铁矿条带, 磁性明显
    6无编号泰安大汶口玉璜(残损)绿褐色, 针状或柱状结构
    7M25:66莒县陵阳河鼓型珠白化
    8T11M26莒县大朱村玉环(残)白色, 完全白化, 隐晶质结构, 表面有溶蚀坑、 黑点
    9M11莒县陵阳河玉饰(四棱锥形)灰绿色, 粒状结构
    10M20:30莒县陵阳河石环灰白-灰绿色, 柱状、 粒状结构, 表面多溶蚀坑, 少量磁铁矿
    11T333-2B①:2日照东海峪石饰(长方形坠)灰绿色, 柱状结构, 少量磁铁矿
    12M49:04邹县野店石环(残)灰绿, 轻微受沁, 柱状结构, 少量磁铁矿
    13资002903M59邹县野店石纺轮(残损)白色, 细腻, 表面有溶蚀坑, 表面擦痕明显
    1492ZJT2062M9枣庄建新石镞白化, 细粒结构, 表面有溶蚀坑, 无使用痕迹
    15采集002418荏平尚庄石玦白色, 完全风化, 玦口平直
    Table 1. Characteristic description of serpentine jade unearthed from Dawenkou Culture
    样号遗址地SiO2TFe2O3MgOCrNiCr/Ni类型
    M1005:3泰安大汶口43.006.3038.253891 0720.41S型
    M1006:4泰安大汶口43.003.8038.009882 1240.44S型
    M1013泰安大汶口43.007.9323.001 0281 6320.69S型
    M2004:1泰安大汶口43.000.2531.50-46-D型
    B型环泰安大汶口43.000.3042.00-24-D型
    M25:66莒县陵阳河43.000.5536.00-32-D型
    T11M26莒县大朱村43.000.8040.00-30-D型
    M11莒县陵阳河43.001.6041.002401 4640.16S型
    M20:30莒县陵阳河43.004.3041.671 1432 8600.4S型
    T333-2B①:2日照东海峪43.002.634.001 0231 6130.63S型
    M49:04邹县野店43.002.2338.675112 0140.25S型
    Table 2. p-XRF results of major and trace elements in serpentine jades unearthed from Dawenkou culture(major element: Wt%; trace element: μg·g-1)
    现代玉料样号产地CrNiCr/Ni成因类型备注(测试方法)
    无损分析szt003山东泰安6931 7760.39S型p-XRF
    szt0041 4453 9400.37
    szt0054961 8230.27
    szt0066232 1810.29
    szt0102169840.22
    tsy12015702 2490.25
    tsy12039771 7200.57
    tsy12047402 7190.27
    tsy12054992 3810.21
    tsy12061 1622 5530.46
    ts054722 0420.23
    ts049282 1520.43
    ts031 7026 5150.26
    ts027551 9390.39
    ts011 0042 2500.45
    有损分析泰山玉山东泰安7972 2560.35S型ICP-MS
    鸳鸯玉甘肃武山2 2621 7601.29S型ICP-MS
    岫玉辽宁岫岩24967.73.68D型ICP-MS
    小寺沟玉河北小寺沟2.801.062.67D型ICP-MS
    淅川玉河南淅川1 3841 1751.18S型ICP-AES
    营口玉辽宁营口3.7421.50.17D型ICP-MS
    Table 3. Nondestructive and destructive test results of Cr, Ni and Cr/Ni value in serpentine jade from different habitats (μg·g-1)
    Jiong YANG, Zhi-li QIU, Bo SUN, Xian-zi GU, Yue-feng ZHANG, Ming-kui GAO, Dong-zhou BAI, Ming-jia CHEN. Nondestructive Testing and Origin Traceability of Serpentine Jade From Dawenkou Culture Based on p-FTIR and p-XRF[J]. Spectroscopy and Spectral Analysis, 2022, 42(2): 446
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