• Laser & Optoelectronics Progress
  • Vol. 58, Issue 8, 0830004 (2021)
Jin Zhang1, Hong Jiang1、*, Feng Liu2, and Bin Duan2
Author Affiliations
  • 1School of Investigation, People's Public Security University of China, Beijing 100038, China
  • 2Nanjing Jianzhi Instrument and Equipment Co., Ltd., Nanjing, Jiangsu 210049,China
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    DOI: 10.3788/LOP202158.0830004 Cite this Article Set citation alerts
    Jin Zhang, Hong Jiang, Feng Liu, Bin Duan. Differential Raman Spectroscopy Visualization and Rapid Identification of Shoe Sole Materials[J]. Laser & Optoelectronics Progress, 2021, 58(8): 0830004 Copy Citation Text show less
    Standard spectra of four types of samples and actual test sample spectra. (a)BR;(b)PVC;(c)NR;(d)EVA
    Fig. 1. Standard spectra of four types of samples and actual test sample spectra. (a)BR;(b)PVC;(c)NR;(d)EVA
    Clustering dendrogram
    Fig. 2. Clustering dendrogram
    CART classification tree model of the sample
    Fig. 3. CART classification tree model of the sample
    Index graph of the decision tree model whose target category is EVA
    Fig. 4. Index graph of the decision tree model whose target category is EVA
    CategoryMain ingredientSample serial number
    1EVA1#,3#,8#,9#,10#,11#,12#,14#,16#,17#,18#,20#,21#,22#,23#,24#,26#,27#,28#,29#,31#,32#,33#,35#,39#,43#,44#,45#,50#
    2NR2#,4#,7#,13#,19#,25#,30#,36#,46#,51#
    3PVC5#,34#,40#,41#,42#,49#
    4BR6#,15#,37#,38#,47#,48#
    Table 1. Classification results of 51 samples
    IngredientPeak/cm-1Vibration attribution
    EVA633-C=O stretching vibration
    814,1059,1127C-C stretching vibration
    1296-CH2 non-planar rocking vibration
    1370-CH3 symmetrical deformation vibration
    1435-C-H shear vibration in CH2
    NR294,349,516C-C-C stretching vibration
    1210C-C stretching vibration
    1261-CH2 in-plane deformation
    1369-CH3 and-CH2 in-plane deformation
    1652Trans C=C double bond stretching vibration
    PVC634,680C-Cl stretching vibration
    1082C-C stretching vibration
    1303C-H bond asymmetric swing vibration
    1436C-H bond bending vibration characteristic peak
    BR282,452C-C-C stretching vibration
    985C-C stretching vibration
    1437-C-H stretching vibration in CH2
    1652Trans C=C stretching vibration
    Table 2. Vibration group information of four types of samples
    Practical testing1234Classification accuracy/%
    129000100
    201000100
    30060100
    4001583.3
    Overall classification accuracy/%56.919.613.79.898.0
    Table 3. Decision tree classification results of four types of shoe sole samples
    Jin Zhang, Hong Jiang, Feng Liu, Bin Duan. Differential Raman Spectroscopy Visualization and Rapid Identification of Shoe Sole Materials[J]. Laser & Optoelectronics Progress, 2021, 58(8): 0830004
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