• Spectroscopy and Spectral Analysis
  • Vol. 41, Issue 1, 11 (2021)
Hao-ran LIU1、1、*, Qi-hou HU1、1, Wei TAN1、1, Wen-jing SU1、1, Yu-jia CHEN1、1, Yi-zhi ZHU1、1, and Jian-guo LIU1、1
Author Affiliations
  • 1[in Chinese]
  • 11. Institutes of Physical Science and Information Technology, Anhui University , Hefei 230601, China
  • show less
    DOI: 10.3964/j.issn.1000-0593(2021)01-0011-09 Cite this Article
    Hao-ran LIU, Qi-hou HU, Wei TAN, Wen-jing SU, Yu-jia CHEN, Yi-zhi ZHU, Jian-guo LIU. Study of the Urban NO2 Distribution and Emission Assessment Based on Mobile MAX-DOAS Observations[J]. Spectroscopy and Spectral Analysis, 2021, 41(1): 11 Copy Citation Text show less
    Schematic diagram of the experimental setup of the MAX-DOAS instrument
    Fig. 1. Schematic diagram of the experimental setup of the MAX-DOAS instrument
    The measurement routes taken and Hengshui city structure during this campaign
    Fig. 2. The measurement routes taken and Hengshui city structure during this campaign
    NO2 fitting case of a measurement spectrum
    Fig. 3. NO2 fitting case of a measurement spectrum
    NO2 time series (a) and correlation (b) between the stationary and mobile MAX-DOAS during the inter-comparison measurement
    Fig. 4. NO2 time series (a) and correlation (b) between the stationary and mobile MAX-DOAS during the inter-comparison measurement
    Spatial distribution of NO2 VCDs and the wind information during this campaignThe black arrow represents the wind field information, and the red five-pointed star represents the location of the stationary MA-DOAS
    Fig. 5. Spatial distribution of NO2 VCDs and the wind information during this campaign
    The black arrow represents the wind field information, and the red five-pointed star represents the location of the stationary MA-DOAS
    Comparison of NO2 between the stationary and mobile MAX-DOAS during the mobile measurement on February 9, 2018Yellow shadow: the time when the vehicle approaching the stationary MAX-DOAS;Gray shadow: time when the vehicle reached the eastern region of Hengshui
    Fig. 6. Comparison of NO2 between the stationary and mobile MAX-DOAS during the mobile measurement on February 9, 2018
    Yellow shadow: the time when the vehicle approaching the stationary MAX-DOAS;Gray shadow: time when the vehicle reached the eastern region of Hengshui
    Spatial distribution of tropospheric mean NO2 VCDs measured by OMI satellite from 16th Jan 2018 to 15th Feb 2018. The 0~100 m 24 h backward trajectories of air masses are also shown to illustrate the transportation of atmospheric NO2 during the measurement campaignThe green, brown and pink lines indicate the clusters in different directions
    Fig. 7. Spatial distribution of tropospheric mean NO2 VCDs measured by OMI satellite from 16th Jan 2018 to 15th Feb 2018. The 0~100 m 24 h backward trajectories of air masses are also shown to illustrate the transportation of atmospheric NO2 during the measurement campaign
    The green, brown and pink lines indicate the clusters in different directions
    实验类型日期时间天气风向风速行驶方向
    平行对比实验2018.01.3010:10—13:40晴—多云西风1~2级-
    走航观测实验2018.01.2410:50—11:41微风顺时针
    2018.01.2413:09—14:06逆时针
    2018.02.099:54—11:00晴—多云西北风3~4级逆时针
    2018.02.0911:33—12:38顺时针
    Table 1. Driving direction, wind field and weather conditions during this campaign
    参数参数设置
    Wavelength range338~370 nm
    NO2Vandaele et al. (1998), 220 K, 294 K, I0-correction* (SCD of 1017 molecules·cm-2)
    HCHOMeller and Moortgat (2000), 297 K
    O3Serdyuchenko et al. (2014), 223 K, 243 K, I0-correction* (SCD of 1020 molecules·cm-2)
    O4Thalman and Volkamer (2013), 293 K
    BrOFleischmann et al. (2004), 223 K
    RingRing spectra calculated with QDOAS according to Chance and Spurr (1997)
    Polynomial degreeOrder 5
    Intensity offsetConstant
    Wavelength calibrationBased on a high resolution solar reference spectrum (SAO2010 solar spectra)
    Table 2. Parameter settings used for NO2 DSCD retrieval
    日期时间浓度范围平均值±标准差东部平均值±标准差西部平均值±标准差
    2018.01.2410:50—11:4116.70~50.7928.45±9.2634.84±8.1821.52±3.69
    13:09~14:069.21~56.3330.20±1.0333.81±8.3624.88±1.07
    2018.02.099:54—11:0020.18~44.4227.77±4.3628.12±4.0327.12±4.91
    11:33~12:380.89~40.3222.42±5.7024.22±5.8121.13±3.69
    Table 3. NO2 Mean VCDs of each area of Hengshui during the mobile MAX-DOAS measurement (1015 molecule·cm-2)
    日期时间输出输入城市
    排放
    输入/
    输出/%
    排放/
    输出/%
    2018.01.2410:50—11:411.761.660.1094.325.68
    2018.01.2413:09—14:061.541.430.1192.867.14
    2018.02.099:54—11:0022.4021.540.8696.163.84
    Table 4. NO2 emissions, input and output flux from outer route of Hengshui (1024 molecs-1)
    Hao-ran LIU, Qi-hou HU, Wei TAN, Wen-jing SU, Yu-jia CHEN, Yi-zhi ZHU, Jian-guo LIU. Study of the Urban NO2 Distribution and Emission Assessment Based on Mobile MAX-DOAS Observations[J]. Spectroscopy and Spectral Analysis, 2021, 41(1): 11
    Download Citation