• Spectroscopy and Spectral Analysis
  • Vol. 42, Issue 10, 3017 (2022)
Gui-jun ZHU*, Gan-zhen WANG, Jun PENG*;, Zong-ping TIAN, and Zhi-hua HOU
Author Affiliations
  • Hunan Province Geological Testing Institute, Changsha 410007, China
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    DOI: 10.3964/j.issn.1000-0593(2022)10-3017-07 Cite this Article
    Gui-jun ZHU, Gan-zhen WANG, Jun PENG, Zong-ping TIAN, Zhi-hua HOU. The Mineralogical and Spectroscopic Characteristics of Phosphohedyphane From Chenzhou of Hunan Province[J]. Spectroscopy and Spectral Analysis, 2022, 42(10): 3017 Copy Citation Text show less
    Picture of experimental samples
    Fig. 1. Picture of experimental samples
    Partial microview of samples
    Fig. 2. Partial microview of samples
    Infrared spectra of samples
    Fig. 3. Infrared spectra of samples
    Raman spectra of samples
    Fig. 4. Raman spectra of samples
    Powder XRD patterns of samples 9 and 10
    Fig. 5. Powder XRD patterns of samples 9 and 10
    编号原石质量
    /g
    洗后质量
    /g
    水中质量
    /g
    相对密度
    /(g·cm3)
    21.0841.0750.2065.218
    42.0612.0420.3835.331
    93.8862.5670.5204.937
    106.5935.1961.1584.487
    Table 1. Relative gravity of samples
    RRUFF ID产 地拉曼特征峰位/cm-1
    R060733智利卡皮塔娜-/-/-398/430555/593831929/9721 069/-
    R110037美 加州-/-/198397/428556/588-928/9661065/-
    a斯洛伐克98/156/-401/434559/595830934/9721 064/-
    b斯洛伐克98/-/-401/430557/595830932/-1 059/-
    c斯洛伐克98/-/196400/432557/594830933/9711 060/-
    d斯洛伐克98/-/-399/429554/594830933/-1 058/-
    e斯洛伐克98/-/-401/430559/595830933/-1 057/-
    2郴州-/170/206402/426558/586822936/9761 058/1 090
    4郴州-/170/208400/426558/586822936/9761 058/1 090
    9郴州-/172/214402/426558/586826938/9781 060/1 092
    10郴州-/170/188398/422558/580820932/9701 054/-
    Table 2. Raman peak positions of phosphohedyphanes from different localities
    编号MgOAl2O3SiO2P2O5ClK2OCaOCr2O3MnOFe2O3NiOCuOZnOReO2PbO
    91.018-1.14223.731.3540.04726.910.0160.0320.0970.0160.0810.5251.17443.27
    101.1530.4522.32921.721.3550.06825.18-0.0830.361-0.1300.4721.04244.92
    Table 3. Results of EDXRF analysis of sample 9 and 10
    9号样品10号样品
    dI/I0hkldI/I0hkldI/I0hkldI/I0hkl
    8.336 559.11002.782 815.13008.344 569.21002.794 922.4300
    4.174 019.62002.350 48.21224.200 026.32002.352 87.4122
    3.974 436.41112.086 710.14003.985 230.61112.087 214.1400
    3.521 517.70021.987 78.12223.524 311.30021.990 38.8222
    3.248 511.51021.883 711.82133.243 810.81021.884 89.9213
    3.155 330.02101.847 110.63213.169 931.42101.847 89.4321
    2.878 21002111.821 69.31402.883 71002111.827 211.3140
    2.842 718.61121.796 310.24022.862 619.81121.797 611.9402
    Table 4. X-Ray powder diffraction data of sample 9 and 10
    磷氯铅矿拉曼R05008590/107/177392/409552/574818/851919/9481 019/1 129
    氟-铅磷灰石拉曼9号样品-/176/216402/428558/590826/938/9781 060/1 092
    氟-铅磷灰石红外9号样品546/566/588/847940/1 015/1 099
    磷氯铅矿红外[10]542/573/--/-924/9691 027/-
    Table 5. Infrared and Raman peak positions of pyromorphites and fluorphosphohedyphane
    Gui-jun ZHU, Gan-zhen WANG, Jun PENG, Zong-ping TIAN, Zhi-hua HOU. The Mineralogical and Spectroscopic Characteristics of Phosphohedyphane From Chenzhou of Hunan Province[J]. Spectroscopy and Spectral Analysis, 2022, 42(10): 3017
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