• Journal of Inorganic Materials
  • Vol. 36, Issue 9, 919 (2021)
Yinben GUO1, Zixi CHEN1, Hongzhi WANG2, and Qinghong ZHANG3、*
Author Affiliations
  • 11. College of Materials Engineering, Shanghai University of Engineering Science, Shanghai 201620, China
  • 22. State Key Laboratory for Modification of Chemical Fibers and Polymer Materials, College of Materials Science and Engineering, Donghua University, Shanghai 201620, China
  • 33. Engineering Research Center of Advanced Glasses Manufacturing Technology, Ministry of Education, Donghua University, Shanghai 201620, China
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    DOI: 10.15541/jim20200742 Cite this Article
    Yinben GUO, Zixi CHEN, Hongzhi WANG, Qinghong ZHANG. Progress of Inorganic Filler Based Composite Films for Triboelectric Nanogenerators[J]. Journal of Inorganic Materials, 2021, 36(9): 919 Copy Citation Text show less
    Schematic diagram of various composite films and devices for TENGs[20,21,22,23,24,25,26,27]
    1. Schematic diagram of various composite films and devices for TENGs[20,21,22,23,24,25,26,27]
    Schematic diagram of rGONRs /PVDF based TENG, 3D-AFM image of the rGONRs/PVDF thin film, and output voltage of the rGONRs/PVDF based TENG for 500 cycles (a)[20], schematic diagram of TiO2/PDMS sponge based TENG, schematic of organic containment degradation by photocatalyst NPs in TiO2/PDMS sponge (b)[21], and SEM images of hierarchical structures for SiO2/P(VDF-TrFE) composite fabricated by electrospinning process, and the surface potentials of pure P(VDF-TrFE) film (blue) and SiO2/P(VDF-TrFE) composite film (red) (c)[40] (Colorful figures are available on website)
    2. Schematic diagram of rGONRs /PVDF based TENG, 3D-AFM image of the rGONRs/PVDF thin film, and output voltage of the rGONRs/PVDF based TENG for 500 cycles (a)[20], schematic diagram of TiO2/PDMS sponge based TENG, schematic of organic containment degradation by photocatalyst NPs in TiO2/PDMS sponge (b)[21], and SEM images of hierarchical structures for SiO2/P(VDF-TrFE) composite fabricated by electrospinning process, and the surface potentials of pure P(VDF-TrFE) film (blue) and SiO2/P(VDF-TrFE) composite film (red) (c)[40] (Colorful figures are available on website)
    Dielectric constants of the cellulose/ BaTiO3 aerogel paper with different BaTiO3 contents (the mass ratios of BaTiO3 in C/BT-1, C/BT-3 and C/BT-5 were 50%, 75% and 83.3%, respectively) and schematic image of wireless application of the TENG(a)[22], dielectric constants and charge densities of the BaTiO3/PVDF nanocomposite films with different BaTiO3 volume fractions (b)[23], and SEM image of ZnSnO3@PDMS composite film, and output currents and voltages of the corresponding TENGs with different ZnSnO3 contents (c)[24] (Colorful figures are available on website)
    3. Dielectric constants of the cellulose/ BaTiO3 aerogel paper with different BaTiO3 contents (the mass ratios of BaTiO3 in C/BT-1, C/BT-3 and C/BT-5 were 50%, 75% and 83.3%, respectively) and schematic image of wireless application of the TENG(a)[22], dielectric constants and charge densities of the BaTiO3/PVDF nanocomposite films with different BaTiO3 volume fractions (b)[23], and SEM image of ZnSnO3@PDMS composite film, and output currents and voltages of the corresponding TENGs with different ZnSnO3 contents (c)[24] (Colorful figures are available on website)
    KPFM images (a) and power densities (b) of P(VDF-TrFE), PDMS, 30BTO and 30CCTO films[46], electrical field distributions (finite-element simulation) (c) and power densities as a function of the external resistance (d) of the devices based on PDMS and PDMS@F-MOF[49]
    4. KPFM images (a) and power densities (b) of P(VDF-TrFE), PDMS, 30BTO and 30CCTO films[46], electrical field distributions (finite-element simulation) (c) and power densities as a function of the external resistance (d) of the devices based on PDMS and PDMS@F-MOF[49]
    Internal resistances and output powers of PDMS@GPs composite membranes with different GP contents with inset showing structural schematic of corresponding TENG device (a)[25], schematic image of PDMS@GO@SDS composite film and the output voltages of different TENGs (b)[50], comparison of charge densities for TENGs : pure Nylon-11 and PVDF-TrFE (black), Nylon-11@MoS2 and P(VDF-TrFE)@MoS2 composite films in non-poled state (red) and poled state (blue) (c)[51], comparison of charges for PVDF and PVDF/TOML nanocomposite films based TENGs with inset showing the picture of PVDF/TOML nanocomposite film (d)[26], optical image of the CNF/phosphorene hybrid paper (e), and the comparison of voltages between pure CNF based TENG and CNF/ phosphorene hybrid paper based TENG (f)[27]
    5. Internal resistances and output powers of PDMS@GPs composite membranes with different GP contents with inset showing structural schematic of corresponding TENG device (a)[25], schematic image of PDMS@GO@SDS composite film and the output voltages of different TENGs (b)[50], comparison of charge densities for TENGs : pure Nylon-11 and PVDF-TrFE (black), Nylon-11@MoS2 and P(VDF-TrFE)@MoS2 composite films in non-poled state (red) and poled state (blue) (c)[51], comparison of charges for PVDF and PVDF/TOML nanocomposite films based TENGs with inset showing the picture of PVDF/TOML nanocomposite film (d)[26], optical image of the CNF/phosphorene hybrid paper (e), and the comparison of voltages between pure CNF based TENG and CNF/ phosphorene hybrid paper based TENG (f)[27]
    Illustration of the fabrication process of a book-shaped TENG (a), normalized surface potential decay of PVDF/mSiO2 nanofibers with different concentrations of mSiO2 (b)[55]; energy landscapes for (injected) charge carriers for SiO2-FP before and during charging, and surface potential decays at elevated temperatures (c), electric field distributions during charging for two competing scenarios with injected charge residing at the aqueous-FP interface (I), and injected charge residing at the FP-oxide interface (II) (d)[57]
    6. Illustration of the fabrication process of a book-shaped TENG (a), normalized surface potential decay of PVDF/mSiO2 nanofibers with different concentrations of mSiO2 (b)[55]; energy landscapes for (injected) charge carriers for SiO2-FP before and during charging, and surface potential decays at elevated temperatures (c), electric field distributions during charging for two competing scenarios with injected charge residing at the aqueous-FP interface (I), and injected charge residing at the FP-oxide interface (II) (d)[57]
    FillerMatrixOptimal fillers ratioDielectric constant Shape/SizeIncreased percentage of output/% Ref.
    wt%vol%
    rGONRsPVDF97Nanoribbon200 (Voltage)[20]
    TiO2PDMS0.05Nanopaticle[21]
    SiO2P(VDF-TrFE)30Nanopaticle (D=10-20 nm) 300 (Voltage)[40]
    BaTiO3Cellulose paper16.76.25Nanopaticle (D=200 nm) 300 (Power)[22]
    BaTiO3PVDF11.2525Nanopaticle (D=100 nm) 650 (Voltage)[23]
    ZnSnO3PDMS6Nanocube620 (Current)[24]
    CaCu3Ti4O12PDMS30Nanopaticle1000 (Power)[46]
    KUAST-8PDMS0.54.23Nanopaticle1100 (Power)[49]
    Graphite particlePDMS33Nanopaticle (D=20-40 nm) 260 (Power)[25]
    GOPDMS16.7Nanosheet300 (Voltage)[50]
    MoS2Nylon-11/P(VDF-TrFE)Nanosheet800 (Power)[51]
    Monolayer titaniaPVDF1.511.51Thickness=1.2 nm5000 (Power)[26]
    PhosphoreneCNF0.2Nanosheet4600 (Power)[27]
    Hydrophobic SiO2PVDF0.8Nanopaticle530 (Power)[55]
    SiO2Thermoplastic nanofiber membranes Nanopaticle[57]
    Table 1. Fillers used in composite materials for TENGs
    Yinben GUO, Zixi CHEN, Hongzhi WANG, Qinghong ZHANG. Progress of Inorganic Filler Based Composite Films for Triboelectric Nanogenerators[J]. Journal of Inorganic Materials, 2021, 36(9): 919
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