Author Affiliations
11. College of Materials Engineering, Shanghai University of Engineering Science, Shanghai 201620, China22. State Key Laboratory for Modification of Chemical Fibers and Polymer Materials, College of Materials Science and Engineering, Donghua University, Shanghai 201620, China33. Engineering Research Center of Advanced Glasses Manufacturing Technology, Ministry of Education, Donghua University, Shanghai 201620, Chinashow less
1. Schematic diagram of various composite films and devices for TENGs
[20,21,22,23,24,25,26,27] 2. Schematic diagram of rGONRs /PVDF based TENG, 3D-AFM image of the rGONRs/PVDF thin film, and output voltage of the rGONRs/PVDF based TENG for 500 cycles (a)
[20], schematic diagram of TiO
2/PDMS sponge based TENG, schematic of organic containment degradation by photocatalyst NPs in TiO
2/PDMS sponge (b)
[21], and SEM images of hierarchical structures for SiO
2/P(VDF-TrFE) composite fabricated by electrospinning process, and the surface potentials of pure P(VDF-TrFE) film (blue) and SiO
2/P(VDF-TrFE) composite film (red) (c)
[40]
(Colorful figures are available on website)
3. Dielectric constants of the cellulose/ BaTiO
3 aerogel paper with different BaTiO
3 contents (the mass ratios of BaTiO
3 in C/BT-1, C/BT-3 and C/BT-5 were 50%, 75% and 83.3%, respectively) and schematic image of wireless application of the TENG(a)
[22], dielectric constants and charge densities of the BaTiO
3/PVDF nanocomposite films with different BaTiO
3 volume fractions (b)
[23], and SEM image of ZnSnO
3@PDMS composite film, and output currents and voltages of the corresponding TENGs with different ZnSnO
3 contents (c)
[24]
(Colorful figures are available on website)
4. KPFM images (a) and power densities (b) of P(VDF-TrFE), PDMS, 30BTO and 30CCTO films
[46], electrical field distributions (finite-element simulation) (c) and power densities as a function of the external resistance (d) of the devices based on PDMS and PDMS@F-MOF
[49] 5. Internal resistances and output powers of PDMS@GPs composite membranes with different GP contents with inset showing structural schematic of corresponding TENG device (a)
[25], schematic image of PDMS@GO@SDS composite film and the output voltages of different TENGs (b)
[50], comparison of charge densities for TENGs : pure Nylon-11 and PVDF-TrFE (black), Nylon-11@MoS
2 and P(VDF-TrFE)@MoS
2 composite films in non-poled state (red) and poled state (blue) (c)
[51], comparison of charges for PVDF and PVDF/TOML nanocomposite films based TENGs with inset showing the picture of PVDF/TOML nanocomposite film (d)
[26], optical image of the CNF/phosphorene hybrid paper (e), and the comparison of voltages between pure CNF based TENG and CNF/ phosphorene hybrid paper based TENG (f)
[27] 6. Illustration of the fabrication process of a book-shaped TENG (a), normalized surface potential decay of PVDF/mSiO
2 nanofibers with different concentrations of mSiO
2 (b)
[55]; energy landscapes for (injected) charge carriers for SiO
2-FP before and during charging, and surface potential decays at elevated temperatures (c), electric field distributions during charging for two competing scenarios with injected charge residing at the aqueous-FP interface (I), and injected charge residing at the FP-oxide interface (II) (d)
[57] Filler | Matrix | Optimal fillers ratio | Dielectric
constant
| Shape/Size | Increased percentage
of output/%
| Ref. |
---|
wt% | vol% |
---|
rGONRs | PVDF | 97 | — | — | Nanoribbon | 200 (Voltage) | [20] | TiO2 | PDMS | 0.05 | — | — | Nanopaticle | — | [21] | SiO2 | P(VDF-TrFE) | 30 | — | — | Nanopaticle (D=10-20 nm)
| 300 (Voltage) | [40] | BaTiO3 | Cellulose paper | 16.7 | — | 6.25 | Nanopaticle (D=200 nm)
| 300 (Power) | [22] | BaTiO3 | PVDF | — | 11.25 | 25 | Nanopaticle (D=100 nm)
| 650 (Voltage) | [23] | ZnSnO3 | PDMS | 6 | — | — | Nanocube | 620 (Current) | [24] | CaCu3Ti4O12 | PDMS | 30 | — | — | Nanopaticle | 1000 (Power) | [46] | KUAST-8 | PDMS | 0.5 | — | 4.23 | Nanopaticle | 1100 (Power) | [49] | Graphite particle | PDMS | 3 | — | 3 | Nanopaticle (D=20-40 nm)
| 260 (Power) | [25] | GO | PDMS | — | 16.7 | — | Nanosheet | 300 (Voltage) | [50] | MoS2 | Nylon-11/P(VDF-TrFE) | — | — | — | Nanosheet | 800 (Power) | [51] | Monolayer titania | PVDF | 1.5 | — | 11.51 | Thickness=1.2 nm | 5000 (Power) | [26] | Phosphorene | CNF | 0.2 | — | — | Nanosheet | 4600 (Power) | [27] | Hydrophobic SiO2 | PVDF | 0.8 | — | — | Nanopaticle | 530 (Power) | [55] | SiO2 | Thermoplastic nanofiber
membranes
| — | — | — | Nanopaticle | — | [57] |
|
Table 1. Fillers used in composite materials for TENGs