• Acta Optica Sinica
  • Vol. 39, Issue 1, 0130001 (2019)
Hongqiu Zhu*, Junming Chen, Chunhua Yang*, Yonggang Li, and Juan Gong
Author Affiliations
  • School of Information Science and Engineering, Central South University, Changsha, Hunan 410083, China
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    DOI: 10.3788/AOS201939.0130001 Cite this Article Set citation alerts
    Hongqiu Zhu, Junming Chen, Chunhua Yang, Yonggang Li, Juan Gong. Spectral Pretreatment Method for Detection of Trace Cu 2+ and Co 2+ in Zinc Solution [J]. Acta Optica Sinica, 2019, 39(1): 0130001 Copy Citation Text show less
    Spectra analysis of three single ions. (a) Original spectra of single ions; (b) ion proportion at wavelength point
    Fig. 1. Spectra analysis of three single ions. (a) Original spectra of single ions; (b) ion proportion at wavelength point
    Spectral signals with different orders. (a) Original spectral signals; (b) original spectral filtering signals; (c) first-order spectral filtering signals; (d) second-order spectral filtering signals
    Fig. 2. Spectral signals with different orders. (a) Original spectral signals; (b) original spectral filtering signals; (c) first-order spectral filtering signals; (d) second-order spectral filtering signals
    Relationship among coverage degrees and orders for different ions. (a) Co2+; (b) Cu2+
    Fig. 3. Relationship among coverage degrees and orders for different ions. (a) Co2+; (b) Cu2+
    Fitting plot of order and distortion degree with wavelet filtering-fractional differentiation method
    Fig. 4. Fitting plot of order and distortion degree with wavelet filtering-fractional differentiation method
    Non-inferior solution sets of different ions. (a) Co2+; (b) Cu2+
    Fig. 5. Non-inferior solution sets of different ions. (a) Co2+; (b) Cu2+
    Spectra with different differential orders. (a) Original spectra; (b) first-order spectra; (c) second-order spectra; (d) 1.4-order spectra; (e) 1.5-order spectra
    Fig. 6. Spectra with different differential orders. (a) Original spectra; (b) first-order spectra; (c) second-order spectra; (d) 1.4-order spectra; (e) 1.5-order spectra
    Wavelength point selection based on multi-index fusion feature after pretreatment
    Fig. 7. Wavelength point selection based on multi-index fusion feature after pretreatment
    Errors between predicted and actual mass concentrations of different ions. (a) Co2+; (b) Cu2+
    Fig. 8. Errors between predicted and actual mass concentrations of different ions. (a) Co2+; (b) Cu2+
    ParameterValue
    Mass concentration of nitroso-R-salt /(g·L-1)0.04
    pH of NaAc-HAc5.5
    Mass concentration of Cu2+ /(mg·L-1)10
    Mass concentration of Co2+ /(mg·L-1)10
    Mass concentration of Zn2+ /(g·L-1)50
    Table 1. Selection of reagent system
    IonsIndexOriginal spectrumFirst-order differentiationSecond-order differentiationMOPSO
    Co2+Coverage degree0.74810.70820.75060.6808
    Distortion degree0.58690.65740.98240.2498
    Cu2+Coverage degree10.97010.85290.9252
    Distortion degree0.58690.65740.98240.5707
    Table 2. Coverage degree and distortion degree with differentiation methods with different orders
    IonsIndexOriginal spectraFirst-order differentiationSecond-order differentiationFractional differentiation
    Co2+RMSEP0.29630.12190.13730.1175
    R20.90980.98400.97960.9866
    Maximum relative error /%161.5319.7125.8315.54
    Mean relative error /%26.806.147.365.25
    Qualified rate /%37.581.257593.75
    Cu2+RMSEP0.08100.06660.19980.0679
    R20.99220.99430.95130.9939
    Maximum relative error /%22.5313.96134.808.53
    Mean relative error /%6.234.3620.723.26
    Qualified rate /%7593.7543.75100
    Table 3. Comparison of results by different pretreatments
    Hongqiu Zhu, Junming Chen, Chunhua Yang, Yonggang Li, Juan Gong. Spectral Pretreatment Method for Detection of Trace Cu 2+ and Co 2+ in Zinc Solution [J]. Acta Optica Sinica, 2019, 39(1): 0130001
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