• Chinese Optics Letters
  • Vol. 19, Issue 1, 011901 (2021)
Danyang Shen1、2, Jing Qian1、2, Chengwei Wang1、2, Guande Wang1、2, Xuehui Wang3, and Quanzhong Zhao1、2、*
Author Affiliations
  • 1State Key Laboratory of High Field Laser Physics, Shanghai Institute of Optics and Fine Mechanics, Chinese Academy of Sciences, Shanghai 201800, China
  • 2Center of Materials Science and Optoelectronics Engineering, University of Chinese Academy of Sciences, Beijing 100049, China
  • 3Technology Center, Huagong Laser Engineering Co., Ltd., Wuhan 430000, China
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    DOI: 10.3788/COL202119.011901 Cite this Article Set citation alerts
    Danyang Shen, Jing Qian, Chengwei Wang, Guande Wang, Xuehui Wang, Quanzhong Zhao. Facile preparation of silver nanoparticles in bulk silicate glass by high-repetition-rate picosecond laser pulses[J]. Chinese Optics Letters, 2021, 19(1): 011901 Copy Citation Text show less
    Photographs of Ag+-doped silicate glasses with a rectangular region processed by a picosecond laser at an average power of 1.1 W and a scanning speed of 200 µm/s.
    Fig. 1. Photographs of Ag+-doped silicate glasses with a rectangular region processed by a picosecond laser at an average power of 1.1 W and a scanning speed of 200 µm/s.
    Ag atoms dissolve in the glass network by breaking the Sb-O-Sb bond.
    Fig. 2. Ag atoms dissolve in the glass network by breaking the Sb-O-Sb bond.
    Absorption spectra of five glass samples (a) before and (b) after picosecond laser irradiation; (c) difference absorbance after picosecond laser irradiation.
    Fig. 3. Absorption spectra of five glass samples (a) before and (b) after picosecond laser irradiation; (c) difference absorbance after picosecond laser irradiation.
    (a) Experimental difference spectrum and theoretical fitting curve of Ag nanoparticle SPR of S5; (b) TEM image of Ag nanoparticles precipitated in the laser-irradiated zone of S5.
    Fig. 4. (a) Experimental difference spectrum and theoretical fitting curve of Ag nanoparticle SPR of S5; (b) TEM image of Ag nanoparticles precipitated in the laser-irradiated zone of S5.
    Optical micrographs of scanned lines by picosecond laser pulses at different processing speeds of 16, 32, 64,…, 1024 µm/s. The inset shows the color comparison of the laser fabricated region in S5 at speeds of 200 and 1000 µm/s.
    Fig. 5. Optical micrographs of scanned lines by picosecond laser pulses at different processing speeds of 16, 32, 64,…, 1024 µm/s. The inset shows the color comparison of the laser fabricated region in S5 at speeds of 200 and 1000 µm/s.
    (a) Normalized Z-scan transmittance of S5 at I0=4.22 TW/cm2; (b) the dependence of Z-scan valley transmittance on incident laser intensity I0.
    Fig. 6. (a) Normalized Z-scan transmittance of S5 at I0=4.22TW/cm2; (b) the dependence of Z-scan valley transmittance on incident laser intensity I0.
    SampleS1S2S3S4S5S6
    Concentration of Ag (%)00.010.040.160.642.56
    Table 1. Concentrations of Doped-Ag+ in the Silicate Glasses
    Danyang Shen, Jing Qian, Chengwei Wang, Guande Wang, Xuehui Wang, Quanzhong Zhao. Facile preparation of silver nanoparticles in bulk silicate glass by high-repetition-rate picosecond laser pulses[J]. Chinese Optics Letters, 2021, 19(1): 011901
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