• Spectroscopy and Spectral Analysis
  • Vol. 42, Issue 2, 568 (2022)
Yan JIANG1,1;, Ling-lin MAO3,3;, Jun WU3,3;, Xi YANG4,4;..., Lu-lu DAI1,1; and Ming-xing YANG1,1; 2; *;|Show fewer author(s)
Author Affiliations
  • 11. Gemmological Institute, China University of Geosciences, Wuhan 430074, China
  • 33. Suichang County Cultural Relics Management Committee Office, Suichang 323300, China
  • 44. Hangzhou Institute of Cultural Relics and Archaeology, Hangzhou 310007, China
  • show less
    DOI: 10.3964/j.issn.1000-0593(2022)02-0568-07 Cite this Article
    Yan JIANG, Ling-lin MAO, Jun WU, Xi YANG, Lu-lu DAI, Ming-xing YANG. Scientific Analysis of Five Turquoise Beads Unearthed From Haochuan Cemetery in Suichang, Zhejiang[J]. Spectroscopy and Spectral Analysis, 2022, 42(2): 568 Copy Citation Text show less
    Five turquoise beads unearthed from tomb No.M52 (a—e); Turquoise in Qingu area, Hubei (f); Turquoise in Bijiashan area, Anhui (g)
    Fig. 1. Five turquoise beads unearthed from tomb No.M52 (a—e); Turquoise in Qingu area, Hubei (f); Turquoise in Bijiashan area, Anhui (g)
    Infrared reflectance spectra of five Haochuan turquoise beads and Hubei and Anhui turquoise samples (a); Infrared Spectra(3 600~3 200 cm-1) of turquoise samples from Haochuan Cemetery (b); Infrared Spectra (3 600~3 200 cm-1) of turquoise samples from Haochuan Cemetery and lacquerware sample from Liangzhu[13](c); Infrared spectra (1 200~400 cm-1) of turquoise samples from Haochuan Cemetery(d)
    Fig. 2. Infrared reflectance spectra of five Haochuan turquoise beads and Hubei and Anhui turquoise samples (a); Infrared Spectra(3 600~3 200 cm-1) of turquoise samples from Haochuan Cemetery (b); Infrared Spectra (3 600~3 200 cm-1) of turquoise samples from Haochuan Cemetery and lacquerware sample from Liangzhu[13](c); Infrared spectra (1 200~400 cm-1) of turquoise samples from Haochuan Cemetery(d)
    M52-2 surface etch pits (a); M52-8 surface polishing surface can be seen with polished small surface (b)
    Fig. 3. M52-2 surface etch pits (a); M52-8 surface polishing surface can be seen with polished small surface (b)
    Drilling situation of five turquoise beads
    Fig. 4. Drilling situation of five turquoise beads
    编号尺寸/cm重量/g光泽形状
    M52-2直径0.5~0.7、 长0.90.50油脂光泽鼓形
    M52-3直径0.8、 长0.90.95油脂光泽鼓形
    M52-4直径0.8、 长10.90油脂光泽鼓形
    M52-5直径0.6~0.7、 长0.90.55油脂光泽鼓形
    M52-8直径0.9、 长11.10油脂光泽鼓形
    Table 1. Basic characteristics of five turquoise beads in Haochuan Cemetery
    官能团/cm-1M52-2M52-3M52-4M52-5M52-8
    ν(OH)伸缩振动3 5133 5073 5073 5093 514
    3 4673 4673 4673 4673 468
    ν(MFe, Cu—H2O)伸缩振动3 0583 0493 0703 0603 058
    ν3(PO4)伸缩振动1 1311 1421 1421 1351 141
    1 0671 0641 0691 0681 066
    1 0141 0141 0141 0141 015
    δ(OH)弯曲振动837837837837838
    ν4(PO4)弯曲振动651655656653656
    573590589586589
    487488490488488
    430431
    ν(—CH2—)伸缩振动2 8902 8882 8942 8872 886
    2 8382 8382 8382 8392 839
    ν(C=C)伸缩振动1 5521 5531 5541 5531 554
    1 5031 5031 503
    ν(—CH2—)伸缩振动变形1 4511 4521 4521 4521 452
    Table 2. Assignments of absorption peaks in infrared spectra of five turquoise beads in Haochuan Cemetery
    Al2O3/
    %
    P2O5/
    %
    SiO2/
    %
    CuO/
    %
    FeO/
    %
    K/
    (mg·kg-1)
    Ca/
    (mg·kg-1)
    Zn/
    (mg·kg-1)
    Ba/
    (mg·kg-1)
    Cr/
    (mg·kg-1)
    Sr/
    (mg·kg-1)
    M52-237.3842.587.209.8302.0731 748728.51 5401 913208.137.60
    M52-337.0443.626.6810.851.079937.6548.51 1512 504213.336.70
    M52-437.2844.025.8710.811.131947.6648.51 3993 570166.534.20
    M52-537.2042.287.9009.8301.9271 465613.51 4182 110156.231.00
    M52-837.2943.196.88010.691.163970.4627.81 4172 625156.045.40
    Table 3. Determination of chemical composition of five turquoise beads in Haochuan Cemetery
    Yan JIANG, Ling-lin MAO, Jun WU, Xi YANG, Lu-lu DAI, Ming-xing YANG. Scientific Analysis of Five Turquoise Beads Unearthed From Haochuan Cemetery in Suichang, Zhejiang[J]. Spectroscopy and Spectral Analysis, 2022, 42(2): 568
    Download Citation