• Journal of Inorganic Materials
  • Vol. 35, Issue 8, 939 (2020)
Bo ZHANG1, Ning ZHANG1, Jianhua YANG2, Jiancheng LAN2, and Jinqu WANG1、2、*
Author Affiliations
  • 1School of Petroleum and Chemical Engineering, Dalian University of Technology, Panjin124221, China
  • 2Institute of Adsorption and Inorganic Membrane, State Key Laboratory of Fine Chemicals, Dalian University of Technology, Dalian 116024, China
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    DOI: 10.15541/jim20190469 Cite this Article
    Bo ZHANG, Ning ZHANG, Jianhua YANG, Jiancheng LAN, Jinqu WANG. High Performance a&b Oriented T Zeolite Membrane by a Two-stage Crystallization Synthesis[J]. Journal of Inorganic Materials, 2020, 35(8): 939 Copy Citation Text show less
    SEM images of α-Al2O3 support photographed from surface (a) and cross section (b), large seeds (c), small seeds (d), modified by large seeds photographed from surface (e) and cross section (f), and the small seed layer photographed from surface (g) and cross section (h)
    1. SEM images of α-Al2O3 support photographed from surface (a) and cross section (b), large seeds (c), small seeds (d), modified by large seeds photographed from surface (e) and cross section (f), and the small seed layer photographed from surface (g) and cross section (h)
    XRD patterns of large seeds (a) and small seeds (b)
    2. XRD patterns of large seeds (a) and small seeds (b)
    SEM images of T-type zeolite membranes after first-step crystallization prepared at different first-step crystallization temperatures
    3. SEM images of T-type zeolite membranes after first-step crystallization prepared at different first-step crystallization temperatures
    SEM images of T-type zeolite membranes after two-step crystallizations prepared at different first-step crystallization temperature
    4. SEM images of T-type zeolite membranes after two-step crystallizations prepared at different first-step crystallization temperature
    XRD patterns of zeolite T membrane M4 (a) and small zeolite T seeds (b)
    5. XRD patterns of zeolite T membrane M4 (a) and small zeolite T seeds (b)
    SEM images of T-type zeolite membranes after first-step crystallization prepared with varying first-step crystallization time
    6. SEM images of T-type zeolite membranes after first-step crystallization prepared with varying first-step crystallization time
    SEM images of T-type zeolite membranes after two-step crystallizations prepared with different first-step crystallization time
    7. SEM images of T-type zeolite membranes after two-step crystallizations prepared with different first-step crystallization time
    SEM images of T-type zeolite membranes after two-step crystallizations prepared at different second-step crystallization temperatures
    8. SEM images of T-type zeolite membranes after two-step crystallizations prepared at different second-step crystallization temperatures
    No.First-step
    crystallization
    Second-step
    crystallization
    J/
    (kg·m-2·h-1)
    α
    Temp./℃Time/hTemp./℃Time/h
    M111041106--
    M2120411064.19968
    M3130411063.875219
    M4135411063.84>10000
    M5150411063.532918
    Table 1. Pervaporation performance of T zeolite membranes prepared under different first-step crystallization temperatures
    No.First-step crystallizationSecond-step crystallizationJ/(kg ·m-2·h-1)α
    Temp./℃Time/hTemp./℃Time/h
    M613521106--
    M7135311064.04915
    M4135411063.84>10000
    M8135511064.22371
    M9135611064.97697
    Table 2. Pervaporation performance of T zeolite membranes prepared with different first-step crystallization time
    NoFirst-step crystallizationSecond-step crystallizationJ/(kg·m-2·h-1)α
    Temp./℃Time/hTemp./℃Time/h
    M101354906--
    M11135410063.942646
    M4135411063.84>10000
    M12135412063.975867
    M13135413063.415594
    Table 3. Pervaporation performance of T zeolite membranes prepared under different second-step crystallization temperatures
    SupportTemp./
    Time/
    h
    J/
    (kg·m-2·h-1)
    αRef.
    α-Al2O3 disc120242.2410000[29]
    α-Al2O3 tube100302.5210000[21]
    α-Al2O3 tube120162.966400[23]
    α-Al2O3 tube100+140a8+1a2.1510000[19]
    α-Al2O3 tube150+120b4+8b2.042874[30]
    α-Al2O3 tube135+110c4+6c3.84>10000This work
    Table 4. Pervaporation performance of zeolite T membranes for 90wt% isopropanol/water mixture at 75 ℃
    Bo ZHANG, Ning ZHANG, Jianhua YANG, Jiancheng LAN, Jinqu WANG. High Performance a&b Oriented T Zeolite Membrane by a Two-stage Crystallization Synthesis[J]. Journal of Inorganic Materials, 2020, 35(8): 939
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