Author Affiliations
State Key Laboratory of Fine Chemicals, Department of Chemistry, School of Chemical Engineering, Dalian University of Technology, Dalian 116024, Chinashow less
. Water contact angle measurements of (a) 3D and (b) 2D/3D perovskite films
. (a) XRD patterns of 3D and 2D/3D perovskite films, and (b) XRD pattern of 2D perovskite film
. Tauc plots of the perovskite films, the optical bandgap is 1.62 eV
. GIWAXS patterns of (a, c) 3D and (b, d) 2D/3D perovskite films with incident angles of (a, b) 0.1° and (c, d)1°
. Top-view SEM images of (a) 3D and (b) 2D/3D perovskite films, cross-sectional SEM images of (c) 3D-PSCs and (d) 2D/3D-PSCs
. Statistics of the PCE for PSCs, processed by 4-CBAI treatment with various concentrations of 0, 0.5, 1.0, and 1.5 mg·mL-1
. (a) UV-Vis absorption, PL spectra and (b) TRPL decay curves of 3D and 2D/3D perovskite films
. J-V curve of flexible PSCs based on 2D/3D perovskite
. Stabilized PCE and photocurrent density curves at the maximum power point for the flexible PSCs based on 2D/3D perovskite
. (a) Schematic diagram of 2D/3D-PSCs structure, (b) J-V curves (reverse and forward scans), (c) EQE spectra with the corresponding integrated current densities, and (d) stabilized PCE curves at the maximum power point for 3D-PSCs and 2D/3D-PSCs
. (a) Thermal stability of 3D-PSCs and 2D/3D-PSCs under 85 ℃ in air (relative humidity: 40%-70%), and (b) light stability of 3D-PSCs and 2D/3D-PSCs under continuous 1 sun illumination in N2
Sample | τ1/ns
| A1 | τ2/ns
| A2 | τave/ns
|
---|
3D | 2.55 | 0.71 | 17.26 | 0.30 | 13.49 | 2D/3D | 4.75 | 0.53 | 24.86 | 0.43 | 21.02 |
|
Table 1. TRPL fitting results of 3D and 2D/3D perovskite films
Sample | Scan method | VOC/V
| JSC/(mA·cm-2)
| FF/%
| PCE/% |
---|
3D | Reverse | 1.11 | 23.17 | 72.74 | 18.70 | Forward | 1.08 | 23.18 | 71.85 | 18.06 | 2D/3D | Reverse | 1.17 | 23.45 | 76.39 | 20.88 | Forward | 1.16 | 23.44 | 75.07 | 20.41 |
|
Table 2. Detailed photovoltaic parameters of 3D-PSCs and 2D/3D-PSCs