• Journal of Inorganic Materials
  • Vol. 37, Issue 1, 72 (2022)
Xinyue YANG*, Qingshun DONG, Weidong ZHAO, and Yantao SHI
Author Affiliations
  • State Key Laboratory of Fine Chemicals, Department of Chemistry, School of Chemical Engineering, Dalian University of Technology, Dalian 116024, China
  • show less
    DOI: 10.15541/jim20210199 Cite this Article
    Xinyue YANG, Qingshun DONG, Weidong ZHAO, Yantao SHI. 4-Chlorobenzylamine-based 2D/3D Perovskite Solar Cells[J]. Journal of Inorganic Materials, 2022, 37(1): 72 Copy Citation Text show less
    Water contact angle measurements of (a) 3D and (b) 2D/3D perovskite films
    . Water contact angle measurements of (a) 3D and (b) 2D/3D perovskite films
    (a) XRD patterns of 3D and 2D/3D perovskite films, and (b) XRD pattern of 2D perovskite film
    . (a) XRD patterns of 3D and 2D/3D perovskite films, and (b) XRD pattern of 2D perovskite film
    Tauc plots of the perovskite films, the optical bandgap is 1.62 eV
    . Tauc plots of the perovskite films, the optical bandgap is 1.62 eV
    GIWAXS patterns of (a, c) 3D and (b, d) 2D/3D perovskite films with incident angles of (a, b) 0.1° and (c, d)1°
    . GIWAXS patterns of (a, c) 3D and (b, d) 2D/3D perovskite films with incident angles of (a, b) 0.1° and (c, d)1°
    Top-view SEM images of (a) 3D and (b) 2D/3D perovskite films, cross-sectional SEM images of (c) 3D-PSCs and (d) 2D/3D-PSCs
    . Top-view SEM images of (a) 3D and (b) 2D/3D perovskite films, cross-sectional SEM images of (c) 3D-PSCs and (d) 2D/3D-PSCs
    Statistics of the PCE for PSCs, processed by 4-CBAI treatment with various concentrations of 0, 0.5, 1.0, and 1.5 mg·mL-1
    . Statistics of the PCE for PSCs, processed by 4-CBAI treatment with various concentrations of 0, 0.5, 1.0, and 1.5 mg·mL-1
    (a) UV-Vis absorption, PL spectra and (b) TRPL decay curves of 3D and 2D/3D perovskite films
    . (a) UV-Vis absorption, PL spectra and (b) TRPL decay curves of 3D and 2D/3D perovskite films
    J-V curve of flexible PSCs based on 2D/3D perovskite
    . J-V curve of flexible PSCs based on 2D/3D perovskite
    Stabilized PCE and photocurrent density curves at the maximum power point for the flexible PSCs based on 2D/3D perovskite
    . Stabilized PCE and photocurrent density curves at the maximum power point for the flexible PSCs based on 2D/3D perovskite
    (a) Schematic diagram of 2D/3D-PSCs structure, (b) J-V curves (reverse and forward scans), (c) EQE spectra with the corresponding integrated current densities, and (d) stabilized PCE curves at the maximum power point for 3D-PSCs and 2D/3D-PSCs
    . (a) Schematic diagram of 2D/3D-PSCs structure, (b) J-V curves (reverse and forward scans), (c) EQE spectra with the corresponding integrated current densities, and (d) stabilized PCE curves at the maximum power point for 3D-PSCs and 2D/3D-PSCs
    (a) Thermal stability of 3D-PSCs and 2D/3D-PSCs under 85 ℃ in air (relative humidity: 40%-70%), and (b) light stability of 3D-PSCs and 2D/3D-PSCs under continuous 1 sun illumination in N2
    . (a) Thermal stability of 3D-PSCs and 2D/3D-PSCs under 85 ℃ in air (relative humidity: 40%-70%), and (b) light stability of 3D-PSCs and 2D/3D-PSCs under continuous 1 sun illumination in N2
    Sampleτ1/ns A1τ2/ns A2τave/ns
    3D2.550.7117.260.3013.49
    2D/3D4.750.5324.860.4321.02
    Table 1. TRPL fitting results of 3D and 2D/3D perovskite films
    SampleScan methodVOC/V JSC/(mA·cm-2) FF/% PCE/%
    3DReverse1.1123.1772.7418.70
    Forward1.0823.1871.8518.06
    2D/3DReverse1.1723.4576.3920.88
    Forward1.1623.4475.0720.41
    Table 2. Detailed photovoltaic parameters of 3D-PSCs and 2D/3D-PSCs
    Xinyue YANG, Qingshun DONG, Weidong ZHAO, Yantao SHI. 4-Chlorobenzylamine-based 2D/3D Perovskite Solar Cells[J]. Journal of Inorganic Materials, 2022, 37(1): 72
    Download Citation