• Laser & Optoelectronics Progress
  • Vol. 60, Issue 13, 1316008 (2023)
Long Qin1、†, Yunci Wang1、†, and Siwei Xiang*
Author Affiliations
  • School of Chemistry and Chemical Engineering, Chongqing University, Chongqing 400044, China
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    DOI: 10.3788/LOP231043 Cite this Article Set citation alerts
    Long Qin, Yunci Wang, Siwei Xiang. Preparation of Long Fiber-Shaped Zinc Oxide Based Composite Photoelectrode by Continuous Electrodeposition[J]. Laser & Optoelectronics Progress, 2023, 60(13): 1316008 Copy Citation Text show less
    Schematic diagram of structure and electrodeposition process of fiber ZnO-based photoelectrode. (a) Structural schematic diagram; (b) schematic diagram of the device for continuously controlled electrodeposition of nano ZnO on a long fiber substrate; (c) SEM image of dense nano ZnO; (d) SEM image of porous nano ZnO; (e) schematic diagram of ZnO electrodeposition mechanism
    Fig. 1. Schematic diagram of structure and electrodeposition process of fiber ZnO-based photoelectrode. (a) Structural schematic diagram; (b) schematic diagram of the device for continuously controlled electrodeposition of nano ZnO on a long fiber substrate; (c) SEM image of dense nano ZnO; (d) SEM image of porous nano ZnO; (e) schematic diagram of ZnO electrodeposition mechanism
    Effect of movement speed of reaction tank on the electrodeposition of ZnO. (a) Schematic diagram; (b)-(f) morphologies of ZnO at movement speeds of 0.16 cm/s, 0.33 cm/s, 0.67 cm/s, 1.33 cm/s, and 2.67 cm/s, respectively
    Fig. 2. Effect of movement speed of reaction tank on the electrodeposition of ZnO. (a) Schematic diagram; (b)-(f) morphologies of ZnO at movement speeds of 0.16 cm/s, 0.33 cm/s, 0.67 cm/s, 1.33 cm/s, and 2.67 cm/s, respectively
    Effect of temperature on electrodeposition behavior and morphologies of ZnO. (a) Electrodeposition behavior of ZnO at different temperatures; (b)-(f) morphologies of ZnO at temperatures of 22 ℃, 24 ℃, 26 ℃, 28 ℃, and 30 ℃, respectively
    Fig. 3. Effect of temperature on electrodeposition behavior and morphologies of ZnO. (a) Electrodeposition behavior of ZnO at different temperatures; (b)-(f) morphologies of ZnO at temperatures of 22 ℃, 24 ℃, 26 ℃, 28 ℃, and 30 ℃, respectively
    SEM images of composite metal fiber and composite metal fiber coated with dense ZnO layer. (a) Surface and (b) partial enlarged view of composite metal fiber; (c) cross sectional view of composite metal fiber; (d) surface and (e) partially enlarged view of composite metal fiber coated with dense ZnO layer; (f) cross section view of composite metal fiber coated with dense ZnO layer
    Fig. 4. SEM images of composite metal fiber and composite metal fiber coated with dense ZnO layer. (a) Surface and (b) partial enlarged view of composite metal fiber; (c) cross sectional view of composite metal fiber; (d) surface and (e) partially enlarged view of composite metal fiber coated with dense ZnO layer; (f) cross section view of composite metal fiber coated with dense ZnO layer
    SEM images of nano ZnO layer grown at different reaction temperatures. (a) (b) 90 ℃; (c) (d) 70 ℃; (e) (f) 50 ℃; (g) (h) 30 ℃
    Fig. 5. SEM images of nano ZnO layer grown at different reaction temperatures. (a) (b) 90 ℃; (c) (d) 70 ℃; (e) (f) 50 ℃; (g) (h) 30 ℃
    SEM images of nano ZnO at different hydrothermal reaction solution concentrations and the performance of corresponding fiber solar cells. (a) 0.01 mol/L; (b) 0.02 mol/L; (c) 0.03 mol/L; (d) 0.04 mol/L; (e) 0.05 mol/L; (f) performance of corresponding fiber solar cells
    Fig. 6. SEM images of nano ZnO at different hydrothermal reaction solution concentrations and the performance of corresponding fiber solar cells. (a) 0.01 mol/L; (b) 0.02 mol/L; (c) 0.03 mol/L; (d) 0.04 mol/L; (e) 0.05 mol/L; (f) performance of corresponding fiber solar cells
    SEM images of nano ZnO at different hydrothermal reaction solution volume and the performance of corresponding fiber solar cells. (a) 60 mL; (b) 70 mL; (c) 80 mL; (d) 90 mL; (e) 100 mL; (f) performance of corresponding fiber solar cells
    Fig. 7. SEM images of nano ZnO at different hydrothermal reaction solution volume and the performance of corresponding fiber solar cells. (a) 60 mL; (b) 70 mL; (c) 80 mL; (d) 90 mL; (e) 100 mL; (f) performance of corresponding fiber solar cells
    SEM images of fiber electrode grown with ZnO nanoarrays and fiber electrode coated with CuI. (a) Surface of ZnO nanoarrays; (b) enlarged view of surface of ZnO nanoarrays; (c) cross section of ZnO nanoarrays; (d) surface of CuI; (e) enlarged view of surface of CuI; (f) cross section of CuI
    Fig. 8. SEM images of fiber electrode grown with ZnO nanoarrays and fiber electrode coated with CuI. (a) Surface of ZnO nanoarrays; (b) enlarged view of surface of ZnO nanoarrays; (c) cross section of ZnO nanoarrays; (d) surface of CuI; (e) enlarged view of surface of CuI; (f) cross section of CuI
    Performance of fiber dye sensitized solar cells. (a) Short circuit current density and open circuit voltage at different light intensities; (b) current density-open circuit voltage curve of the batteries in series; (c) current density-open circuit voltage of the batteries in parallel; (d) current density-open circuit voltage curve before and after bending; (e) short circuit current density and open circuit voltage after different bending times; (f) current density-open circuit voltage curve before and after being soaked in water
    Fig. 9. Performance of fiber dye sensitized solar cells. (a) Short circuit current density and open circuit voltage at different light intensities; (b) current density-open circuit voltage curve of the batteries in series; (c) current density-open circuit voltage of the batteries in parallel; (d) current density-open circuit voltage curve before and after bending; (e) short circuit current density and open circuit voltage after different bending times; (f) current density-open circuit voltage curve before and after being soaked in water
    Long Qin, Yunci Wang, Siwei Xiang. Preparation of Long Fiber-Shaped Zinc Oxide Based Composite Photoelectrode by Continuous Electrodeposition[J]. Laser & Optoelectronics Progress, 2023, 60(13): 1316008
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