• Opto-Electronic Advances
  • Vol. 5, Issue 2, 200051 (2022)
Tangyao Shen1、†, Jiajun Qin2、†, Yujie Bai1、†, Jia Zhang3, Lei Shi1、*, Xiaoyuan Hou1, Jian Zi1、*, and Bin Hu3、*
Author Affiliations
  • 1Department of Physics, Fudan University, Shanghai 200433, China
  • 2Department of Physics, Chemistry and Biology (IFM), Linköping University, Linköping 58183, Sweden
  • 3Department of Materials Science and Engineering, University of Tennessee, Knoxville, Tennessee 37996, USA
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    DOI: 10.29026/oea.2022.200051 Cite this Article
    Tangyao Shen, Jiajun Qin, Yujie Bai, Jia Zhang, Lei Shi, Xiaoyuan Hou, Jian Zi, Bin Hu. Giant magneto field effect in up-conversion amplified spontaneous emission via spatially extended states in organic-inorganic hybrid perovskites[J]. Opto-Electronic Advances, 2022, 5(2): 200051 Copy Citation Text show less

    Abstract

    Up-conversion lasing actions are normally difficult to realize in light-emitting materials due to small multi-photon absorption cross section and fast dephasing of excited states during multi-photon excitation. This paper reports an easily accessible up-conversion amplified spontaneous emission (ASE) in organic-inorganic hybrid perovskites (MAPbBr3) films by optically exciting broad gap states with sub-bandgap laser excitation. The broad absorption was optimized by adjusting the grain sizes in the MAPbBr3 films. At low sub-bandgap pumping intensities, directly exciting the gap states leads to 2-photon, 3-photon, and 4-photon up-conversion spontaneous emission, revealing a large optical cross section of multi-photon excitation occurring in such hybrid perovskite films. At moderate pumping intensity (1.19 mJ/cm2) of 700 nm laser excitation, a significant spectral narrowing phenomenon was observed with the full width at half maximum (FWHM) decreasing from 18 nm to 4 nm at the peak wavelength of 550 nm, simultaneously with a nonlinear increase on spectral peak intensity, showing an up-conversion ASE realized at low threshold pumping fluence. More interestingly, the up-conversion ASE demonstrated a giant magnetic field effect, leading to a magneto-ASE reaching 120%. In contrast, the up-conversion photoluminescence (PL) showed a negligible magnetic field effect (< 1%). This observation provides an evidence to indicate that the light-emitting states responsible for up-conversion ASE are essentially formed as spatially extended states. The angular dependent spectrum results further verify the existence of spatially extended states which are polarized to develop coherent in-phase interaction. Clearly, using broad gap states with spatially extended light-emitting states presents a new approach to develop up-conversion ASE in organic-inorganic hybrid perovskites.
    Supplementary Materials
    Tangyao Shen, Jiajun Qin, Yujie Bai, Jia Zhang, Lei Shi, Xiaoyuan Hou, Jian Zi, Bin Hu. Giant magneto field effect in up-conversion amplified spontaneous emission via spatially extended states in organic-inorganic hybrid perovskites[J]. Opto-Electronic Advances, 2022, 5(2): 200051
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