Analysis and Evaluation of Inorganic Elements in Salvia miltiorrhiza and Rhizosphere Soils From Different Areas

Qin-rong LIU; Zi-wei DU; Jia-zhen LI; Yi-shuo WANG; Xuan GU; Xiu-mei CUI

doi:10.3964/j.issn.1000-0593(2021)11-3618-07

Journals >Spectroscopy and Spectral Analysis >Volume 41 >Issue 11 >Page 3618 > Article

Spectroscopy and Spectral Analysis
Vol. 41, Issue 11, 3618 (2021)

Analysis and Evaluation of Inorganic Elements in Salvia miltiorrhiza and Rhizosphere Soils From Different Areas

Qin-rong LIU^1,*, Zi-wei DU^1,1;, Jia-zhen LI^1,1;, Yi-shuo WANG^{1,1; 3; *;}..., Xuan GU^2,2; and Xiu-mei CUI^2,2;|Show fewer author(s)

Author Affiliations

¹1. School of Pharmacy, Henan University of Chinese Medicine, Zhengzhou 450046, China

²2. Beijing Huamiao Pharmaceutical Co., Ltd., Beijing 102600, China

show less

DOI: 10.3964/j.issn.1000-0593(2021)11-3618-07 Cite this Article

Qin-rong LIU, Zi-wei DU, Jia-zhen LI, Yi-shuo WANG, Xuan GU, Xiu-mei CUI. Analysis and Evaluation of Inorganic Elements in Salvia miltiorrhiza and Rhizosphere Soils From Different Areas[J]. Spectroscopy and Spectral Analysis, 2021, 41(11): 3618 Copy Citation Text

show less

Fig. 1. Cluster analysis of inorganic elements in Salvia miltiorrhiza

Download full size | View in the Article

Fig. 2. Score scatter

Download full size | View in the Article

Fig. 3. PLS-DA model

Download full size | View in the Article

Fig. 4. VIP plot

Download full size | View in the Article

编号	产地	品种	生长年限	土壤质地	土壤类型
S1	河南确山	栽培	1年	砂壤	黄褐土
S2	河南方城	栽培	1年	砂壤	黄褐土
S3	河南方城	栽培	1年	砂壤	黄褐土
S4	陕西丹凤	栽培	1年	砂壤	褐土
S5	陕西丹凤	栽培	1年	砂壤	褐土
S6	四川中江	栽培	1年	黏壤	红褐土
S7	四川中江	栽培	1年	黏壤	红褐土
S8	山东诸城	栽培	1年	砂壤	棕壤土
S9	山东莒县	栽培	1年	砂壤	棕壤土
S10	山东临朐	栽培	1年	砂壤	棕壤土
S11	山西万荣	栽培	1年	粉土	黄棕土
S12	山西襄汾	栽培	1年	粉土	黄棕土

Table 1. Sample information

View in the Article

元素	波长/nm	狭缝/nm	灯电流/mA	光电倍增管负高压/V	乙炔流量/(L·min^-1)	乙炔压力/MPa	燃气高度/mm
Na	589.0	0.4	10.0	330/235	2.0	0.06	7.5
Mg	285.2	1.3	7.5	330/172	2.0	0.05	12.5
K	766.5	1.3	10.0	380/254	2.2	0.05	7.5
Ca	422.7	1.3	7.5	560/243	2.2	0.05	7.5
Mn	279.5	0.4	7.5	400/309	2.0	0.06	7.5
Fe	248.3	0.2	12.5	400/427	1.8	0.05	7.5
Cu	324.8	1.3	7.5	330/243	2.0	0.05	7.5
Zn	213.9	1.3	5.0	430/317	1.8	0.05	7.5

Table 2. Using parameters of atomic absorption spectrometer

View in the Article

程序	时间/min	功率/W	温度/℃	压力/atm
1	5.0	800	120	10.0
2	10.0	800	150	20.0
3	30.0	800	200	30.0

Table 3. Operating parameters of microwave digestion instrument

View in the Article

元素	线性方程	线性范围/(mg·L^-1)	相关系数r²	检出限/(mg·L^-1)
Na	y=2.62×10^-2x+1.38×10^-4	0~5.0	0.999 7	0.014 3
Mg	y=3.13×10^-1x+3.83×10^-3	0~0.5	0.999 1	0.090 2
K	y=0.070 2x+0.027 3	0~10	0.998 1	0.041 5
Ca	y=0.048 2x+0.025 1	0~10	0.997 8	0.069 8
Mn	y=0.074 1x-0.000 5	0~0.9	0.999 9	0.001 1
Fe	y=3.58×10^-2x+6.33×10^-3	0~10	0.999 4	0.030 2
Cu	y=0.028 5x-0.000 1	0~0.5	0.999 4	0.001 1
Zn	y=2.41×10^-1x+2.71×10^-3	0~1.0	0.999 8	0.036 8

Table 4. Linear regression equation and detection limit

View in the Article

编号	Na	Mg	K	Ca	Mn	Fe	Cu	Zn
S1	1.808	0.489	5.115	1.488	0.061	0.208	0.017	0.023
S2	1.314	0.222	6.534	1.933	0.092	0.141	0.015	0.038
S3	1.244	0.494	6.294	1.596	0.072	0.150	0.016	0.043
S4	2.854	0.407	6.822	1.921	0.765	0.793	0.065	0.016
S5	3.194	0.355	6.754	2.561	0.688	0.665	0.067	0.016
S6	1.275	1.587	9.144	3.856	0.134	2.390	0.049	0.065
S7	1.416	1.873	9.637	3.516	0.214	2.580	0.055	0.055
S8	4.734	0.636	4.660	1.502	1.259	1.189	0.076	0.064
S9	4.664	0.088	4.563	1.455	1.258	1.157	0.074	0.059
S10	5.192	0.617	4.439	1.442	1.252	1.107	0.066	0.046
S11	5.873	2.353	4.496	2.286	0.027	0.679	0.022	0.026
S12	6.003	2.600	4.351	2.706	0.026	0.592	0.024	0.022

Table 5. Content of inorganic elements in Salvia miltiorrhiza

View in the Article

编号	Na	Mg	K	Ca	Mn	Fe	Cu	Zn
T-S1	52.836	1.676	13.529	1.686	15.242	19.948	0.022	0.141
T-S2	60.183	1.679	13.681	1.446	13.493	20.939	0.021	0.140
T-S3	59.650	1.557	14.557	1.559	12.268	20.239	0.022	0.143
T-S4	59.857	1.066	13.886	4.279	16.020	21.455	0.080	0.156
T-S5	59.769	1.070	13.777	4.216	15.638	21.250	0.082	0.155
T-S6	54.652	2.915	16.654	3.946	10.249	27.472	0.071	0.021
T-S7	55.270	2.152	16.404	2.958	10.239	28.694	0.061	0.026
T-S8	59.809	1.659	14.051	1.362	16.267	20.439	1.056	0.145D
T-S9	61.055	1.425	14.282	1.426	17.666	22.261	0.055	0.144
T-S10	60.991	1.486	14.064	1.242	17.182	22.366	0.045	0.161
T-S11	57.681	2.357	14.655	3.350	10.694	15.668	0.021	0.029
T-S12	59.132	2.589	15.108	3.125	10.528	19.828	0.021	0.031

Table 6. Content of inorganic elements in root soil

View in the Article

编号	T-Na	T-Mg	T-K	T-Ca	T-Mn	T-Fe	T-Cu	T-Zn
Na	0.453	0.055	-0.204	-0.044	0.211	-0.527	-0.138	-0.071
Mg	-0.367	0.832^**	0.664^*	0.413	-0.812^**	0.021	-0.242	-0.925^**
K	-0.452	0.230	0.650^*	0.473	-0.465	0.805^**	0.497	-0.361
Ca	-0.494	0.678^*	0.858^**	0.680^*	-0.752^**	0.623^*	0.340	-0.806^**
Mn	0.585^*	-0.565	-0.352	-0.284	0.830^**	0.058	0.504	0.586^*
Fe	-0.346	0.449	0.816^**	0.292	-0.295	0.833^**	0.571	-0.539
Cu	0.347	-0.378	0.013	0.120	0.573	0.386	0.829^**	0.285
Zn	-0.031	0.299	0.489	-0.427	-0.022	0.562	0.154	-0.149

Table 7. Correlation analysis of elements between soil and medicinal

View in the Article

成分	初始特征值			提取载荷平方和			旋转载荷平方和
成分	总计	方差百分比	累积/%	总计	方差百分比	累积/%	总计	方差百分比	累积/%
1	2.738	34.220	34.220	2.738	34.220	34.220	2.625	32.817	32.817
2	2.231	27.887	62.108	2.231	27.887	62.108	2.120	26.504	59.321
3	1.756	21.951	84.058	1.756	21.951	84.058	1.979	24.737	84.058
4	0.884	11.055	95.113
5	0.217	2.709	97.822
6	0.146	1.824	99.646
7	0.017	0.216	99.863
8	0	0.137	100.000

Table 8. The characteristics of the principal component value and contribution

View in the Article

元素	成分1	成分2	成分3
Na	0.118	0.858	0.437
Mg	-0.517	-0.062	0.722
K	0.435	0.652	0.401
Ca	-0.076	-0.488	0.693
Mn	0.554	0.653	0.335
Fe	0.835	-0.432	0.277
Cu	0.854	-0.456	0.106
Zn	0.727	-0.089	-0.032

Table 9. The initial factor loading matrix

View in the Article

样品	主成分1 得分	主成分2 得分	主成分3 得分	综合得分
S1	-2.006 6	-1.162 0	-0.383 7	-1.302 6
S2	-1.685 1	-0.599 4	-0.796 1	-1.092 8
S3	-1.539 1	-0.474 7	-1.266 8	-1.114 9
S4	-0.511 0	-0.007 5	-1.410 0	-0.578 7
S5	-0.653 9	-0.188 0	-0.810 1	-0.540 1
S6	2.450 6	-1.982 3	-0.285 8	0.265 4
S7	1.664 3	-2.691 6	1.757 6	0.243 5
S8	1.925 6	1.236 7	0.139 2	1.230 6
S9	1.355 7	1.275 2	-0.804 6	0.764 9
S10	1.582 7	2.411 8	-0.567 8	1.296 2
S11	-1.173 1	1.257 7	1.820 1	0.415 0
S12	-1.410 3	0.924 1	2.607 9	0.413 5

Table 10. Principal component score and comprehensive score of S. miltiorrhiza

Download Citation

Save the article for my favorites

Paper Information

微信扫一扫：分享

微信扫一扫：分享