• Photonics Research
  • Vol. 9, Issue 2, 187 (2021)
Shuangyi Zhao1、†, Qionghua Mo1、†, Wensi Cai, Huaxin Wang, and Zhigang Zang*
Author Affiliations
  • Key Laboratory of Optoelectronic Technology & Systems (Ministry of Education), Chongqing University, Chongqing 400044, China
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    DOI: 10.1364/PRJ.409398 Cite this Article Set citation alerts
    Shuangyi Zhao, Qionghua Mo, Wensi Cai, Huaxin Wang, Zhigang Zang. Inorganic lead-free cesium copper chlorine nanocrystal for highly efficient and stable warm white light-emitting diodes[J]. Photonics Research, 2021, 9(2): 187 Copy Citation Text show less
    References

    [1] J. Shamsi, A. S. Urban, M. Imran, L. De Trizio, L. Manna. Metal halide perovskite nanocrystals: synthesis, post-synthesis modifications, and their optical properties. Chem. Rev., 119, 3296-3348(2019).

    [2] Q. A. Akkerman, G. Raino, M. V. Kovalenko, L. Manna. Genesis, challenges and opportunities for colloidal lead halide perovskite nanocrystals. Nat. Mater., 17, 394-405(2018).

    [3] X. Li, F. Cao, D. Yu, J. Chen, Z. Sun, Y. Shen, Y. Zhu, L. Wang, Y. Wei, Y. Wu, H. Zeng. All inorganic halide perovskites nanosystem: synthesis, structural features, optical properties and optoelectronic applications. Small, 13, 1603996(2017).

    [4] F. Liu, Y. Zhang, C. Ding, S. Kobayashi, T. Izuishi, N. Nakazawa, T. Toyoda, T. Ohta, S. Hayase, T. Minemoto, K. Yoshino, S. Dai, Q. Shen. Highly luminescent phase-stable CsPbI3 perovskite quantum dots achieving near 100% absolute photoluminescence quantum yield. ACS Nano, 11, 10373-10383(2017).

    [5] Q. Wang, X. Wang, Z. Yang, N. Zhou, Y. Deng, J. Zhao, X. Xiao, P. Rudd, A. Moran, Y. Yan, J. Huang. Efficient sky-blue perovskite light-emitting diodes via photoluminescence enhancement. Nat. Commun., 10, 5633(2019).

    [6] J. Song, J. Li, L. Xu, J. Li, F. Zhang, B. Han, Q. Shan, H. Zeng. Room-remperature triple-ligand surface engineering synergistically boosts ink stability, recombination dynamics, and charge injection toward EQE-11.6% perovskite QLEDs. Adv. Mater., 30, 1800764(2018).

    [7] Q. Zhao, A. Hazarika, X. Chen, S. P. Harvey, B. W. Larson, G. R. Teeter, J. Liu, T. Song, C. Xiao, L. Shaw, M. Zhang, G. Li, M. C. Beard, J. M. Luther. High efficiency perovskite quantum dot solar cells with charge separating heterostructure. Nat. Commun., 10, 2842(2019).

    [8] L. M. Wheeler, E. M. Sanehira, A. R. Marshall, P. Schulz, M. Suri, N. C. Anderson, J. A. Christians, D. Nordlund, D. Sokaras, T. Kroll, S. P. Harvey, J. J. Berry, L. Y. Lin, J. M. Luther. Targeted ligand-exchange chemistry on cesium lead halide perovskite quantum dots for high-efficiency photovoltaics. J. Am. Chem. Soc., 140, 10504-10513(2018).

    [9] K. Chen, Q. Zhong, W. Chen, B. Sang, Y. Wang, T. Yang, Y. Liu, Y. Zhang, H. Zhang. Short-chain ligand-passivated stable α-CsPbI3 quantum dot for all-inorganic perovskite solar cells. Adv. Funct. Mater., 29, 1900991(2019).

    [10] A. Swarnkar, A. R. Marshall, E. M. Sanehira, B. D. Chernomordik, D. T. Moore, J. A. Christians, T. Chakrabarti, J. M. Luther. Quantum dot-induced phase stabilization of α-CsPbI3 perovskite for high-efficiency photovoltaics. Science, 354, 92-95(2016).

    [11] J. Liu, B. Shabbir, C. Wang, T. Wan, Q. Ou, P. Yu, A. Tadich, X. Jiao, D. Chu, D. Qi, D. Li, R. Kan, Y. Huang, Y. Dong, J. Jasieniak, Y. Zhang, Q. Bao. Flexible, printable soft-X-ray detectors based on all-inorganic perovskite quantum dots. Adv. Mater., 31, 1901644(2019).

    [12] G. C. Adhikari, S. Thapa, H. Zhu, P. Zhu. Mg2+-alloyed all-inorganic halide perovskites for white light-emitting diodes by 3D-printing method. Adv. Opt. Mater., 7, 1900916(2019).

    [13] S. Thapa, G. C. Adhikari, H. Zhu, A. Grigoriev, P. Zhu. Zn-alloyed all-inorganic halide perovskite-based white light-emitting diodes with superior color quality. Sci. Rep., 9, 18636(2019).

    [14] Z. Tan, J. Li, C. Zhang, Z. Li, Q. Hu, Z. Xiao, T. Kamiya, H. Hosono, G. Niu, E. Lifshitz, Y. Cheng, J. Tang. Highly efficient blue-emitting bi-doped Cs2SnCl6 perovskite variant: photoluminescence induced by impurity doping. Adv. Funct. Mater., 28, 1801131(2018).

    [15] J. Zhang, Y. Yang, H. Deng, U. Farooq, X. Yang, J. Khan, J. Tang, H. Song. High quantum yield blue emission from lead-free inorganic antimony halide perovskite colloidal quantum dots. ACS Nano, 11, 9294-9302(2017).

    [16] M. Leng, Y. Yang, K. Zeng, Z. Chen, Z. Tan, S. Li, J. Li, B. Xu, D. Li, M. P. Hautzinger, Y. Fu, T. Zhai, L. Xu, G. Niu, S. Jin, J. Tang. All-Inorganic bismuth-based perovskite quantum dots with bright blue photoluminescence and excellent stability. Adv. Funct. Mater., 28, 1704446(2018).

    [17] F. Locardi, M. Cirignano, D. Baranov, Z. Dang, M. Prato, F. Drago, M. Ferretti, V. Pinchetti, M. Fanciulli, S. Brovelli, L. De Trizio, L. Manna. Colloidal synthesis of double perovskite Cs2AgInCl6 and Mn-doped Cs2AgInCl6 nanocrystals. J. Am. Chem. Soc., 140, 12989-12995(2018).

    [18] B. Yang, J. Chen, S. Yang, F. Hong, L. Sun, P. Han, T. Pullerits, W. Deng, K. Han. Lead-free silver-bismuth halide double perovskite nanocrystals. Angew. Chem. Int. Ed., 57, 5359-5363(2018).

    [19] Z. X. Zhang, C. Li, Y. Lu, X. W. Tong, F. X. Liang, X. Y. Zhao, D. Wu, C. Xie, L. B. Luo. Sensitive deep ultraviolet photodetector and image sensor composed of inorganic lead-free Cs3Cu2I5 perovskite with wide bandgap. J. Phys. Chem. Lett., 10, 5343-5350(2019).

    [20] X. Zhao, G. Niu, J. Zhu, B. Yang, J. H. Yuan, S. Li, W. Gao, Q. Hu, L. Yin, K. H. Xue, E. Lifshitz, X. Miao, J. Tang. All-inorganic copper halide as a stable and self-absorption-free X-ray scintillator. J. Phys. Chem. Lett., 11, 1873-1880(2020).

    [21] H. Zhou, X. Liu, G. He, L. Fan, S. Shi, J. Wei, W. Xu, C. Yuan, N. Chai, B. Chen, Y. Zhang, X. Zhang, J. Zhao, X. Wei, J. Yin, D. Tian. Synthesis, crystal structure, UV-Vis adsorption properties, photoelectric behavior, and DFT computational study of all-inorganic and lead-free copper halide salt K2Cu2Cl6. ACS Omega, 3, 14021-14026(2018).

    [22] T. C. Jellicoe, J. M. Richter, H. F. Glass, M. Tabachnyk, R. Brady, S. E. Dutton, A. Rao, R. H. Friend, D. Credgington, N. C. Greenham, M. L. Bohm. Synthesis and optical properties of lead-free cesium tin halide perovskite nanocrystals. J. Am. Chem. Soc., 138, 2941-2944(2016).

    [23] Z. Luo, Q. Li, L. Zhang, X. Wu, L. Tan, C. Zou, Y. Liu, Z. Quan. 0D Cs3Cu2X5 (X = I, Br, and Cl) nanocrystals: colloidal syntheses and optical properties. Small, 16, 1905226(2019).

    [24] R. Lin, Q. Guo, Q. Zhu, Y. Zhu, W. Zheng, F. Huang. All-inorganic CsCu2I3 single crystal with high-PLQY (≈ 15.7%) intrinsic white-light emission via strongly localized 1D excitonic recombination. Adv. Mater., 31, 1905079(2019).

    [25] T. Jun, K. Sim, S. Iimura, M. Sasase, H. Kamioka, J. Kim, H. Hosono. Lead-free highly efficient blue-emitting Cs3Cu2I5 with 0D electronic structure. Adv. Mater., 30, 1804547(2018).

    [26] Z. Xiao, K. Du, W. Meng, D. B. Mitzi, Y. Yan. Chemical origin of the stability difference between copper(I)- and silver(I)-based halide double perovskite. Angew. Chem. Int. Ed., 129, 12275-12279(2017).

    [27] M. H. Du. Emission trend of multiple self-trapped excitons in luminescent 1D copper halides. ACS Energy Lett., 5, 464-469(2020).

    [28] R. Roccanova, A. Yangui, G. Seo, T. D. Creason, Y. Wu, D. Y. Kim, M. H. Du, B. Saparov. Bright luminescence from nontoxic CsCu2X3 (X = Cl, Br, I). ACS Mater. Lett., 1, 459-465(2019).

    [29] R. Roccanova, A. Yangui, H. Nhalil, H. Shi, M.-H. Du, B. Saparov. Near-unity photoluminescence quantum yield in blue-emitting Cs3Cu2Br5-xIx(0 ≤ x ≤ 5). ACS Appl. Electron. Mater., 1, 269-274(2019).

    [30] T. Li, X. Mo, C. Peng, Q. Lu, C. Qi, X. Tao, Y. Ouyang, Y. Zhou. Distinct green electroluminescence from lead-free CsCuBr2 halide micro-crosses. Chem. Commun., 55, 4554-4557(2019).

    [31] P. Yang, G. Liu, B. Liu, X. Liu, Y. Lou, J. Chen, Y. Zhao. All-inorganic Cs2CuX4 (X = Cl, Br, and Br/I) perovskite quantum dots with blue-green luminescence. Chem. Commun., 54, 11638-11641(2018).

    [32] P. Cheng, L. Sun, L. Feng, S. Yang, Y. Yang, D. Zheng, Y. Zhao, Y. Sang, R. Zhang, D. Wei, W. Deng, K. Han. Colloidal synthesis and optical properties of all-inorganic low-dimensional cesium halide nanocrystals. Angew. Chem. Int. Ed., 58, 16087-16091(2019).

    [33] P. Sebastia-Luna, J. Navarro-Alapont, M. Sessolo, F. Palazon, H. J. Bolink. Solvent-free synthesis and thin-film deposition of cesium copper halides with bright blue photoluminescence. Chem. Mater., 31, 10205-10210(2019).

    [34] L. Xie, B. Chen, F. Zhang, Z. Zhao, X. Wang, L. Shi, Y. Liu, L. Huang, R. Liu, B. Zou, Y. Wang. Highly luminescent and stable lead-free cesium copper halide perovskite powders for UV-pumped phosphor-converted light-emitting diodes. Photon. Res., 8, 768-775(2020).

    [35] C. Brink, N. F. Binnendijk, J. van de Linde. The crystal structures of CsCu2CI3 and CsAg2I3. Acta Crystallogr., 7, 176(1953).

    [36] S. Hull, P. Berastegui. Crystal structures and ionic conductivities of ternary derivatives of the silver and copper monohalides-II: ordered phases within the (AgX)x-(MX)1−x and (CuX)x-(MX)1−x (M = K, Rb and Cs; X = Cl, Br and I) systems. J. Solid State Chem., 177, 3156-3173(2004).

    [37] T. A. Malakhovskaya-Rosokha, I. E. Barchii, A. I. Pogodin, A. P. Kokhan, I. P. Stercho, E. Y. Peresh. Interaction of components in the RbI-CsI-CuI quasi-ternary system. Russian J. Inorg. Chem., 58, 577-580(2013).

    [38] L. Lian, M. Zheng, W. Zhang, L. Yin, X. Du, P. Zhang, X. Zhang, J. Gao, D. Zhang, L. Gao, G. Niu, H. Song, R. Chen, X. Lan, J. Tang, J. Zhang. Efficient and reabsorption-free radioluminescence in Cs3Cu2I5 nanocrystals with self-trapped excitons. Adv. Sci., 7, 2000195(2020).

    [39] X. Huang, Q. Sun, B. Devakumar. Facile low-temperature solid-state synthesis of efficient blue-emitting Cs3Cu2I5 powder phosphors for solid-state lighting. Mater. Today Chem., 17, 100288(2020).

    [40] L. Wang, Z. Shi, Z. Ma, D. Yang, F. Zhang, X. Ji, M. Wang, X. Chen, G. Na, S. Chen, D. Wu, Y. Zhang, X. Li, L. Zhang, C. Shan. Colloidal synthesis of ternary copper halide nanocrystals for high-efficiency deep-blue light-emitting diodes with a half-lifetime above 100 h. Nano Lett., 20, 3568-3576(2020).

    [41] Z. Ma, Z. Shi, C. Qin, M. Cui, D. Yang, X. Wang, L. Wang, X. Ji, X. Chen, J. Sun, D. Wu, Y. Zhang, X. J. Li, L. Zhang, C. Shan. Stable yellow light-emitting devices based on ternary copper halides with broadband emissive self-trapped excitons. ACS Nano, 14, 4475-4486(2020).

    [42] S. Li, J. Luo, J. Liu, J. Tang. Self-trapped excitons in all-inorganic halide perovskites: fundamentals, status, and potential applications. J. Phys. Chem. Lett., 10, 1999-2007(2019).

    [43] K. M. McCall, C. C. Stoumpos, S. S. Kostina, M. G. Kanatzidis, B. W. Wessels. Strong electron–phonon coupling and self-trapped excitons in the defect halide perovskites A3M2I9 (A = Cs, Rb; M = Bi, Sb). Chem. Mater., 29, 4129-4145(2017).

    [44] G. C. Adhikari, S. Thapa, H. Zhu, A. Grigoriev, P. Zhu. Synthesis of CsPbBr3 and transformation into Cs4PbBr6 crystals for white light emission with high CRI and tunable CCT. J. Phys. Chem. C, 123, 12023-12028(2019).

    [45] G. C. Adhikari, P. A. Vargas, H. Zhu, A. Grigoriev, P. Zhu. Tetradic phosphor white light with variable CCT and superlative CRI through organolead halide perovskite nanocrystals. Nanoscale Adv., 1, 1791-1798(2019).

    [46] P. Du, L. Luo, W. Cheng. Neoteric Mn2+-activated Cs3Cu2I5 dazzling yellow-emitting phosphors for white-LED. J. Am. Ceram. Soc., 103, 1149-1155(2019).

    Shuangyi Zhao, Qionghua Mo, Wensi Cai, Huaxin Wang, Zhigang Zang. Inorganic lead-free cesium copper chlorine nanocrystal for highly efficient and stable warm white light-emitting diodes[J]. Photonics Research, 2021, 9(2): 187
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