Crystal Structures, Optical, and Magnetic Properties of Zn3-xMnxTeO6

Shufang LI; Shuang ZHAO; Xiao ZHOU; Manrong LI

doi:10.15541/jim20190606

Journals >Journal of Inorganic Materials >Volume 35 >Issue 8 >Page 895 > Article

Journal of Inorganic Materials
Vol. 35, Issue 8, 895 (2020)

Crystal Structures, Optical, and Magnetic Properties of Zn_3-_xMn_xTeO₆

Shufang LI, Shuang ZHAO, Xiao ZHOU, and Manrong LI^*

Author Affiliations

Key Laboratory of Bioinorganic and Synthetic Chemistry of Ministry of Education, School of Chemistry, Sun Yat-Sen University, Guangzhou 510275, China

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DOI: 10.15541/jim20190606 Cite this Article

Shufang LI, Shuang ZHAO, Xiao ZHOU, Manrong LI. Crystal Structures, Optical, and Magnetic Properties of Zn_3-_xMn_xTeO₆[J]. Journal of Inorganic Materials, 2020, 35(8): 895 Copy Citation Text

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1. XRD patterns of Zn_3-_xMn_xTeO₆ (0<x≤2.0)

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Lattice parameters a, b and c [nm] (a), and V [nm3] (b) obtained from Zn3-xMnxTeO6 (0<x≤2.0) solid solutions by XRD measurements at room temperature

2. Lattice parameters a, b and c [nm] (a), and V [nm³] (b) obtained from Zn_3-_xMn_xTeO₆ (0<x≤2.0) solid solutions by XRD measurements at room temperature

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3. Rietveld refined of the PXRD data (a) and crystal structure (b) of ZnMn₂TeO₆

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4. Color evolution of the Zn_3-_xMn_xTeO₆ (0<x≤2.0) compounds in daylight

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5. Optical absorption (UV/Vis) spectra of the Zn_3-_xMn_xTeO₆ (0<x≤2.0) compounds

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6. Temperature-dependent susceptibility of Zn_3-_xMn_xTeO₆ (0<x≤2.0) measured between 5-300 K under magnetic field of 7.96×10⁴ A/m

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7. Isothermal magnetization of Zn_3-_xMn_xTeO₆ (0<x≤2.0) measured at 5 and 300 K, respectively

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Atom	Site	x	y	z	B/nm²	Occ.
Mn/Zn	18f	0.0388(1)	0.2240(1)	0.2864(1)	0.00510(1)	0.667/0.333
Te1	3b	0	0	0.5	0.00710(1)	1.0
Te2	3a	0	0	0	0.00320(1)	1.0
O1	18f	0.1773(4)	0.1972(4)	0.3833(1)	0.00510(1)	1.0
O2	18f	0.2061(3)	0.0348(5)	0.1071(2)	0.00550(1)	1.0

Table 1. Crystallographic parameters for ZnMn₂TeO₆ obtained from the Rietveld refinement of the PXRD data

Shufang LI, Shuang ZHAO, Xiao ZHOU, Manrong LI. Crystal Structures, Optical, and Magnetic Properties of Zn_3-_xMn_xTeO₆[J]. Journal of Inorganic Materials, 2020, 35(8): 895

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