Pt/hierarchical ZSM-5 zeolites were successfully synthesized by the steam-assisted crystallization and subsequent wetness impregnation method. Structural features were characterized by XRD, N₂ isotherm, SEM, and TEM. Its catalytic behaviors for o-xylene storage at room temperature, and catalytic combustion of stored o-xylene at elevated temperatures were evaluated. It was found that crystallinity of the product underwent a reducing tendency after introduction of mesostructure, but the mesoporosity and pore volume were remarkably increased. Compared with Pt/conventional ZSM-5 zeolite, the o-xylene adsorption capacity of Pt/hierarchical HZSM-5 was around 8 times as that of the counterpart without mesostructure. Moreover, the Pt dispersion was improved due to mesoporosity. The highly dispersed Pt nanoparticles were beneficial for catalytic combustion of o-xylene. Futhermore, Pt/hierarchical ZSM-5 showed the efficient bi-functional performance during adsorption/catalytic combustion cycling process for o-xylene. Carbon balance was kept for three cycles without secondary pollutants, showing higher adsorption capacity and better reusing stability.