• Chinese Journal of Lasers
  • Vol. 48, Issue 13, 1300001 (2021)
Ningning Dong1, Qianghu Liu2, and Jun Wang1、*
Author Affiliations
  • 1Laboratory of Micro⁃Nano Optoelectronic Materials and Devices, Shanghai Institute of Optics and Fine Mechanics, Chinese Academy of Sciences, Shanghai 201800, China
  • 2Science and Technology on Electro⁃Optical Information Security Control Laboratory, Academy of Opto⁃Electronics, China Electronics Technology Group Corporation, Tianjin 300308, China
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    DOI: 10.3788/CJL202148.1300001 Cite this Article Set citation alerts
    Ningning Dong, Qianghu Liu, Jun Wang. Research Progress of Two-Dimensional Nonlinear Optical Limiting Materials[J]. Chinese Journal of Lasers, 2021, 48(13): 1300001 Copy Citation Text show less
    Principle diagram of ideal optical limiter
    Fig. 1. Principle diagram of ideal optical limiter
    Research status of optical limiting[4]
    Fig. 2. Research status of optical limiting[4]
    Optical limiting properties of graphene. (a)(b) Nonlinear transmittance and scattering signal of graphene dispersions versus incident laser energy density[22]; (c)(d) open aperture Z-scan curves of graphene NMP dispersions under action of nanosecond pulse laser [23]; high-magnification (e) SEM and (f) TEM images of etched graphene[24]; (g) open aperture Z-scan curves of different materials[24]; (h) normalized transmittance versus incident laser fluence [24]
    Fig. 3. Optical limiting properties of graphene. (a)(b) Nonlinear transmittance and scattering signal of graphene dispersions versus incident laser energy density[22]; (c)(d) open aperture Z-scan curves of graphene NMP dispersions under action of nanosecond pulse laser [23]; high-magnification (e) SEM and (f) TEM images of etched graphene[24]; (g) open aperture Z-scan curves of different materials[24]; (h) normalized transmittance versus incident laser fluence [24]
    Optical limiting properties of different nanostructured graphene dispersions under action of 532 nm and 1064 nm nanosecond lasers[25]. (a)(b) Normalized transmittance; (c)(d) scattering signals
    Fig. 4. Optical limiting properties of different nanostructured graphene dispersions under action of 532 nm and 1064 nm nanosecond lasers[25]. (a)(b) Normalized transmittance; (c)(d) scattering signals
    Nonlinear optical properties and mechanisms of MoX2 dispersions. (a)(b) open aperture Z-scan results of MoX2 dispersions under action of femtosecond laser[33] ; (c)(d) normalized transmittance (solid circles) and scattering signals (open circles) of TMDCs suspensions[34]; (e) mechanism diagram of all-optical modulation[35]; (f) mechanism diagram of SA and NLS of nanosheet dispersions[35]
    Fig. 5. Nonlinear optical properties and mechanisms of MoX2 dispersions. (a)(b) open aperture Z-scan results of MoX2 dispersions under action of femtosecond laser[33] ; (c)(d) normalized transmittance (solid circles) and scattering signals (open circles) of TMDCs suspensions[34]; (e) mechanism diagram of all-optical modulation[35]; (f) mechanism diagram of SA and NLS of nanosheet dispersions[35]
    Nonlinear optical properties of TMDCs. (a) Two-photon absorption property of monolayer MoS2 under action of near-infrared femtosecond laser[36]; (b) SA property of multilayer MoS2[36] ; (c) two-photon absorption coefficients of cm-scaled few-layered WS2 under 1030 nm laser irradiation[37]; (d) four two-photon absorption saturation models[38]; (e)(f) self-focusing and defocusing behaviors of monolayer and bulk WS2 [39]
    Fig. 6. Nonlinear optical properties of TMDCs. (a) Two-photon absorption property of monolayer MoS2 under action of near-infrared femtosecond laser[36]; (b) SA property of multilayer MoS2[36] ; (c) two-photon absorption coefficients of cm-scaled few-layered WS2 under 1030 nm laser irradiation[37]; (d) four two-photon absorption saturation models[38]; (e)(f) self-focusing and defocusing behaviors of monolayer and bulk WS2 [39]
    Optical limiting properties of MoS2 composite materials under 532 nm and 1064 nm laser irradiation. (a)(b) Output fluence versus input fluence for MoS2/PMMA composite materials [40]; (c)(d) normalized transmittance versus input laser intensity for MoS2 composite materials[41]
    Fig. 7. Optical limiting properties of MoS2 composite materials under 532 nm and 1064 nm laser irradiation. (a)(b) Output fluence versus input fluence for MoS2/PMMA composite materials [40]; (c)(d) normalized transmittance versus input laser intensity for MoS2 composite materials[41]
    Nonlinear optical properties of BP nanosheets. (a)--(c) Z scan results under action of 1064, 532, 355 nm lasers[48]; (d) normalized transmittance versus input laser intensity for each wavelength[48]; (e) optical modulation properties of BP dispersions[49]; (f) modulation depths under different pump fluences[49]; (g) open aperture Z-scan results and corresponding (h) scattering signals[49]
    Fig. 8. Nonlinear optical properties of BP nanosheets. (a)--(c) Z scan results under action of 1064, 532, 355 nm lasers[48]; (d) normalized transmittance versus input laser intensity for each wavelength[48]; (e) optical modulation properties of BP dispersions[49]; (f) modulation depths under different pump fluences[49]; (g) open aperture Z-scan results and corresponding (h) scattering signals[49]
    Laser protectiontechnologyAdvantageIssue to be addressed
    Notch filterMulti-time scale, low protection threshold, high damage threshold, and large laser repetition rateNarrow-band spectral range of ~10 nm, single wavelength, and low linear transmittance
    Phase change materialBeing effective for laser heating, high damage threshold, near infrared wavelength, and broadband spectral range of 0.5--10 μmLong recovery time and low linear transmittance under laser operation
    Optical limitingShort response time, continuous broadband spectral range,low protection threshold, and being softBeing unable to resist thermal ablation of continuous wave laser
    Liquid crystalLarge electro-optic coefficient and low driving voltageLong response time
    Table 1. Summarization of several laser protection technologies
    Ningning Dong, Qianghu Liu, Jun Wang. Research Progress of Two-Dimensional Nonlinear Optical Limiting Materials[J]. Chinese Journal of Lasers, 2021, 48(13): 1300001
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