• Journal of Inorganic Materials
  • Vol. 35, Issue 1, 86 (2020)
Meng-Xia LI1, Yue LU2, Li-Bin WANG1, and Xian-Luo HU1、*
Author Affiliations
  • 1School of Materials Science and Engineering, Huazhong University of Science and Technology, Wuhan 430074, China
  • 2China-EU Institute for Clean and Renewable Energy, Huazhong University of Science and Technology, Wuhan 430074, China
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    DOI: 10.15541/jim20190277 Cite this Article
    Meng-Xia LI, Yue LU, Li-Bin WANG, Xian-Luo HU. Controlled Synthesis of Core-shell Structured Mn3O4@ZnO Nanosheet Arrays for Aqueous Zinc-ion Batteries[J]. Journal of Inorganic Materials, 2020, 35(1): 86 Copy Citation Text show less

    Abstract

    Manganese-based oxides are promising cathode materials for zinc-ion batteries. However, these materials often suffer from rapid capacity fade due to structure collapse during charge and discharge processes. Here, we report that core-shell structured Mn3O4@ZnO nanosheet arrays are synthesized on the carbon cloth, combining microwave hydrothermal process with atomic layer deposition. With an optimized thickness of ZnO coating layer, the capacity retention of the as-formed Mn3O4@ZnO nanosheet arrays exhibits 60.3% over 100 discharge-charge cycles at a current density of 100 mA·g -1. It is demonstrated that the introduction of ZnO layers is beneficial to maintain the microstructure and improve the structural stability of the Mn3O4 electrode material during the discharge-charge process, benefiting from avoiding direct contact with the electrolyte. The design of the well-defined core-shell structure provides an effective way to develop high-performance manganese-based oxide cathode materials for zinc-ion batteries.
    Meng-Xia LI, Yue LU, Li-Bin WANG, Xian-Luo HU. Controlled Synthesis of Core-shell Structured Mn3O4@ZnO Nanosheet Arrays for Aqueous Zinc-ion Batteries[J]. Journal of Inorganic Materials, 2020, 35(1): 86
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