• Spectroscopy and Spectral Analysis
  • Vol. 42, Issue 10, 3314 (2022)
Hong-mei REN1、*, Ang LI1、1; *;, Zhao-kun HU1、1;, Pin-hua XIE1、1; 2; 3;, Jin XU1、1;, Ye-yuan HUANG1、1; 2;, Xiao-mei LI1、1; 2;, Hong-yan ZHONG1、1; 4;, Hai-rong ZHANG1、1; 2;, Xin TIAN1、1; 4;, Bo REN2、2;, Jiang-yi ZHENG1、1; 2;, Shuai WANG5、5;, and Wen-xuan CHAI5、5;
Author Affiliations
  • 11. Key Laboratory of Environmental Optical and Technology, Anhui Institute of Optics and Fine Mechanics, Chinese Academy of Sciences, Hefei 230031, China
  • 22. Science Island Branch of Graduate School, University of Science and Technology of China, Hefei 230026, China
  • 55. State Environmental Protection Key Laboratory of Quality Control in Environmental Monitoring, China National Environment Monitoring Centre, Beijing 100012, China
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    DOI: 10.3964/j.issn.1000-0593(2022)10-3314-07 Cite this Article
    Hong-mei REN, Ang LI, Zhao-kun HU, Pin-hua XIE, Jin XU, Ye-yuan HUANG, Xiao-mei LI, Hong-yan ZHONG, Hai-rong ZHANG, Xin TIAN, Bo REN, Jiang-yi ZHENG, Shuai WANG, Wen-xuan CHAI. Measurement of Water Vapor Absorption in the Ultraviolet Band Using MAX-DOAS and Evaluation of Its Influence on DOAS Retrieval[J]. Spectroscopy and Spectral Analysis, 2022, 42(10): 3314 Copy Citation Text show less
    MAX-DOAS regional station location in Qianxian, Xi'an and the instrument observation principle(a): Observation location; (b): Observation principle
    Fig. 1. MAX-DOAS regional station location in Qianxian, Xi'an and the instrument observation principle
    (a): Observation location; (b): Observation principle
    Ultraviolet and visible blue H2O and O4 absorption cross section
    Fig. 2. Ultraviolet and visible blue H2O and O4 absorption cross section
    Water vapor optimal retrieval band test(a): Ultraviolet; (b): Visible
    Fig. 3. Water vapor optimal retrieval band test
    (a): Ultraviolet; (b): Visible
    Examples of DOAS fitting retrieval in ultraviolet (a) and visible bands (b)
    Fig. 4. Examples of DOAS fitting retrieval in ultraviolet (a) and visible bands (b)
    The DSCD in the ultraviolet and visible bands (α=5°)(a): O4 DSCD; (b): H2O DSCD; (c): H2O DSCD/O4 DSCD
    Fig. 5. The DSCD in the ultraviolet and visible bands (α=5°)
    (a): O4 DSCD; (b): H2O DSCD; (c): H2O DSCD/O4 DSCD
    Correlation analysis of O4 and H2O DSCD in in the ultraviolet and visible bands(a): H2O DSCD; (b): O4 DSCD; (c): H2O DSCD/O4 DSCD
    Fig. 6. Correlation analysis of O4 and H2O DSCD in in the ultraviolet and visible bands
    (a): H2O DSCD; (b): O4 DSCD; (c): H2O DSCD/O4 DSCD
    The absorption cross section of H2O and other trace gases (O4, HONO and HCHO) in the ultraviolet band
    Fig. 7. The absorption cross section of H2O and other trace gases (O4, HONO and HCHO) in the ultraviolet band
    Example of DOAS fitting retrieval for O4, HONO and HCHO(a): The water vapor absorption reference cross section was not included in the fitting process;(b): The water vapor absorption reference cross section was included in the fitting process
    Fig. 8. Example of DOAS fitting retrieval for O4, HONO and HCHO
    (a): The water vapor absorption reference cross section was not included in the fitting process;(b): The water vapor absorption reference cross section was included in the fitting process
    SpectrometerLocation and TimeAngle setting
    NameAvantesCityXi'anAzimuth
    Spectral range294~460 nmLongitude108.05°EElevation1°, 2°, 3°, 4°, 5°, 6°, 8°, 10°, 20°, 30°, 90°
    FWHM0.35 nmLatitude34.53°N
    Temperature control25 ℃Measuring time4:00—22:00 LT
    Table 1. Parameter settings of MAX-DOAS regional station in Qianxian, Xi'an
    ParameterSourceultraviolet
    351~370 nm
    visible
    434~455 nm
    NO2298 K, 220 K
    O3223 K, 293 K
    O4293 K
    H2OHITEMP, 296 K
    H2OPOKAZATEL, 298 K
    HCHO297 K
    HONO296 K
    BrO223 K
    RingCalculated from QDOAS and additional Ring spectrum multiplied by λ-4
    Polynomial
    degree
    -55
    Table 2. Parameter settings of water vapor DOAS fitting
    ParameterO4
    (338.2~370 nm)
    HONO
    (337~375 nm)
    HCHO
    (336.5~359 nm)
    NO2
    O3
    O4
    HCHO
    HONO
    BrO
    Ring
    Polynomial degree354
    Table 3. The DOAS fitting parameter for O4, HONO and HCHO
    Hong-mei REN, Ang LI, Zhao-kun HU, Pin-hua XIE, Jin XU, Ye-yuan HUANG, Xiao-mei LI, Hong-yan ZHONG, Hai-rong ZHANG, Xin TIAN, Bo REN, Jiang-yi ZHENG, Shuai WANG, Wen-xuan CHAI. Measurement of Water Vapor Absorption in the Ultraviolet Band Using MAX-DOAS and Evaluation of Its Influence on DOAS Retrieval[J]. Spectroscopy and Spectral Analysis, 2022, 42(10): 3314
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