• Spectroscopy and Spectral Analysis
  • Vol. 40, Issue 10, 3161 (2020)
Yin HU, Min-chang WANG, Qing PAN, Yan-li NING, Ying KANG, Ming WANG, Jie-yu LUAN, and Zhi-qun CHEN
Author Affiliations
  • Xi’an Modern Chemistry Research Institute, Xi’an 710065, China
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    DOI: 10.3964/j.issn.1000-0593(2020)10-3161-06 Cite this Article
    Yin HU, Min-chang WANG, Qing PAN, Yan-li NING, Ying KANG, Ming WANG, Jie-yu LUAN, Zhi-qun CHEN. Spectroscopic Analysis of Endo and Exo-Tetrahydrodicyclopentadiene[J]. Spectroscopy and Spectral Analysis, 2020, 40(10): 3161 Copy Citation Text show less
    Chemical structure of endo-THDCPD
    Fig. 1. Chemical structure of endo-THDCPD
    Preparation reaction of endo-THDCPD
    Fig. 2. Preparation reaction of endo-THDCPD
    Chemical structure of exo-THDCPD
    Fig. 3. Chemical structure of exo-THDCPD
    Preparation reaction of exo-THDCPD
    Fig. 4. Preparation reaction of exo-THDCPD
    The 1H NMR spectrum of exo-THDCPD
    Fig. 5. The 1H NMR spectrum of exo-THDCPD
    The 13C NMR spectrum of exo-THDCPD
    Fig. 6. The 13C NMR spectrum of exo-THDCPD
    The 1H NMR spectrum of endo-THDCPD
    Fig. 7. The 1H NMR spectrum of endo-THDCPD
    The 13C NMR spectrum of endo-THDCPD
    Fig. 8. The 13C NMR spectrum of endo-THDCPD
    Comparison of MS spectrometry between endo-THDCPD and exo-THDCPD
    Fig. 9. Comparison of MS spectrometry between endo-THDCPD and exo-THDCPD
    Comparison of infrared spectrum (a) and its partial enlargement (b) betweenn endo-THDCPD and exo-THDCPD
    Fig. 10. Comparison of infrared spectrum (a) and its partial enlargement (b) betweenn endo-THDCPD and exo-THDCPD
    Comparison of Raman spectrum (a) and its partial enlargement (b) between endo-THDCPD and exo-THDCPD
    Fig. 11. Comparison of Raman spectrum (a) and its partial enlargement (b) between endo-THDCPD and exo-THDCPD
    The THz spectrum of exo-THDCPD
    Fig. 12. The THz spectrum of exo-THDCPD
    The THz spectrum of endo-THDCPD
    Fig. 13. The THz spectrum of endo-THDCPD
    Comparison of THz spectrum between endo-THDCPD and exo-THDCPD
    Fig. 14. Comparison of THz spectrum between endo-THDCPD and exo-THDCPD
    No.endo-THDCPDexo-THDCPD归属
    δCδHδCδH
    123.071.42, 1.2728.761.45, 1.05CH2
    241.572.0840.651.93CH
    323.071.42, 1.2728.761.45*, 1.05*CH2
    441.572.0840.651.93CH
    545.492.3448.181.75CH
    645.492.3448.181.75CH
    726.981.49, 1.4332.421.82, 1.90CH2
    826.981.49, 1.4332.421.82, 1.90CH2
    928.741.6027.251.59, 1.13CH2
    1043.281.50, 1.3732.071.31, 0.88CH2
    Table 1. NMR spectrum data of endo-THDCPD and exo-THDCPD
    名称—CH2伸缩振动(γ-CH2/cm-1)—CH2弯曲振动(δ-CH2/ cm-1)
    endo-THDCPD2 947, 2 8731 483, 1 466, 1 454, 1 331, 1 303, 1 285, 745, 701
    exo-THDCPD2 946, 2 8661 468, 1 455, 1 331, 1 309, 1 297, 746, 733
    Table 2. IR and Raman spectrum data of endo-THDCPD and exo-THDCPD
    Yin HU, Min-chang WANG, Qing PAN, Yan-li NING, Ying KANG, Ming WANG, Jie-yu LUAN, Zhi-qun CHEN. Spectroscopic Analysis of Endo and Exo-Tetrahydrodicyclopentadiene[J]. Spectroscopy and Spectral Analysis, 2020, 40(10): 3161
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