• Spectroscopy and Spectral Analysis
  • Vol. 42, Issue 10, 3130 (2022)
Xuan HU1、1;, Zi-hui CHENG1、1; *;, Shu-chao ZHANG2、2;, and Lei SHI2、2;
Author Affiliations
  • 11. Guobiao (Beijing) Testing & Certification Co., Ltd., Beijing 100088, China
  • 22. China National Quality Supervision and Inspection Center for Light Metal, Zhengzhou 450041, China
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    DOI: 10.3964/j.issn.1000-0593(2022)10-3130-05 Cite this Article
    Xuan HU, Zi-hui CHENG, Shu-chao ZHANG, Lei SHI. Matrix Separation-Determination of Rare Earth Oxides in Bauxite by Inductively Coupled Plasma-Atomic Emission Spectrometry[J]. Spectroscopy and Spectral Analysis, 2022, 42(10): 3130 Copy Citation Text show less
    Schematic diagram of dissolution process
    Fig. 1. Schematic diagram of dissolution process
    编号赤泥/g氢氧化钠/g溶解状况
    10.254.0溶清, Pr6O11相对标准偏差稍大
    20.255.0溶清, Pr6O11相对标准偏差稍大
    30.256.0溶清, Pr6O11相对标准偏差稍大
    40.257.0溶清, Pr6O11相对标准偏差稍大
    50.504.0赤泥覆盖不完全
    60.505.0溶清
    70.506.0溶清
    80.507.0试样和熔剂溢出坩埚
    91.04.0后续过滤和洗涤困难
    101.05.0后续过滤和洗涤困难
    111.06.0后续过滤和洗涤困难
    121.07.0后续过滤和洗涤困难
    Table 1. The investigation of amount of sample and flux
    元素波长/nm元素波长/nm
    La408.6Nd406.1
    Ce418.6Sc361.3
    Pr410.0Y377.4
    Table 2. Spectral line of rare earth elements
    基体La2O3CeO2Pr6O11Nd2O3Sc2O3Y2O3
    /0.201.000.200.200.200.20
    1 500 μg·mL-1 Fe2O30.120.860.150.170.180.18
    3 500 μg·mL-1 Al2O30.150.750.140.160.190.18
    10 μg·mL-1 Fe2O30.211.100.210.200.190.18
    20 μg·mL-1 Al2O30.211.200.200.220.200.19
    Table 3. Changes of content of rare earth oxides before and after separation of matrix/μg·mL-1
    稀土
    氧化物
    线性方程相关
    系数
    检出限
    /%
    测定下
    限/%
    La2O3y=51.91x+0.850.999 90.000 80.002 7
    CeO2y=8.35x+0.0970.999 90.001 00.003 3
    Pr6O11y=7.35x+0.220.999 90.001 20.004 0
    Nd2O3y=7.39x-0.320.999 90.001 50.005 0
    Sc2O3y=176.63x-0.581.000 00.000 20.000 5
    Y2O3y=22.40x-0.510.999 90.000 20.000 5
    Table 4. Linear equation, correlation coefficient and detection limit
    稀土
    氧化物
    本底值
    /mg
    RSD
    /%
    加标量
    /mg
    测定总量
    /mg
    回收率
    /%
    La2O30.0383.50.0200.058102.5
    CeO20.0853.20.0500.1398.0
    Pr6O110.0216.50.0100.03092.7
    Nd2O30.0367.20.0200.05385.0
    Sc2O30.0342.50.0200.054100.0
    Y2O30.0323.10.0200.053105.0
    Table 5. Precision and recovery rate tests of the method
    测定方法La2O3CeO2Pr6O11Nd2O3Sc2O3Y2O3
    ICP-OES/%0.007 50.0170.004 10.007 20.006 80.006 3
    ICP-MS/%0.007 70.0180.004 50.007 80.006 60.006 1
    相对误差/%2.675.889.768.332.943.17
    Table 6. Analytical results of rare earth oxide in red mud
    Xuan HU, Zi-hui CHENG, Shu-chao ZHANG, Lei SHI. Matrix Separation-Determination of Rare Earth Oxides in Bauxite by Inductively Coupled Plasma-Atomic Emission Spectrometry[J]. Spectroscopy and Spectral Analysis, 2022, 42(10): 3130
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