Fig. 1. Garnet samples from three localities
A1—A14: Samples from Australia; T1—T5: Samples from Tanzania; ZP1—ZR222: Samples from Zambia
Fig. 2. Samples from three localities plotted according to different pairs of chemical components
(a): MgO; (b): Co; (c): CaO; (d): Li
Fig. 3. Chondrite-normalized REE patterns of garnets from three localities
Chondrite data cited from Ref. [8]
Fig. 4. Raman spectra of several samples
ZP222: Zambia; T3: Tansania; A4: Australia
Fig. 5. Colors of garnets from three localities distributed in L*a*b* color space (only a*, b* coordinates were drawn)
Fig. 6. UV-Vis spectrum of garnets from three localities
(a): Group ZP from Zambia; (b): Group ZR from Zambia; (c): Group from Tanzania; (d): Group from Australia
Fig. 7. Linear Regression of ratio between absorbanceat 368 and 503 nm (a) and b*, and linear Regression of ratio between absorbanceat 425 and 503 nm and b* (b)
| 坦桑尼亚 | 赞比亚 | 澳大利亚 |
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主量成分/Wt% | MgO | 13.5~14.5 | 12.9~17.8 | 10.3~10.7 | Al2O3 | 21.6~21.9 | 21.6~22.4 | 21.3~21.6 | SiO2 | 41.5~41.6 | 40.4~41.9 | 40~40.7 | CaO | 0.41~0.87 | 0.52~1.97 | 0.86~0.98 | MnO | 0.08~0.24 | 0.18~0.91 | 0.99~1.18 | FeO | 20.2~21.2 | 16.2~21.8 | 24.5~25.1 | 微量元素/ppmw | Li | 19.5~36.3 | 4.68~12 | 2.12~3.79 | Na | 130~297 | 70.5~272 | 165~200 | P | 598~962 | 278~759 | 381~462 | Sc | 8.06~52.9 | 16.3~66.4 | 89.3~101 | Ti | 16.5~65.3 | 6.65~218 | 113~262 | V | 3.02~32.7 | 14.7~71.4 | 22.8~32 | Co | 11.9~13.3 | 5.3~28.7 | 16.6~18.6 | Zn | 3.76~62.9 | 24.7~67.7 | 40.8~49.5 | Ga | 4.72~8.82 | 5~10.8 | 6.95~9.9 | Y | 20.8~49.6 | 14.5~146 | 326~417 | Zr | 17.1~23.6 | 12.3~46 | 21.6~26.5 | Hf | 0.23~0.4 | 0.29~0.77 | 0.22~0.41 | | 15.9~31.8 | 10.2~88.1 | 147~229 |
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Table 1. Range of chemical components in garnet samples from three localities
变量 | 典则判别函数 | 标准化典则判别函数 |
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F1系数 | F2系数 | F1std系数 | F2std系数 |
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MgO | 5.386 | 0.999 | 7.229 | 1.341 | Al2O3 | -1.104 | 2.764 | -0.204 | 0.510 | CaO | -6.766 | 7.477 | -2.515 | 2.779 | MnO | 3.668 | 11.889 | 0.621 | 2.014 | FeO | 4.797 | 0.575 | 6.890 | 0.827 | Li | -0.142 | -0.812 | -0.448 | -2.562 | Na | -0.005 | 0.014 | -0.269 | 0.842 | P | 0.001 | 0.003 | 0.086 | 0.463 | Sc | 0.195 | -0.101 | 2.566 | -1.330 | Ti | 0.011 | -0.005 | 0.737 | -0.341 | V | -0.010 | 0.066 | -0.146 | 0.987 | Co | -0.679 | 0.223 | -3.215 | 1.054 | Zn | 0.006 | 0.140 | 0.093 | 2.013 | Ga | -0.585 | -0.317 | -0.916 | -0.497 | Y | 0.040 | -0.006 | 1.466 | -0.223 | Zr | -0.179 | -0.030 | -1.16 | -0.192 | 1(常数项) | -140.973 | -99.922 | - | - |
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Table 2. Coefficients of different element variables in canonical discriminant functions and standard canonical discriminant functions
归属[9] | 峰位 | 振动模式[9] | 澳大利亚/cm-1 | 坦桑尼亚/cm-1 | 赞比亚/cm-1 |
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Si—O伸缩振动 | a | F2g | 1 045~1 050 | 1 049~1 055 | 1 050~1 058 | b | A1g | 917~920 | 921~923 | 920~928 | c | F2g | 865~867 | 866~870 | 864~871 | Si—O弯曲振动 | d | F2g | 635~639 | 638~641 | 639~647 | e | A1g | 556~560 | 559~561 | 559~566 | f | F2g | 501~505 | 504~507 | 505~512 | [SiO4]转动 | g | F2g | 349~352 | 354~355 | 354~358 | [SiO4]平动 | h | Eg/F2g | 207~211 | 209~212 | 206~212 |
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Table 3. Vibration modes of different Raman peaks and wavenumber ranges of Raman peaks of samples from different localities(peaks are consistent with Fig.4)
拉曼峰位 (波数) | 和不同化学成分(含量)的相关系数 |
---|
MgO | FeO | MnO | CaO |
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a | 0.875 | -0.880 | -0.637 | -0.058 | b | 0.926 | -0.893 | -0.685 | -0.348 | c | 0.590 | -0.553 | -0.424 | -0.466 | d | 0.855 | -0.839 | -0.658 | -0.139 | e | 0.918 | -0.883 | -0.698 | -0.275 | f | 0.905 | -0.900 | -0.753 | -0.141 | g | 0.973 | -0.973 | -0.785 | 0.064 | h | -0.299 | 0.268 | 0.467 | -0.072 |
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Table 4. Pearson correlation coefficients between wavenumber of Raman peaks and content of chemical components
波长/nm | 致色离子 | 能级跃迁[10] |
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368 | Fe3+ | 6A1g→4Eg(D) | 398 | Fe2+ | 5Eg→3A1g(3G) | 407 | Mn2+ | 6A1g→4A1g+4Eg(4G) | 425 | Fe3+ | 6A1g→4A1g+4Eg(4G) | 461, 503, 523 | Fe2+ | 5Eg→3E1g(3H) | 574, 617, 696 | Fe2+ | 5Eg→3T1g(3H) |
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Table 5. UV-Vis absorption bands and their color-causing ions and energy level transitions