• Spectroscopy and Spectral Analysis
  • Vol. 42, Issue 3, 896 (2022)
Fang-fang WANG*, Xiao-dong ZHANG1; 2; *;, Xiao-duo PING1;, Shuo ZHANG1;, and Xiao LIU1; 2;
Author Affiliations
  • 1. School of Energy Science and Engineering, Henan Polytechnic University, Jiaozuo 454000, China
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    DOI: 10.3964/j.issn.1000-0593(2022)03-0896-08 Cite this Article
    Fang-fang WANG, Xiao-dong ZHANG, Xiao-duo PING, Shuo ZHANG, Xiao LIU. Effect of Acidification Pretreatment on the Composition and Structure of Soluble Organic Matter in Coking Coal[J]. Spectroscopy and Spectral Analysis, 2022, 42(3): 896 Copy Citation Text show less
    FTIR spectra of coal samples
    Fig. 1. FTIR spectra of coal samples
    FTIR curve-fitting results of RC and DC
    Fig. 2. FTIR curve-fitting results of RC and DC
    Types and relative contents of low molecular compounds in RC extract
    Fig. 3. Types and relative contents of low molecular compounds in RC extract
    Types and relative contents of low molecular compounds in DC extract
    Fig. 4. Types and relative contents of low molecular compounds in DC extract
    Composition and relative content of heteroatom compounds in RC extract
    Fig. 5. Composition and relative content of heteroatom compounds in RC extract
    Composition and relative content of heteroatom compounds in DC extract
    Fig. 6. Composition and relative content of heteroatom compounds in DC extract
    SampleProximate analysis/(%, daf)Ultimateanalysis/%
    CHO*NSMadAdVdafFCdaf
    RC81.104.7912.371.320.420.8215.2317.8182.19
    DC79.054.4614.711.340.440.850.4319.4080.60
    Table 1. Ultimate and proximate analyses of coal samples
    样品25%50%75%100%
    RC0.120.250.420.61
    DC0.450.550.610.68
    Table 2. Extraction rate of coking coal with different concentrations of THF before and after deashing
    样品CHC=CCH3CH2, CH3CH2CH3—O—
    700~900
    cm-1
    1 545~1 645
    cm-1
    1 420~1 350
    cm-1
    2 850~2 800
    cm-1
    2 943~2 850
    cm-1
    2 990~2 943
    cm-1
    3 600~3 200
    cm-1
    RC2.926.853.955.935.031.7118.46
    R-15.364.284.264.303.561.1910.46
    R-23.372.752.782.082.420.2511.16
    R-33.773.082.572.102.810.429.76
    R-411.537.138.198.037.132.7512.09
    DC8.149.615.252.804.280.9233.15
    D-17.959.547.442.914.321.1326.19
    D-27.9010.396.013.284.381.1325.86
    D-36.489.765.682.834.911.2432.95
    D-414.5711.968.854.535.171.8017.45
    Table 3. Relative content of each functional group in each coal sample
    样品I1I2I3I4
    RC2.470.204.372.94
    R-12.710.514.632.99
    R-22.270.586.209.68
    R-32.280.585.676.69
    R-43.240.564.722.59
    DC1.860.9911.820.22
    D-11.810.979.010.27
    D-21.880.907.90/
    D-31.820.886.550.29
    D-41.541.134.870.35
    Table 4. Characteristic parameters of infrared spectrum of coking coal
    化合物相对含量/%
    25%
    THF
    50%
    THF
    75%
    THF
    100%
    THF
    1-碘十三烷3.813.84//
    甲基环己基二甲氧基硅烷3.453.58/3.87
    4-乙基十四烷4.461.24//
    1,3-二氯丙烷2.70/7.79/
    庚烷10.4116.717.5616.08
    2,4-二叔丁基苯酚4.714.351.71/
    3-乙基二十四烷0.321.780.691.12
    二十七烷///5.35
    三乙基磷酸酯/7.86/4.70
    十九烷//0.794.28
    9-辛基十七烷1.921.280.092.57
    二乙胺/11.8649.996.80
    1-环丙基乙醇13.82///
    3-甲基曲金刚烷0.64/0.120.19
    Table 5. Main compounds in coal extract of RC
    化合物相对含量/%
    25%
    THF
    50%
    THF
    75%
    THF
    100%
    THF
    2-甲基十七烷24.257.06//
    2-甲基十八烷10.198.850.090.09
    2-甲基十五烷3.00///
    3-甲基十七烷1.833.411.43/
    2-甲基十六烷9.663.622.74/
    3-甲基十五烷5.11///
    二十三烷//6.79/
    3-甲基十八烷1.326.69//
    丙烷0.721.46//
    二十烷/3.2226.406.74
    十九烷3.1226.803.110.90
    己烷//2.690.76
    十六烷6.13///
    二十二烷/0.6242.8768.89
    Table 6. Main compounds in the extract of DC
    Fang-fang WANG, Xiao-dong ZHANG, Xiao-duo PING, Shuo ZHANG, Xiao LIU. Effect of Acidification Pretreatment on the Composition and Structure of Soluble Organic Matter in Coking Coal[J]. Spectroscopy and Spectral Analysis, 2022, 42(3): 896
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