Bacterial Cellulose Based Nano-biomaterials for Energy Storage Applications

Li-Na MA; Chuan SHI; Ning ZHAO; Zhi-Jie BI; Xiang-Xin GUO; Yu-Dong HUANG

doi:10.15541/jim20190108

Journals >Journal of Inorganic Materials >Volume 35 >Issue 2 >Page 145 > Article

Journal of Inorganic Materials
Vol. 35, Issue 2, 145 (2020)

Bacterial Cellulose Based Nano-biomaterials for Energy Storage Applications

Li-Na MA¹, Chuan SHI², Ning ZHAO², Zhi-Jie BI², Xiang-Xin GUO^2、*, and Yu-Dong HUANG³

Author Affiliations

¹College of Chemistry & Chemical Engineering, Qingdao University, Qingdao 266071, China

²College of Physical Sciences, Qingdao University, Qingdao 266071, China

³School of Chemistry and Chemical Engineering, Harbin Institute of Technology, Harbin 150001, China

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DOI: 10.15541/jim20190108 Cite this Article

Li-Na MA, Chuan SHI, Ning ZHAO, Zhi-Jie BI, Xiang-Xin GUO, Yu-Dong HUANG. Bacterial Cellulose Based Nano-biomaterials for Energy Storage Applications[J]. Journal of Inorganic Materials, 2020, 35(2): 145 Copy Citation Text

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(a) Photograph of the production line for BC[3]; (b) Schematic model of the plant cellulose fibrils (left) and the BC microfibers (right)[5]; (c) Photograph of BC slice; (d) SEM and (e)TEM images of BC[4]

1. (a) Photograph of the production line for BC^[3]; (b) Schematic model of the plant cellulose fibrils (left) and the BC microfibers (right)^[5]; (c) Photograph of BC slice; (d) SEM and (e)TEM images of BC^[4]

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(a) Schematic diagram for asymmetric supercapacitor device; (b) TEM images, (c) GCD curves, (d) specific capacitance and (e) cycle performance of N-CNF/MnO2[12]

2. (a) Schematic diagram for asymmetric supercapacitor device; (b) TEM images, (c) GCD curves, (d) specific capacitance and (e) cycle performance of N-CNF/MnO₂^[12]

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3. (a) Fabrication process of heteroatom-doped CNF; (b) Elemental mapping images of C, N, P, and O for N, P-CNF; (c) CV curves, (d) GCD curves and (e) cycling stability test of N,P-CNF supercapacitor^[2]

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4. (a) Synthesis scheme of PPY/BC/GO composites; SEM images of (b) pristine GO, (c) cross-linked BC/GO, (d) a single layer and (e) multilayers of PPY/BC/GO hybrid, and (f) PPY/BC core-sheath hybrid^[38]

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5. Photographs of (a) BC paper and (b) flexible CNT/BC paper; (c) Cross-sectional image of CNT/BC paper; (d) GCD curve and (e) CV curves for CNT/BC/ion gel flexible supercapacitors; (f) Photograph of a LED turned on by the flexible supercapacitors^[41]

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6. (a) Photographs of CNT/BC paper and PANI/CNT/BC paper; (b) SEM image and (c) CV curves of PANI/CNT/BC electrode; (d) Schematic structure, (e) digital images and (f) CV curves for flexible supercapacitor^[1]

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7. (a) SEM and (b) TEM images of Ni(OH)₂/RGO/BC; (c, d) Cross-sectional SEM micrographs of Ni(OH)₂/RGO/BC; (e) CV and (f) GCD curves of Ni(OH)₂/RGO/BC electrode^[58]

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Material	Function of BC	Potential window/V	Capacitance/(F∙g^-1)	Rate capability	Stability(cycle number)	Highest energy density/(Wh∙kg^-1)	Highest powerdensity/(kW∙kg^-1)	Ref.
CO₂ activated CNF	Active material	-0.2-0.2(vs. Ag/AgCl)	42 (1 mV∙s^-1)(659 mF∙cm^-2)	70% (10 mV∙s^-1)	—	—	—	[14]
CNF	Active material	-1-0(vs. Ag/AgCl)	108 (2 A∙g^-1)	—	—	—	—	[15]
PCN/CNF	Active material	-1-0(vs. Hg/HgO)	261 (2 mV∙s^-1)	76.6 (500 mV∙s^-1)	97.6% (10000)	—	—	[18]
PCN/CNF//PCN/CNF	Active material	0-1.8	—	—	94.8% (10000)	20.4	17.8	[18]
N,P-CNF//N,P-CNF	Active material	0-1	204.9(1 A∙g^-1)	—	100% (4000)	7.76	26.1	[2]
N-S-CNF-700	Active material	0-1(vs. Ag/AgCl)	171.2(0.5 A∙g^-1)	105.2 (10 A∙g^-1)	>90% (1000)	—	—	[20]
KOH activated N-CNF	Active material	0.9-0.1(vs. SHE)	296 (2 mV∙s^-1)	75% (500 mV∙s^-1)	99% (10000)	—	—	[12]
N-CNF	Active material	-1-0(vs. Ag/AgCl)	120 (1 A∙g^-1)	—	98.2% (5000)	—	—	[13]
N,P-CNWs	Active material	-1-0(vs. Hg/HgO)	258 (1 A∙g^-1)	208 (10 A∙g^-1)	98% (30000)	—	—	[26]
N,P-CNWs//N,P-CNWs	Active material	0-1	74 (0.5 A∙g^-1)	—	87% (6000)	5.4	0.2	[26]
CNF aerogels	Active material	-1-0(vs. Ag/AgCl)	194.7 (0.5 A∙g^-1)	108.7(10 A∙g^-1)	94% (5000)	—	—	[19]

Table 1. BC-based carbon material electrodes for supercapacitor

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Material	Function of BC	Potential window/V	Capacitance/(F∙g^-1)	Rate capability	Stability (cycle number)	Highest energy density/(Wh∙kg^-1)	Highest powerdensity/(kW∙kg^-1)	Ref.
CNF@MnO₂	Active material	0-1(vs. Ag/AgCl)	254.64 (1 A∙g^-1)	77.53% (10 A∙g^-1)	—	—	—	[24]
CNF@MnO₂//N-CNF	Active material	0-2	—	—	95.4% (2000)	32.91	284.63	[24]
Ni₃S₂/CNF	Active material	0-0.6(vs. Ag/AgCl)	957 (1 A∙g^-1)	703 (8 A∙g^-1)	16.5% (1000)	—	—	[15]
Ni₃S₂/CNF//CNF	Active material	0-1.7	56.6 (1 A∙g^-1)	35.4 (10 A∙g^-1)	97% (2500)	25.8	0.425	[15]
CNF/MnO₂	Active material	0.15-1.15(vs. SCE)	273 (2 mV∙s^-1)	75% (100 mV∙s^-1)	—	—	—	[12]
CNF//CNF/MnO₂	Active material	0-2	113 (20 mV∙s^-1)	53%(10~200 mV∙s^-1)	92% (5000)	63	8	[12]
N-CNF@LDH	Active material	0-0.5(Ag/AgCl)	1949.5 (1 A∙g^-1)	54.7 (10 A∙g^-1)	74.4% (5000)	—	—	[23]
N-CNF@LDH//N-CNF	Active material	0-1.6	101.9 (1 A∙g^-1)	63.8 (10 A∙g^-1)	89.3% (2500)	36.3	8	[23]

Table 2. BC-based composites electrodes for supercapacitor

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Material	Function of BC	Potential window/V	Capacitance/(mF∙cm^-2)	Capacitance/(F∙g^-1)	Rate capability	Stability (cycle number)	Highest energy density	Highest powerdensity	Ref.
N-CNF/RGO/BC	Active material & substrate	-0.8-0.2(vs. Hg/HgO)	2106(1 mV∙s^-1)	263	76%(50 mV∙s^-1)	100% (2×10⁴)	—	—	[45]
N-CNF/RGO/BC//N-CNF/RGO/BC	Active material & substrate	0-1	810(2 mV∙s^-1)	—	755(50 mV∙s^-1)	99.6% (10⁴)	0.11 mWh∙cm^-2	27mW∙cm^-2	[46]
N,P-CNF/RGO/BC	Active material & substrate	-0.8-0.2(vs. Hg/HgO)	1900(2 mV∙s^-1)	244.8	1554(50 mV∙s^-1)	100% (2×10⁴)	—	—	[16]
N,P-CNF/RGO/BC//N,P-CNF/RGO/BC	Active material & substrate	0-1	690(2 mV∙s^-1)	—	620(40 mV∙s^-1)	99.6% (1×10⁴)	0.096mWh∙cm^-2	19.98mW∙cm^-2	[16]
BC/GO electrode	Scaffold	-0.2-0.8(vs. SCE)	—	160 (0.4 A∙g^-1)	68(2 A∙g^-1)	90.3% (2×10³)	—	—	[44]
BC/CNT/ion gel supercapacitors	Substrate	0-3	18.8(100 mV∙s^-1)	46.9	42.0(500 mV∙s^-1)	99.5% (5×10⁴)	15.5Wh∙kg^-1	1.5kW∙kg^-1	[41]
a-CNF//BC gel//a-CNF supercapacitors	Active material & electrolyte & separator	0-1	289(0.1 mA∙cm^-2)	—	70%(10 mA∙cm^-2)	66.7% (100)	—	—	[60]

Table 3. BC-based electrodes for flexible EDLCs

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