Author Affiliations
1School of Environment and Architecture, University of Shanghai for Science and Technology, Shanghai 200093, China2School of Information Science and Engineering, Fudan University, Shanghai 200433, Chinashow less
Fig. 1. Spectroscopic gas sensing system based on FTIR and hollow waveguide
Fig. 2. Fingerprint absorption of gases and typical loss spectra of waveguides. (a) Normalized absorption coefficient; (b) loss spectra of waveguides
Fig. 3. Typical loss spectra of PI/Ag, FCP/Ag, and PS/Ag hollow waveguides
Fig. 4. Schematic diagram of sample gas preparation by bubbling method
Fig. 5. Standard absorption of HN3 and loss spectra of hollow waveguides before and after injecting HN3 sample gas. (a) Ag waveguide; (b) AgI/Ag waveguide; (c) SiO2/Ag waveguide; (d) COP/Ag waveguide
Fig. 6. High resolution loss spectra of Ag waveguide filled with wet HN3 gas
Fig. 7. Loss spectra of hollow waveguides with HCl sample gas, and standard absorption of HCl is added for comparison in the insets. (a) AgI/Ag waveguide; (b) Ag waveguide
Fig. 8. Original loss spectra and loss spectra of the hollow waveguide before and after importing the HCl sample gas. (a) AgI/Ag waveguide; (b) Ag waveguide
Fig. 9. Absorption spectrum of cyclohexane volatiles
Waveguide | Concentration hydrochloric acid sample |
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5% | 4% | 3% | 1% | 0.5% |
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AgI/Ag | × | √ | √ | √ | √ | COP/Ag | × | × | √ | √ | √ | SiO2/Ag | × | × | × | × | √ | PC/Ag | × | × | × | × | × |
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Table 1. Durability of waveguide to diluted hydrochloric acid liquid
Waveguide | Property |
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Loss | Applicable wavelength band /μm | Nonapplicable wavelength /μm | Alkali resistance | Acid resistance | Resistant to organic solvent volatiles | High temperature |
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AgI/Ag | A | 2--12 | | A | A | A | C | COP/Ag | A | 1--12 | 3.5 | A | B+ | C | A | SiO2/Ag | A | 2--5 | 3.5 | A | B- | B- | A- | Ag only | B | 0.4--12 | | A | C | A | A- | FCP/Ag | A- | 2--3 | | A | B- | B | A | PI/Ag | A- | 2--3 | | A | B- | B | A |
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Table 2. Summary of characteristics of the waveguide for anti-corrosion