• Acta Optica Sinica
  • Vol. 40, Issue 19, 1906002 (2020)
Zhiyun Zhou1, Debao Li1, Su Wan1, and Yiwei Shi2、*
Author Affiliations
  • 1School of Environment and Architecture, University of Shanghai for Science and Technology, Shanghai 200093, China
  • 2School of Information Science and Engineering, Fudan University, Shanghai 200433, China
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    DOI: 10.3788/AOS202040.1906002 Cite this Article Set citation alerts
    Zhiyun Zhou, Debao Li, Su Wan, Yiwei Shi. Durability of Waveguide Absorption Cell for a Spectroscopic Gas Sensing System[J]. Acta Optica Sinica, 2020, 40(19): 1906002 Copy Citation Text show less
    Spectroscopic gas sensing system based on FTIR and hollow waveguide
    Fig. 1. Spectroscopic gas sensing system based on FTIR and hollow waveguide
    Fingerprint absorption of gases and typical loss spectra of waveguides. (a) Normalized absorption coefficient; (b) loss spectra of waveguides
    Fig. 2. Fingerprint absorption of gases and typical loss spectra of waveguides. (a) Normalized absorption coefficient; (b) loss spectra of waveguides
    Typical loss spectra of PI/Ag, FCP/Ag, and PS/Ag hollow waveguides
    Fig. 3. Typical loss spectra of PI/Ag, FCP/Ag, and PS/Ag hollow waveguides
    Schematic diagram of sample gas preparation by bubbling method
    Fig. 4. Schematic diagram of sample gas preparation by bubbling method
    Standard absorption of HN3 and loss spectra of hollow waveguides before and after injecting HN3 sample gas. (a) Ag waveguide; (b) AgI/Ag waveguide; (c) SiO2/Ag waveguide; (d) COP/Ag waveguide
    Fig. 5. Standard absorption of HN3 and loss spectra of hollow waveguides before and after injecting HN3 sample gas. (a) Ag waveguide; (b) AgI/Ag waveguide; (c) SiO2/Ag waveguide; (d) COP/Ag waveguide
    High resolution loss spectra of Ag waveguide filled with wet HN3 gas
    Fig. 6. High resolution loss spectra of Ag waveguide filled with wet HN3 gas
    Loss spectra of hollow waveguides with HCl sample gas, and standard absorption of HCl is added for comparison in the insets. (a) AgI/Ag waveguide; (b) Ag waveguide
    Fig. 7. Loss spectra of hollow waveguides with HCl sample gas, and standard absorption of HCl is added for comparison in the insets. (a) AgI/Ag waveguide; (b) Ag waveguide
    Original loss spectra and loss spectra of the hollow waveguide before and after importing the HCl sample gas. (a) AgI/Ag waveguide; (b) Ag waveguide
    Fig. 8. Original loss spectra and loss spectra of the hollow waveguide before and after importing the HCl sample gas. (a) AgI/Ag waveguide; (b) Ag waveguide
    Absorption spectrum of cyclohexane volatiles
    Fig. 9. Absorption spectrum of cyclohexane volatiles
    WaveguideConcentration hydrochloric acid sample
    5%4%3%1%0.5%
    AgI/Ag×
    COP/Ag××
    SiO2/Ag××××
    PC/Ag×××××
    Table 1. Durability of waveguide to diluted hydrochloric acid liquid
    WaveguideProperty
    LossApplicable wavelength band /μmNonapplicable wavelength /μmAlkali resistanceAcid resistanceResistant to organic solvent volatilesHigh temperature
    AgI/AgA2--12AAAC
    COP/AgA1--123.5AB+CA
    SiO2/AgA2--53.5AB-B-A-
    Ag onlyB0.4--12ACAA-
    FCP/AgA-2--3AB-BA
    PI/AgA-2--3AB-BA
    Table 2. Summary of characteristics of the waveguide for anti-corrosion
    Zhiyun Zhou, Debao Li, Su Wan, Yiwei Shi. Durability of Waveguide Absorption Cell for a Spectroscopic Gas Sensing System[J]. Acta Optica Sinica, 2020, 40(19): 1906002
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