• Journal of Inorganic Materials
  • Vol. 38, Issue 5, 544 (2023)
Dong FAN1、2, Xin ZHONG1、*, Yawen WANG1, Zhenzhong ZHANG2、*, Yaran NIU1, Qilian LI3, Le ZHANG3, and Xuebin ZHENG1
Author Affiliations
  • 11. Shanghai Institute of Ceramics, Chinese Academy of Sciences, Shanghai 200050, China
  • 22. College of Materials Science and Engineering, Nanjing Tech University, Nanjing 211816, China
  • 33. Avic Manufacturing Technology Institute, Beijing 100024, China
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    DOI: 10.15541/jim20220532 Cite this Article
    Dong FAN, Xin ZHONG, Yawen WANG, Zhenzhong ZHANG, Yaran NIU, Qilian LI, Le ZHANG, Xuebin ZHENG. Corrosion Behavior and Mechanism of Aluminum-rich CMAS on Rare-earth Silicate Environmental Barrier Coatings:[J]. Journal of Inorganic Materials, 2023, 38(5): 544 Copy Citation Text show less
    XRD patterns of powders and as-sprayed coatings
    1. XRD patterns of powders and as-sprayed coatings
    XRD pattern of CMAS powders
    S1. XRD pattern of CMAS powders
    XRD patterns of coatings after CMAS corrosion for 4 and 25 h
    2. XRD patterns of coatings after CMAS corrosion for 4 and 25 h
    Surface microstructures of coatings after corrosion for 4 and 25 h
    3. Surface microstructures of coatings after corrosion for 4 and 25 h
    Cross-sectional microstructures of coatings after CMAS corrosion for 4 h
    4. Cross-sectional microstructures of coatings after CMAS corrosion for 4 h
    Surface and cross-sectional microstructures of as-sprayed coatings
    S2. Surface and cross-sectional microstructures of as-sprayed coatings
    Cross-sectional microstructures of the X1-Gd2SiO5 coating after corrosion for 25 h
    5. Cross-sectional microstructures of the X1-Gd2SiO5 coating after corrosion for 25 h
    Schematic diagrams of different coatings under CMAS molten salt corrosion at 1400 ℃
    6. Schematic diagrams of different coatings under CMAS molten salt corrosion at 1400 ℃
    ParameterRE2SiO5 (RE=Gd, Y, Er)
    Primary Ar/(L·min-1)43
    Secondary H2/(L·min-1)12
    Carrier Ar/(L·min-1)2.3
    Spray distance/mm230
    Table 1. Technical parameters used for plasma spraying
    XRF/(%,in mol)CaOMgOAlO1.5SiO2
    CMAS27.878.7926.2238.52
    Table 2. Chemical compositions of CMAS powders
    EDS/(%, in atom) GdYErSiOCaAlMg
    Point 120.6019.6251.738.02
    Point 226.0417.5550.575.83
    Point 326.9515.1650.787.10
    Point 414.035.7252.274.0120.313.66
    Table 3. EDS elemental compositions of the marked regions in Fig. 3
    EDS/(%, in atom)GdYErSiOCaAlMg
    Point 119.21—-11.7060.658.44
    Point 21.1613.0659.3713.7810.182.45
    Point 315.2916.0061.826.89
    Point 47.1815.5050.179.5812.145.43
    Point 50.9613.5659.6213.0310.402.42
    Point 620.2712.1161.126.50
    Point 78.7010.9559.158.0910.954.65
    Point 80.923.2958.7419.613.292.07
    Table 4. EDS elemental compositions of the marked regions in Fig. 4
    EDS/(%, in atom) GdYErSiOCaAlMg
    Point 124.4816.2251.617.68
    Point 21.0512.6259.6314.259.782.66
    Point 326.7015.7850.127.40
    Point 417.108.2351.252.9216.414.09
    Point 50.9414.2357.3613.9411.981.54
    Point 628.8012.7752.226.22
    Point 77.1213.0549.267.0818.265.24
    Table 5. EDS elemental compositions of the marked regions in Fig. 5
    Dong FAN, Xin ZHONG, Yawen WANG, Zhenzhong ZHANG, Yaran NIU, Qilian LI, Le ZHANG, Xuebin ZHENG. Corrosion Behavior and Mechanism of Aluminum-rich CMAS on Rare-earth Silicate Environmental Barrier Coatings:[J]. Journal of Inorganic Materials, 2023, 38(5): 544
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