• Spectroscopy and Spectral Analysis
  • Vol. 42, Issue 7, 2309 (2022)
Jin-ke GUO*, Ji-long LU, Jun-shi SI, Wei ZHAO, Yang LIU, Tian-xin WANG, and Ya-wen LAI*;
Author Affiliations
  • College of Geo-exploration Science and Technology, Jilin University, Changchun 130026, China
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    DOI: 10.3964/j.issn.1000-0593(2022)07-2309-06 Cite this Article
    Jin-ke GUO, Ji-long LU, Jun-shi SI, Wei ZHAO, Yang LIU, Tian-xin WANG, Ya-wen LAI. Study on Heavy Metal in Soil by Portable X-Ray Fluorescence Spectrometry Based on Matrix Effect Correction and Correspondence Analysis[J]. Spectroscopy and Spectral Analysis, 2022, 42(7): 2309 Copy Citation Text show less
    Study area and sample distribution(a): China; (b): Jilin Province; (c): Urban area of Changchun City
    Fig. 1. Study area and sample distribution
    (a): China; (b): Jilin Province; (c): Urban area of Changchun City
    Linear regression images between pXRF data and ICP-MS data after correction
    Fig. 2. Linear regression images between pXRF data and ICP-MS data after correction
    The symmetrical normalization distribution map obtained by correspondence analysis
    Fig. 3. The symmetrical normalization distribution map obtained by correspondence analysis
    元素a元素b基体效应校正法传统线性回归法
    CrFey=0.143x+0.000 895z+32.545y=0.169x+57.947
    NiKy=0.514x-0.000 557z+32.307y=0.482x+21.918
    CuTiy=0.845x-0.002 574z+25.401y=0.835x+15.243
    ZnTiy=0.853x-0.010 800z+79.415y=0.806x+39.430
    PbMny=1.243x+0.058 472z-54.151y=1.274x-15.200
    Table 1. Regression equation by methods and the maximum influencing element for each element
    元素提升程度基体效应校正法传统线性回归法
    R2MAERMSER2MAERMSER2MAERMSE
    Cr75%22%22%0.6012.0562.3660.3432.6423.036
    Ni11%4%8%0.6441.5903.0070.5821.6633.263
    Cu3%4%11%0.8921.4512.9350.8641.5153.295
    Zn4%11%8%0.8436.55313.8950.8147.34015.145
    Pb10%14%40%0.9567.51012.2010.8708.77120.402
    Table 2. Statistical parameters and degree of improvement after correction of each method
    Jin-ke GUO, Ji-long LU, Jun-shi SI, Wei ZHAO, Yang LIU, Tian-xin WANG, Ya-wen LAI. Study on Heavy Metal in Soil by Portable X-Ray Fluorescence Spectrometry Based on Matrix Effect Correction and Correspondence Analysis[J]. Spectroscopy and Spectral Analysis, 2022, 42(7): 2309
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