• Spectroscopy and Spectral Analysis
  • Vol. 42, Issue 4, 1036 (2022)
Ling-ling ZHA1、*, Wei WANG2、2; *;, Yu XIE1、1;, Chang-gong SHAN2、2;, Xiang-yu ZENG2、2;, You-wen SUN2、2;, Hao YIN2、2;, and Qi-hou HU2、2;
Author Affiliations
  • 11. Department of Automation, Hefei University, Hefei 230061, China
  • 22. Key Laboratory of Environmental Optics and Technology, Anhui Institute of Optics and Fine Mechanics, Hefei Institute of Material Sciences, Chinese Academy of Sciences, Hefei 230031, China
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    DOI: 10.3964/j.issn.1000-0593(2022)04-1036-08 Cite this Article
    Ling-ling ZHA, Wei WANG, Yu XIE, Chang-gong SHAN, Xiang-yu ZENG, You-wen SUN, Hao YIN, Qi-hou HU. Observation of Variations of Ambient CO2 Using Portable FTIR Spectrometer[J]. Spectroscopy and Spectral Analysis, 2022, 42(4): 1036 Copy Citation Text show less
    (a) Observing site (Science Island in the western suburb of Hefei); (b) Observing site (Environmental monitoring center of Shanghai); (c) FTIR spectrometer
    Fig. 1. (a) Observing site (Science Island in the western suburb of Hefei); (b) Observing site (Environmental monitoring center of Shanghai); (c) FTIR spectrometer
    Amplitude modulation efficiency and phrase error of the spectrometer
    Fig. 2. Amplitude modulation efficiency and phrase error of the spectrometer
    Typical spectral fitting and residuals of CO2 in two spectral windows near (a) 6 220 cm-1, (b) 6 339.5 cm-1
    Fig. 3. Typical spectral fitting and residuals of CO2 in two spectral windows near (a) 6 220 cm-1, (b) 6 339.5 cm-1
    Time series of retrieved Xair
    Fig. 4. Time series of retrieved Xair
    The time series of XCO2 observed in HefeiThe light blue circles represent individual measurements; the red circles represent daily average XCO2; the dark blue lines with blue triangles represent monthly average XCO2
    Fig. 5. The time series of XCO2 observed in Hefei
    The light blue circles represent individual measurements; the red circles represent daily average XCO2; the dark blue lines with blue triangles represent monthly average XCO2
    XCO2 observed by portable FTIR and high-resolution FTIR spectrometer in 2017
    Fig. 6. XCO2 observed by portable FTIR and high-resolution FTIR spectrometer in 2017
    Daily average of XCO2 measured by portable FTIR spectrometer plotted against the corresponding values of the high-resolution FTIR spectrometerThe line shows the best fit to the ratio of the two values
    Fig. 7. Daily average of XCO2 measured by portable FTIR spectrometer plotted against the corresponding values of the high-resolution FTIR spectrometer
    The line shows the best fit to the ratio of the two values
    XCO2 observed by GOSAT and portable FTIR spectrometerBlue circles are GOSAT data and orange triangle are FTIR data
    Fig. 8. XCO2 observed by GOSAT and portable FTIR spectrometer
    Blue circles are GOSAT data and orange triangle are FTIR data
    Scatter plot of XCO2 observed by GOSAT and portable FTIR spectrometer
    Fig. 9. Scatter plot of XCO2 observed by GOSAT and portable FTIR spectrometer
    The time series of XCO2 observed in Hefei and ShanghaiThe black and red circles indicate the data observed in Hefei and Shanghai, respectively
    Fig. 10. The time series of XCO2 observed in Hefei and Shanghai
    The black and red circles indicate the data observed in Hefei and Shanghai, respectively
    Distance/cmME/无量纲PE/rad
    3000.990.002
    4000.990.003
    5000.970.003
    6000.970.003
    Mean0.980.003
    Standard deviation0.013.02×10-4
    Table 1. ME and PE values
    GasCenter of
    spectral
    Windows/cm-1
    Width
    /cm-1
    Interfering
    gases
    CO26 220.080.0H2O, HDO, CH4
    CO26 339.585.0H2O, HDO
    O27 885.0240.0H2O, HF, CO2
    Table 2. Spectral windows for retrieval of CO2 column
    Ling-ling ZHA, Wei WANG, Yu XIE, Chang-gong SHAN, Xiang-yu ZENG, You-wen SUN, Hao YIN, Qi-hou HU. Observation of Variations of Ambient CO2 Using Portable FTIR Spectrometer[J]. Spectroscopy and Spectral Analysis, 2022, 42(4): 1036
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