• Spectroscopy and Spectral Analysis
  • Vol. 41, Issue 2, 505 (2021)
Hong-ming LIU1、1、*, Yu-juan LIU1、1, Zhi-cheng ZHONG1、1, Ying SONG1、1, Zhe LI1、1, and Yang XU1、1
Author Affiliations
  • 1[in Chinese]
  • 11. Key Laboratory of Geophysical Exploration Equipment, Ministry of Education, College of Instrumentation & Electrical Engineering, National Geophysical Exploration Equipment Engineering Research Center, Jilin University, Changchun 130012, China
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    DOI: 10.3964/j.issn.1000-0593(2021)02-0505-06 Cite this Article
    Hong-ming LIU, Yu-juan LIU, Zhi-cheng ZHONG, Ying SONG, Zhe LI, Yang XU. Detection and Analysis of Water Content of Crude Oil by Near Infrared Spectroscopy[J]. Spectroscopy and Spectral Analysis, 2021, 41(2): 505 Copy Citation Text show less
    Experimental system design of near infrared spectroscopy for crude oil samples
    Fig. 1. Experimental system design of near infrared spectroscopy for crude oil samples
    Spectrum of mercury lamp measured by experimental system
    Fig. 2. Spectrum of mercury lamp measured by experimental system
    Purified crude oil produced in Daqing Oilfield
    Fig. 3. Purified crude oil produced in Daqing Oilfield
    Sample average processing curve(a): 10 spectral datas; (b): Average spectral data; (c): Average spectra of all samples
    Fig. 4. Sample average processing curve
    (a): 10 spectral datas; (b): Average spectral data; (c): Average spectra of all samples
    Spectral curves after moving average smoothing
    Fig. 5. Spectral curves after moving average smoothing
    Spectral curves after S-G smoothing
    Fig. 6. Spectral curves after S-G smoothing
    Algorithm prediction model fitting results(a): PLS; (b): SVR
    Fig. 7. Algorithm prediction model fitting results
    (a): PLS; (b): SVR
    Wavelength
    range/nm
    fluctuation
    stability/%
    intensity
    drift/%hr
    bulb color
    temperature/K
    50~1 7000.5<0.32 800
    Table 1. Parameters of halogen light source
    Performanceparameters
    Wavelength Range/nm950~1 700
    Dynamic Range7 200∶1
    SNR(Signal to Noise Ratio)6 000∶1
    Stray Light<0.15%
    Thermal Stability<0.069
    Spectral Resolution/nm8
    Wavelength Accuracy/nm±1
    Table 2. Parameters of SW2520 spectrometer
    1%~5.5%
    samples/μL
    6%~10.5%
    samples/μL
    11%~15.5%
    samples/μL
    16%~20%
    samples/μL
    70/6 930420/6 580770/6 2301 120/5 880
    105/6 895455/6 545805/6 1951 155/5 845
    140/6 860490/6 510840/6 1601 190/5 810
    175/6 825525/6 475875/6 1251 225/5 775
    210/6 790560/6 440910/6 0901 260/5 740
    245/6 755595/6 405945/6 0551 295/5 705
    280/6 720630/6 370980/6 0201 330/5 670
    315/6 685665/6 3351 015/5 9851 365/5 635
    350/6 650700/6 3001 050/5 9501 400/5 600
    385/6 615735/6 2651 085/5 915
    Table 3. Content of materials prepared from 39 component samples (crude oil/water)
    actual
    value/%
    PLS ModelSVR Model
    predicted
    value/%
    relative
    error/%
    predicted
    value/%
    relative
    error/%
    2.01.997 961-0.100 01.938 493-3.00
    5.55.498 486-0.002 85.541 8230.76
    6.56.501 2310.019 06.513 1760.20
    8.58.503 2530.038 08.549 2010.58
    10.09.991 002-0.090 010.054 1800.54
    12.512.499 670-0.003 012.462 110-0.30
    13.513.504 9600.037 013.546 9100.35
    16.516.498 520-0.009 016.524 2000.15
    18.518.500 7300.004 018.524 4300.13
    Table 4. Prediction data of PLS analysis prediction model
    Hong-ming LIU, Yu-juan LIU, Zhi-cheng ZHONG, Ying SONG, Zhe LI, Yang XU. Detection and Analysis of Water Content of Crude Oil by Near Infrared Spectroscopy[J]. Spectroscopy and Spectral Analysis, 2021, 41(2): 505
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