• Chinese Journal of Quantum Electronics
  • Vol. 40, Issue 3, 376 (2023)
ZHANG Ranran, YING Luna, and ZHOU Weidong*
Author Affiliations
  • Key Laboratory of Researching Optical Information Detecting and Display Technology in Zhejiang Province,Zhejiang Normal University, Jinhua 321004, China
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    DOI: 10.3969/j.issn.1007-5461.2023.03.009 Cite this Article
    Ranran ZHANG, Luna YING, Weidong ZHOU. Application of relevance vector machine combined with principal component analysis in quantitative analysis of LIBS[J]. Chinese Journal of Quantum Electronics, 2023, 40(3): 376 Copy Citation Text show less
    Schematic diagram of experimental setup
    Fig. 1. Schematic diagram of experimental setup
    LIBS of soil sample Train1 (GWB7406) in the range of 270.02-278.97 nm
    Fig. 2. LIBS of soil sample Train1 (GWB7406) in the range of 270.02-278.97 nm
    Training results of quantitative analysis of chromium elements
    Fig. 3. Training results of quantitative analysis of chromium elements
    Testing results of quantitative analysis of chromium elements
    Fig. 4. Testing results of quantitative analysis of chromium elements
    Content of Cr in train samples/(ug·g-1)Content of Cr in test samples/(ug·g-1)
    12345678910#1#2#3#4
    75.0068.0068.5081.0061.0061.5074.0062.0074.5087.0066.0074.6770.0074.33
    Table 1. The content of chromium element in soil samples
    Sample

    ARE/%

    RVM PCA-RVM

    #1

    #2

    #3

    #4

    11.03

    6.18

    6.52

    5.73

    0.91

    5.86

    2.17

    0.91

    Table 2. Average relative error (ARE) of 21 predictions by PCA-RVM and RVM model for each sample
    SampleRSD /%
    RVMPCA-RVM

    #1

    #2

    #3

    #4

    48.75

    0.91

    1.00

    1.33

    1.89

    0.77

    0.19

    0.84

    Table 3. Relative standard deviation (RSD) of 21 predictions by PCA-RVM and RVM model for each sample
    Ranran ZHANG, Luna YING, Weidong ZHOU. Application of relevance vector machine combined with principal component analysis in quantitative analysis of LIBS[J]. Chinese Journal of Quantum Electronics, 2023, 40(3): 376
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