• Acta Optica Sinica
  • Vol. 42, Issue 2, 0209001 (2022)
Diqin Zhang1、4, Yu Zhao2、**, Zhen Zhang3, Jianhua Zhu3, and Yuxia Zhao1、4、*
Author Affiliations
  • 1Key Laboratory of Photochemical Conversion and Optoelectronic Materials, Technical Institute of Physics and Chemistry, Chinese Academy of Sciences, Beijing 100190, China
  • 2Optoelectronic Technology and Equipment R&D Center, Institute of Fluid Physics, China Academy of Engineering Physics, Mianyang, Sichuan 621900, China;
  • 3College of Physics, Sichuan University, Chengdu, Sichuan 610065, China
  • 4University of Chinese Academy of Sciences, Beijing 100049, China
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    DOI: 10.3788/AOS202242.0209001 Cite this Article Set citation alerts
    Diqin Zhang, Yu Zhao, Zhen Zhang, Jianhua Zhu, Yuxia Zhao. Synthesis and Properties of Photosensitizer for Green-Sensitive Holographic Recording Medium[J]. Acta Optica Sinica, 2022, 42(2): 0209001 Copy Citation Text show less
    Molecular structural formula of green-sensitive cyclopentanone photosensitizer
    Fig. 1. Molecular structural formula of green-sensitive cyclopentanone photosensitizer
    Fabrication process of holographic photopolymer samples
    Fig. 2. Fabrication process of holographic photopolymer samples
    Optical path of holographic test. (a) Test of exposure characteristics; (b) test of angle selectivity of Bragg grating; (c) reconstruction of hologram
    Fig. 3. Optical path of holographic test. (a) Test of exposure characteristics; (b) test of angle selectivity of Bragg grating; (c) reconstruction of hologram
    Photophysical and photochemical properties of photosensitizer in DMF solution. (a) Normalized UV-VIS absorption spectra; (b) UV-VIS absorption intensity of photosensitizer under 532 nm laser irradiation varies with light time
    Fig. 4. Photophysical and photochemical properties of photosensitizer in DMF solution. (a) Normalized UV-VIS absorption spectra; (b) UV-VIS absorption intensity of photosensitizer under 532 nm laser irradiation varies with light time
    Photopolymerization kinetics of prepolymer solution containing 0.02% photosensitizer under 532 nm laser irradiation. (a) Curves of carbon-carbon double bond conversion rate with time; (b) curves of monomer polymerization rate with time
    Fig. 5. Photopolymerization kinetics of prepolymer solution containing 0.02% photosensitizer under 532 nm laser irradiation. (a) Curves of carbon-carbon double bond conversion rate with time; (b) curves of monomer polymerization rate with time
    Holographic exposure characteristic curves of samples containing 0.02% photosensitizer under interference exposure of 532 nm laser
    Fig. 6. Holographic exposure characteristic curves of samples containing 0.02% photosensitizer under interference exposure of 532 nm laser
    Relationship between diffraction efficiency and exposure of samples containing BTMI under 532 nm monopulse laser exposure
    Fig. 7. Relationship between diffraction efficiency and exposure of samples containing BTMI under 532 nm monopulse laser exposure
    Original image and hologram reconstruction image recorded by sample containing BTMI. (a) Dot diameter is 100 μm; (b) dot diameter is 30 μm
    Fig. 8. Original image and hologram reconstruction image recorded by sample containing BTMI. (a) Dot diameter is 100 μm; (b) dot diameter is 30 μm
    Photosensitizerλmaxabs /nmεmax /(104 L·mol-1·cm-1)ε532 nm /(104 L·mol-1·cm-1)
    BTCP4985.131.80
    BTMI52111.209.16
    PRZA5266.546.35
    BTAP5388.227.98
    Table 1. Photophysical properties of photosensitizers in DMF solution
    Photosensitizer770 line/mm2000 line/mm
    ηmax /%E /(mJ·cm-2)S /(10-2 cm2·mJ-1)Δn /10-4ηmax/%E /(mJ·cm-2)S /(10-2 cm2·mJ-1)Δθ /(°)Δn /10-4
    BTCP88.61060.884.0765.60.450.181.033.40
    BTMI90.0641.484.1471.60.240.350.903.64
    PRZA89.7891.064.1370.00.310.270.903.57
    BTAP88.31000.944.0557.50.370.200.932.18
    Table 2. Holographic properties of samples containing 0.02% photosensitizer at different spatial frequencies
    Diqin Zhang, Yu Zhao, Zhen Zhang, Jianhua Zhu, Yuxia Zhao. Synthesis and Properties of Photosensitizer for Green-Sensitive Holographic Recording Medium[J]. Acta Optica Sinica, 2022, 42(2): 0209001
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