• Spectroscopy and Spectral Analysis
  • Vol. 41, Issue 9, 2829 (2021)
Lin XU1、1;, Hong-yuan HE1、1; *;, Cui-mei LIU2、2; *;, and Zhen-dong HUA2、2;
Author Affiliations
  • 11. College of Investigation, People's Public Security University of China, Beijing 100038, China
  • 22. Key Laboratory of Drug Monitoring and Control, Drug Intelligence and Forensic Center, Ministry of Public Security, Beijing 100193, China
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    DOI: 10.3964/j.issn.1000-0593(2021)09-2829-06 Cite this Article
    Lin XU, Hong-yuan HE, Cui-mei LIU, Zhen-dong HUA. Study on Vibrational Spectral Characteristics of Fentanyl-Class Substances[J]. Spectroscopy and Spectral Analysis, 2021, 41(9): 2829 Copy Citation Text show less
    Chemical structures of the fentanyl-class substances
    Fig. 1. Chemical structures of the fentanyl-class substances
    Infrared spectra for different salt forms of fentanyl-class substances(a): Base; (b): Hydrochloride; (c): Citrate
    Fig. 2. Infrared spectra for different salt forms of fentanyl-class substances
    (a): Base; (b): Hydrochloride; (c): Citrate
    Infrared spectra of five fentanyl-class substances(a): Fentanyl HCl; (b): Butyrylfentanyl HCl; (c): Thiofentanyl HCl; (d): Fentanyl Citrarte; (e): Furanylfentanyl Citrarte
    Fig. 3. Infrared spectra of five fentanyl-class substances
    (a): Fentanyl HCl; (b): Butyrylfentanyl HCl; (c): Thiofentanyl HCl; (d): Fentanyl Citrarte; (e): Furanylfentanyl Citrarte
    Raman spectra of six fentanyl-class substances(a): Alpha-methylfentanyl HCl; (b): 3-Methylfentanyl HCl; (c): Fentanyl HCl; (d): Butyrylfentanyl HCl; (e): Phenylfentanyl HCl; (f): THF-F HCl
    Fig. 4. Raman spectra of six fentanyl-class substances
    (a): Alpha-methylfentanyl HCl; (b): 3-Methylfentanyl HCl; (c): Fentanyl HCl; (d): Butyrylfentanyl HCl; (e): Phenylfentanyl HCl; (f): THF-F HCl
    Raman spectra of seven fentanyl-class substances(a): 4-Fluorofentanyl HCl; (b): 4-Fluorobutyrylfentanyl; (c): 4-FIBF HCl; (d): Remifentanil HCl; (e): Thiofentanyl HCl; (f): Furanylfentanly Citrate; (g): Sufentanil Citrate
    Fig. 5. Raman spectra of seven fentanyl-class substances
    (a): 4-Fluorofentanyl HCl; (b): 4-Fluorobutyrylfentanyl; (c): 4-FIBF HCl; (d): Remifentanil HCl; (e): Thiofentanyl HCl; (f): Furanylfentanly Citrate; (g): Sufentanil Citrate
    SpectroscopyCompoundCorrelation
    coefficients
    InfraredFentanyl HCl95
    Butyrylfentanyl HCl
    Fentanyl HCl91
    Thiofentanyl HCl
    Fentanyl Citrate91
    Furanylfentanyl Citrate
    RamanAlpha-methylfentanyl HCl93
    3-Methylfentanyl HCl
    Fentanyl HCl92
    Butyrylfentanyl HCl
    Phenylfentanyl HCl92
    THF-F HCl
    Table 1. The correlation coefficients of fentanyl-class substances
    Lin XU, Hong-yuan HE, Cui-mei LIU, Zhen-dong HUA. Study on Vibrational Spectral Characteristics of Fentanyl-Class Substances[J]. Spectroscopy and Spectral Analysis, 2021, 41(9): 2829
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