• Journal of Inorganic Materials
  • Vol. 38, Issue 2, 170 (2023)
Qingong ZHU*, Gaoling ZHAO, and Gaorong HAN
DOI: 10.15541/jim20220286 Cite this Article
Qingong ZHU, Gaoling ZHAO, Gaorong HAN. Effect of Recombination Time on the Structure and Properties of P2O5-Al2O3 Heterogeneous Composite Glass[J]. Journal of Inorganic Materials, 2023, 38(2): 170 Copy Citation Text show less
XRD patterns of samples prepared with different recombination time (a) and recombination time of 10 min (b) with inset showing optical photo of the sample
. XRD patterns of samples prepared with different recombination time (a) and recombination time of 10 min (b) with inset showing optical photo of the sample
FT-IR spectra of P2O5-Al2O3 matrix glass (a) and SiO2-Na2O high-silicate glass (b)
. FT-IR spectra of P2O5-Al2O3 matrix glass (a) and SiO2-Na2O high-silicate glass (b)
AFM-IR images of the matrix glass (a) and heterogeneous composite glass prepared with different recombination time (b-f)
. AFM-IR images of the matrix glass (a) and heterogeneous composite glass prepared with different recombination time (b-f)
High-resolution P2p XPS spectra for heterogeneous composite glass fitting with the least squares method
. High-resolution P2p XPS spectra for heterogeneous composite glass fitting with the least squares method
High-resolution O1s XPS spectra for heterogeneous composite glass fitting with the least squares method
. High-resolution O1s XPS spectra for heterogeneous composite glass fitting with the least squares method
Raman spectra of P2O5-Al2O3 heterogeneous composite glass prepared with different recombination time
. Raman spectra of P2O5-Al2O3 heterogeneous composite glass prepared with different recombination time
Young's modulus of P2O5-Al2O3 heterogeneous composite glass prepared with different recombination time
. Young's modulus of P2O5-Al2O3 heterogeneous composite glass prepared with different recombination time
Recombination timePeak position/eVFWHM/eVArea/%
Main peakDeconvoluted peak
10 s134.46134.231.4666.7
135.171.4733.3
2 min134.42134.221.4166.7
135.171.4133.3
4 min134.59134.351.4766.7
135.281.4433.3
6 min134.67134.361.7466.7
135.602.1633.3
8 min134.44134.261.4566.7
135.181.5033.3
Table 1. Peak positions, full width at half maximum (FWHM) and area from the fitting curves of P2p core levels for heterogeneous composite glass
Recombina-tion time NBO-Li/MgNBO-AlBO
BE/eVFWHM/eVArea/%BE/eVFWHM/eVArea/%BE/eVFWHM/eVArea/%
10 s531.931.3929.69532.361.3929.68533.351.7840.63
2 min532.101.4337.42532.782.1731.30533.202.1731.29
4 min531.951.4331.66532.411.9734.18533.291.9734.16
6 min531.971.3929.65532.361.9935.18533.291.9935.17
8 min532.071.3531.65532.552.0734.18533.242.0734.17
Table 2. Peak positions, full width at half maximum (FWHM) and area from the fitting curves of O1s core levels for heterogeneous composite glass
Qingong ZHU, Gaoling ZHAO, Gaorong HAN. Effect of Recombination Time on the Structure and Properties of P2O5-Al2O3 Heterogeneous Composite Glass[J]. Journal of Inorganic Materials, 2023, 38(2): 170
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