• Journal of Inorganic Materials
  • Vol. 36, Issue 2, 203 (2021)
Gaoyao JIN, Haichuan HE, Jie WU, Mengyuan ZHANG, Yajuan LI*, and Younian LIU
Author Affiliations
  • Hunan Provincial Key Laboratory of Micro & Nano Materials Interface Science, College of Chemistry and Chemical Engineering, Central South University, Changsha 410083, China
  • show less
    DOI: 10.15541/jim20200161 Cite this Article
    Gaoyao JIN, Haichuan HE, Jie WU, Mengyuan ZHANG, Yajuan LI, Younian LIU. Cobalt-doped Hollow Carbon Framework as Sulfur Host for the Cathode of Lithium Sulfur Battery[J]. Journal of Inorganic Materials, 2021, 36(2): 203 Copy Citation Text show less
    Schematic illustration for the synthesis steps of hollow Co/C composite and its effect for the resulting electrode
    . Schematic illustration for the synthesis steps of hollow Co/C composite and its effect for the resulting electrode
    (a) XRD pattern, (b) Raman spectrum, (c) XPS spectrum and (d) N2 adsorption/desorption isotherm of Co/C-700 with insert in (d) showing pore size distribution
    . (a) XRD pattern, (b) Raman spectrum, (c) XPS spectrum and (d) N2 adsorption/desorption isotherm of Co/C-700 with insert in (d) showing pore size distribution
    XRD pattern of UWC-700
    . XRD pattern of UWC-700
    (a) TGA curve of Co/C-700 in air and (b) XRD pattern of the final product
    . (a) TGA curve of Co/C-700 in air and (b) XRD pattern of the final product
    (a, b) TEM, (c) high-resolution TEM (HRTEM) images and (d) EDS elemental mappings (Co, C and O) of Co/C-700
    . (a, b) TEM, (c) high-resolution TEM (HRTEM) images and (d) EDS elemental mappings (Co, C and O) of Co/C-700
    N2 adsorption/desorption isotherms (a) and pore size distributions (b) of UWC-700 and HEC-700
    . N2 adsorption/desorption isotherms (a) and pore size distributions (b) of UWC-700 and HEC-700
    SEM image of Co/C-700
    . SEM image of Co/C-700
    XRD pattern (a) and SEM image (b) of HEC-700
    . XRD pattern (a) and SEM image (b) of HEC-700
    TGA curves of S@Co/C-700 and S@HEC-700 under N2 atmosphere
    . TGA curves of S@Co/C-700 and S@HEC-700 under N2 atmosphere
    XPS spectrum of S@Co/C-700 composite
    . XPS spectrum of S@Co/C-700 composite
    High resolution XPS spectra of Co/C-700(a) C1s; (b) O1s; (c) Co2p
    . High resolution XPS spectra of Co/C-700(a) C1s; (b) O1s; (c) Co2p
    High resolution XPS spectra for S@Co/C-700 composites
    . High resolution XPS spectra for S@Co/C-700 composites
    Photograph of static adsorption test of HEC-700 and Co/C-700 after standing for 1 h
    . Photograph of static adsorption test of HEC-700 and Co/C-700 after standing for 1 h
    Multi-cycle CV curves of Co/C-700 based symmetric cells at 1 mV∙s-1 (a) and increased rates (b), and multi-cycle CV curves of HEC-700 at 1 mV∙s-1 (c) and increased rates (d)
    . Multi-cycle CV curves of Co/C-700 based symmetric cells at 1 mV∙s-1 (a) and increased rates (b), and multi-cycle CV curves of HEC-700 at 1 mV∙s-1 (c) and increased rates (d)
    CV curves of (a) Co/C-700 and (b) HEC-700 based symmetric cells with and without 0.2 mol∙L-1 Li2S6 at 1 mV∙s-1; (c) CV curves and (d) EIS plots of S@Co/C-700 and S@HEC-700 electrodes
    . CV curves of (a) Co/C-700 and (b) HEC-700 based symmetric cells with and without 0.2 mol∙L-1 Li2S6 at 1 mV∙s-1; (c) CV curves and (d) EIS plots of S@Co/C-700 and S@HEC-700 electrodes
    (a) Rate capabilities at various rates from 0.5C to 10C and (b) cycling stabilities at 1C for S@Co/C-700 and S@HEC-700 electrodes
    . (a) Rate capabilities at various rates from 0.5C to 10C and (b) cycling stabilities at 1C for S@Co/C-700 and S@HEC-700 electrodes
    Voltage profiles of S@HEC-700 (a) and S@Co/C-700 (b) electrodes at various rates from 0.5C to 10C
    . Voltage profiles of S@HEC-700 (a) and S@Co/C-700 (b) electrodes at various rates from 0.5C to 10C
    (a) Cycling stabilities of S@Co/C-700 and S@HEC-700 electrodes at 2C; (b) Cycling performance of S@Co/C-700 at 5C and 10C
    . (a) Cycling stabilities of S@Co/C-700 and S@HEC-700 electrodes at 2C; (b) Cycling performance of S@Co/C-700 at 5C and 10C
    SampleSBET/(m2∙g-1)Vtotal/(cm3∙g-1)Pore volume/%
    MicroMesoMacro
    UWC-70015.090.0261.7698.240
    Co/C-700376.130.5228.8562.768.49
    HEC-700369.530.5425.4768.176.36
    Table 1.

    BET surface area and pore volume distribution of UWC-700, Co/C-700 and HEC-700

    Gaoyao JIN, Haichuan HE, Jie WU, Mengyuan ZHANG, Yajuan LI, Younian LIU. Cobalt-doped Hollow Carbon Framework as Sulfur Host for the Cathode of Lithium Sulfur Battery[J]. Journal of Inorganic Materials, 2021, 36(2): 203
    Download Citation