• Spectroscopy and Spectral Analysis
  • Vol. 41, Issue 10, 3147 (2021)
Yan-jun ZHANG*, Cheng-long KANG, Ya-qian LIU, Xing-hu FU*;, Jin-xiao ZHANG, Ming-xue WANG, and Liu-zhen YANG
Author Affiliations
  • School of Information Science and Engineering, The Key Laboratory for Special Fiber and Fiber Sensor of Hebei Province, Yanshan University, Qinhuangdao 066004, China
  • show less
    DOI: 10.3964/j.issn.1000-0593(2021)10-3147-06 Cite this Article
    Yan-jun ZHANG, Cheng-long KANG, Ya-qian LIU, Xing-hu FU, Jin-xiao ZHANG, Ming-xue WANG, Liu-zhen YANG. Rapidly Detection of Total Nitrogen and Phosphorus Content in Water by Surface Enhanced Raman Spectroscopy and GWO-SVR Algorithm[J]. Spectroscopy and Spectral Analysis, 2021, 41(10): 3147 Copy Citation Text show less
    GWO-SVR algorithm flow chart
    Fig. 1. GWO-SVR algorithm flow chart
    Surface enhanced Raman spectrum(a): TN; (b): TP
    Fig. 2. Surface enhanced Raman spectrum
    (a): TN; (b): TP
    Spectra pretreatment(a): Background removal; (b): Smoothed
    Fig. 3. Spectra pretreatment
    (a): Background removal; (b): Smoothed
    Correlation between predicted value and true value(a): TN; (b): TP
    Fig. 4. Correlation between predicted value and true value
    (a): TN; (b): TP
    Different model correclation curves(a): TN; (b): TP
    Fig. 5. Different model correclation curves
    (a): TN; (b): TP
    特征峰位/cm-1官能团振动方式
    797.08伸缩振动
    834.95—CH/—CO平面弯曲振动
    948.90CH3/CH平面摇摆振动/平面外弯曲振动
    1 024.09邻-双取代苯伸缩振动
    1 394.32N—H平面内弯曲振动
    Table 1. The characteristic Raman spectral peak of TN
    特征峰位/cm-1官能团振动方式
    561.44O—P—O反对称角振动
    930.44P—O对称伸缩振动
    1 080.22P—O反对称角振动
    Table 2. The characteristic Raman spectral peak of TP
    R2MSEElapsed time/s
    TN0.999 50.005 81.467
    TP0.998 50.037 61.646
    Table 3. GWO-SVR model evaluation results
    ModelR2MSEElapsed time/s
    PSO-BP0.998 30.022 713.94
    ABC-SVR0.993 80.052 72.29
    GWO-SVR0.999 50.005 81.47
    Table 4. Comparison of prediction results of different models (TN)
    ModelR2MSEElapsed time/s
    PSO-BP0.9960.042 619.67
    ABC-SVR0.979 20.299 21.85
    GWO-SVR0.998 50.037 61.65
    Table 5. Comparison of prediction results of different models(TP)
    Yan-jun ZHANG, Cheng-long KANG, Ya-qian LIU, Xing-hu FU, Jin-xiao ZHANG, Ming-xue WANG, Liu-zhen YANG. Rapidly Detection of Total Nitrogen and Phosphorus Content in Water by Surface Enhanced Raman Spectroscopy and GWO-SVR Algorithm[J]. Spectroscopy and Spectral Analysis, 2021, 41(10): 3147
    Download Citation