• Spectroscopy and Spectral Analysis
  • Vol. 42, Issue 11, 3546 (2022)
Yang LÜ1、1;, Jing-cheng PEI1、1; *;, and Yu-yang ZHANG2、2;
Author Affiliations
  • 11. Gemmological Institute, China University of Geosciences (Wuhan), Wuhan 430074, China
  • 22. School of Earth Sciences, China University of Geosciences (Wuhan), Wuhan 430074, China
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    DOI: 10.3964/j.issn.1000-0593(2022)11-3546-06 Cite this Article
    Yang LÜ, Jing-cheng PEI, Yu-yang ZHANG. Chemical Composition and Spectra Characteristics of Hydrothermal Synthetic Sapphire[J]. Spectroscopy and Spectral Analysis, 2022, 42(11): 3546 Copy Citation Text show less
    Samples' pictures(a): Natural sapphire; (b): Flame-fusionsynthetic sapphire; (c): Hydrothermal synthetic sapphire
    Fig. 1. Samples' pictures
    (a): Natural sapphire; (b): Flame-fusionsynthetic sapphire; (c): Hydrothermal synthetic sapphire
    Raman spectra of natural and synthetic sapphire samples
    Fig. 2. Raman spectra of natural and synthetic sapphire samples
    Infrared spectra of natural and synthetic sapphire samples(400~1 000 cm-1)
    Fig. 3. Infrared spectra of natural and synthetic sapphire samples(400~1 000 cm-1)
    Infrared spectra of flame-fusion and hydrothermal synthetic samples(3 000~4 000 cm-1)
    Fig. 4. Infrared spectra of flame-fusion and hydrothermal synthetic samples(3 000~4 000 cm-1)
    UV-Vis spectra of natural and synthetic sapphire samples
    Fig. 5. UV-Vis spectra of natural and synthetic sapphire samples
    Three-dimensional fluorescence spectra of natural and synthetic sapphire samples(a): Sapphire SR-1; (b): Sapphire SR-2; (c): Flame-fusion synthetic sapphire TR; (d): Natural sapphire XR-2
    Fig. 6. Three-dimensional fluorescence spectra of natural and synthetic sapphire samples
    (a): Sapphire SR-1; (b): Sapphire SR-2; (c): Flame-fusion synthetic sapphire TR; (d): Natural sapphire XR-2
    Emission fluorescence spectra of natural and synthetic sapphire samples excited by 240 nm
    Fig. 7. Emission fluorescence spectra of natural and synthetic sapphire samples excited by 240 nm
    类别数量颜色重量/ct折射率双折射密度/(g·cm-3)多色性荧光
    水热法7颗蓝色0.91~1.14均位于均位于3.94~4.00三组样品均为强多色性水热法和焰熔法
    焰熔法2颗蓝色1.00~1.021.760~0.008~3.90~4.00蓝绿-蓝或均为短波下蓝白色
    天然1颗蓝色1.011.7700.0103.96浅蓝-深蓝惰性
    Table 1. Routine gemological parameters of natural and synthetic sapphire samples
    水热
    法1
    水热
    法2
    水热
    法3
    水热
    法4
    水热
    法5
    焰熔法合成
    蓝宝石[4]
    Mgudl192514udlnd
    Si3 3194 4263 9083 1923 527nd
    Ti299208302272547444
    V343222770nd
    Fe508425477516662508
    Table 2. Trace element of natural and synthetic sapphire samples (ppm)
    拉曼位移/cm-1强度振动归属
    SR-1SR-2YR-1TR
    378378378378中等Eg
    415415415415A1g
    428428428428Eg
    -447-447Eg
    -576-575Eg
    643-642-中等A1g
    -750-750中等Eg
    Table 3. Raman displacement and attribution of nature and synthetic sapphire samples
    峰位/cm-1强度峰位归属
    SR-7YR-1
    3 184-OH伸缩振动(Ti4+相关)
    3 2323 232中等OH伸缩振动(Ti4+相关)
    3 3093 309OH伸缩振动(Ti4+相关)
    3 485-中等OH(含水矿物包裹体)
    3 532-OH(含水矿物包裹体)
    3 562-中等OH(含水矿物包裹体)
    Table 4. Infrared absorption peaks and the attribution of samples (3 000~4 000 cm-1)
    Yang LÜ, Jing-cheng PEI, Yu-yang ZHANG. Chemical Composition and Spectra Characteristics of Hydrothermal Synthetic Sapphire[J]. Spectroscopy and Spectral Analysis, 2022, 42(11): 3546
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