• Journal of Inorganic Materials
  • Vol. 34, Issue 4, 425 (2019)
Yang LIU1, Shan YU1、*, Kai-Wen ZHENG1, Wei-Wei CHEN1, Xing-An DONG2, Fan DONG2, and Ying ZHOU1、*
Author Affiliations
  • 1The Center of New Energy Materials and Technology, School of Materials Science and Engineering, Southwest Petroleum University, Chengdu 610500, China
  • 2Chongqing Key Laboratory Catalysis and New Environmental Materials, College of Environment and Resources, Chongqing Technology and Business University, Chongqing 400067, China
  • show less
    DOI: 10.15541/jim20180299 Cite this Article
    Yang LIU, Shan YU, Kai-Wen ZHENG, Wei-Wei CHEN, Xing-An DONG, Fan DONG, Ying ZHOU. NO Photo-oxidation and In-situ DRIFTS Studies on N-doped Bi2O2CO3/CdSe Quantum Dot Composite[J]. Journal of Inorganic Materials, 2019, 34(4): 425 Copy Citation Text show less
    Schematic diagram of photo-oxidation NO reaction equipment
    1. Schematic diagram of photo-oxidation NO reaction equipment
    Photocatalytic removal ratio of NO (a) and generation of NO2 (b) in the presence of N-BOC and N-BOC/CdSe QDs under visible light irradiation (λ>420 nm), and photocatalytic recycling tests on N-BOC/CdSe QDs (1%) under visible light (c) and UV-Visible light (d) irradiation
    2. Photocatalytic removal ratio of NO (a) and generation of NO2 (b) in the presence of N-BOC and N-BOC/CdSe QDs under visible light irradiation (λ>420 nm), and photocatalytic recycling tests on N-BOC/CdSe QDs (1%) under visible light (c) and UV-Visible light (d) irradiation
    XRD patterns of N-BOC and N-BOC/CdSe QDs(1%) and their corresponding standard PDF card
    3. XRD patterns of N-BOC and N-BOC/CdSe QDs(1%) and their corresponding standard PDF card
    (a)TEM and (b)HRTEM images of N-BOC/CdSe QDs(1%)
    4. (a)TEM and (b)HRTEM images of N-BOC/CdSe QDs(1%)
    High-resolution XPS spectra of Bi 4f (a), O 1s (b), C 1s (c), and valance band (d) of N-BOC and N-BOC/CdSe QDs (1%) sample
    5. High-resolution XPS spectra of Bi 4f (a), O 1s (b), C 1s (c), and valance band (d) of N-BOC and N-BOC/CdSe QDs (1%) sample
    UV-Vis DRS of N-BOC and N-BOC/CdSe QDs
    6. UV-Vis DRS of N-BOC and N-BOC/CdSe QDs
    Photoluminescence spectra of N-BOC and N-BOC/CdSe QDs (1%)
    7. Photoluminescence spectra of N-BOC and N-BOC/CdSe QDs (1%)
    In situ DRIFTS of NO adsorption on N-BOC/CdSe QDs (1%) before (a), during (b) and after (c) visible light illumination
    8. In situ DRIFTS of NO adsorption on N-BOC/CdSe QDs (1%) before (a), during (b) and after (c) visible light illumination
    Proposed processes of NO adsorption and photocatalytic NO oxidation
    9. Proposed processes of NO adsorption and photocatalytic NO oxidation
    Schematic representation of the mechanism for photodegrading NO by N-BOC/CdSe QDs
    10. Schematic representation of the mechanism for photodegrading NO by N-BOC/CdSe QDs
    SpeciesRedox potential (NHE)
    Potential/eVRef.
    O2/•O2--0.28[30]
    NO/NO20.94[29]
    NO/NO3-1.03[29]
    Table 1. Redox potentials of different active species
    Wavenumber/cm-1AssignmentRef.
    935Bidentate nitrite[31]
    949, 978Monodentate nitrate[32-35]
    1002Bridge nitrate[32-35]
    1024Bidentate/monodentate nitrate[8, 32-35]
    1092, 1134NO[31]
    1180NO-[8,18]
    1120Bidentate nitrite[18, 31]
    1262Monodentate nitrate[18, 31]
    Table 2. Assignments of the IR bands observed during NO adsorption and photocatalysis over N-BOC/CdSe QDs
    Yang LIU, Shan YU, Kai-Wen ZHENG, Wei-Wei CHEN, Xing-An DONG, Fan DONG, Ying ZHOU. NO Photo-oxidation and In-situ DRIFTS Studies on N-doped Bi2O2CO3/CdSe Quantum Dot Composite[J]. Journal of Inorganic Materials, 2019, 34(4): 425
    Download Citation