Yu-Hui DONG, Shu-Yu ZENG, Bo-Ning HAN, Jie XUE, Ji-Zhong SONG, Hai-Bo ZENG, [in Chinese], [in Chinese], [in Chinese], [in Chinese], [in Chinese], and [in Chinese]
Author Affiliations
MIIT Key Laboratory of Advanced Display Materials and Devices, Institute of Optoelectronics & Nanomaterials, School of Materials Science and Engineering, Nanjing University of Science and Technology, Nanjing 210094, Chinashow less
. Scheme of the all-solid-state ball milling procedure for synthesis of CsPbX3 NCs (a) and optical image of large-scale red emission powder under UV light excitation (365 nm) (b)
. PL intensity of CsPbBr3 NCs powder with different size of grind medium under the same test condition
. PL intensity of CsPbBr3 NCs powder with different ball-to-powder ratio under the same condition
. (a) PL emission spectra of CsPbX3 NCs powder, the corresponding optical images under normal daylight and UV light (black background) were exhibited inside; (b) Color gamut spectra of perovskite NCs (the inner black line indicating NTSC)
. EDS information of CsPbI3 NCs powder(a) SEM image with corresponding atomic percentage information; (b) EDS spectrum of CsPbI3 NCs
. SEM images of CsPbX3 NCs
. PL spectra of CsPbBr3 NCs powder with various rotation speed of the planetary mill
. The air stability of CsPbI3 NCs powder (a) The PL stability exposed in air; (b) X-ray diffraction (XRD) pattern of CsPbI3 NCs powder; (c) Photographs of the powder samples with time changing under the sunlight (left) and UV light (right)
. The X-Ray diffraction spectra of CsPbX3 NCs powder with various halogen ratios
. The PL spectrum of CsPbI3 powder adding amount of 0.2 g of BN
. Analysis of air stability of CsPbI3 NCs (a) Stability test of CsPbI3 NCs powder with different BN quantity; (b) SEM image of CsPbI3 NCs; (c) Energy dispersive spectroscopy (EDS) mapping images of (b)
. Proof-of-concept demonstration of white LED by blending green and red Pe-NCs on a commercial blue LED chip (a) Schematically depicts the packing method of white LED; (b) EL spectra of three typical devices exhibiting (1) green-white, (2) white, and (3) red-white; (c) Photographs of the white LED under different operating voltage
. The stability of white-light LED (a) The luminance stability of white-light LED placed in the air measured at the voltage of 2.7 V; (b) The working stability of the white-light LED after continuous operating for 2 h
CsPbX3 | Emission peak/nm | FWHM/nm | CsPbX3 | Emission peak/nm | FWHM/nm |
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CsPbCl3 | 417 | 23 | CsPbIBr2 | 551 | 41 | CsPbCl2.14Br0.86 | 430 | 23 | CsPbI2Br | 605 | 47 | CsPbCl2Br | 447 | 27 | CsPbI2.14Br0.86 | 642 | 46 | CsPbClBr2 | 483 | 38 | CsPbI3 | 680 | 40 | CsPbBr3 | 532 | 33 | | | |
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Table 1. Comprehensive comparisons for the representative perovskite NCs
Sample | Synthetic methods | FWHM/nm | Color/nm | Ref. |
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CsPbX3(X=Cl, Br, I) | All-solid-state ball milling | 23-47 | 417-680 | This work | CsPbX3(X=Cl, Br, I) | Supersaturated recrystallization | 12-39 | 400-650 | [1] | CsPbX3(CsPb(Br/Cl)3 -CsPbI3) | Droplet-based microfluidic platform | 20-45 | 470-690 | [2] | CsPbX3(X=Cl, Br, I) | Fast Anion-Exchange | 12-40 | 410-700 | [3] |
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Table 2. Comparison of FWHM of CsPbX3 with typical solution synthesis