• Journal of Inorganic Materials
  • Vol. 34, Issue 1, 72 (2019)
Yu-Hui DONG, Shu-Yu ZENG, Bo-Ning HAN, Jie XUE, Ji-Zhong SONG, Hai-Bo ZENG, [in Chinese], [in Chinese], [in Chinese], [in Chinese], [in Chinese], and [in Chinese]
Author Affiliations
  • MIIT Key Laboratory of Advanced Display Materials and Devices, Institute of Optoelectronics & Nanomaterials, School of Materials Science and Engineering, Nanjing University of Science and Technology, Nanjing 210094, China
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    DOI: 10.15541/jim20180207 Cite this Article
    Yu-Hui DONG, Shu-Yu ZENG, Bo-Ning HAN, Jie XUE, Ji-Zhong SONG, Hai-Bo ZENG, [in Chinese], [in Chinese], [in Chinese], [in Chinese], [in Chinese], [in Chinese]. BN/CsPbX3 Composite Nanocrystals: Synthesis and Applications in White LED[J]. Journal of Inorganic Materials, 2019, 34(1): 72 Copy Citation Text show less
    Scheme of the all-solid-state ball milling procedure for synthesis of CsPbX3 NCs (a) and optical image of large-scale red emission powder under UV light excitation (365 nm) (b)
    . Scheme of the all-solid-state ball milling procedure for synthesis of CsPbX3 NCs (a) and optical image of large-scale red emission powder under UV light excitation (365 nm) (b)
    PL intensity of CsPbBr3 NCs powder with different size of grind medium under the same test condition
    . PL intensity of CsPbBr3 NCs powder with different size of grind medium under the same test condition
    PL intensity of CsPbBr3 NCs powder with different ball-to-powder ratio under the same condition
    . PL intensity of CsPbBr3 NCs powder with different ball-to-powder ratio under the same condition
    (a) PL emission spectra of CsPbX3 NCs powder, the corresponding optical images under normal daylight and UV light (black background) were exhibited inside; (b) Color gamut spectra of perovskite NCs (the inner black line indicating NTSC)
    . (a) PL emission spectra of CsPbX3 NCs powder, the corresponding optical images under normal daylight and UV light (black background) were exhibited inside; (b) Color gamut spectra of perovskite NCs (the inner black line indicating NTSC)
    EDS information of CsPbI3 NCs powder(a) SEM image with corresponding atomic percentage information; (b) EDS spectrum of CsPbI3 NCs
    . EDS information of CsPbI3 NCs powder(a) SEM image with corresponding atomic percentage information; (b) EDS spectrum of CsPbI3 NCs
    SEM images of CsPbX3 NCs
    . SEM images of CsPbX3 NCs
    PL spectra of CsPbBr3 NCs powder with various rotation speed of the planetary mill
    . PL spectra of CsPbBr3 NCs powder with various rotation speed of the planetary mill
    The air stability of CsPbI3 NCs powder (a) The PL stability exposed in air; (b) X-ray diffraction (XRD) pattern of CsPbI3 NCs powder; (c) Photographs of the powder samples with time changing under the sunlight (left) and UV light (right)
    . The air stability of CsPbI3 NCs powder (a) The PL stability exposed in air; (b) X-ray diffraction (XRD) pattern of CsPbI3 NCs powder; (c) Photographs of the powder samples with time changing under the sunlight (left) and UV light (right)
    The X-Ray diffraction spectra of CsPbX3 NCs powder with various halogen ratios
    . The X-Ray diffraction spectra of CsPbX3 NCs powder with various halogen ratios
    The PL spectrum of CsPbI3 powder adding amount of 0.2 g of BN
    . The PL spectrum of CsPbI3 powder adding amount of 0.2 g of BN
    Analysis of air stability of CsPbI3 NCs (a) Stability test of CsPbI3 NCs powder with different BN quantity; (b) SEM image of CsPbI3 NCs; (c) Energy dispersive spectroscopy (EDS) mapping images of (b)
    . Analysis of air stability of CsPbI3 NCs (a) Stability test of CsPbI3 NCs powder with different BN quantity; (b) SEM image of CsPbI3 NCs; (c) Energy dispersive spectroscopy (EDS) mapping images of (b)
    Proof-of-concept demonstration of white LED by blending green and red Pe-NCs on a commercial blue LED chip (a) Schematically depicts the packing method of white LED; (b) EL spectra of three typical devices exhibiting (1) green-white, (2) white, and (3) red-white; (c) Photographs of the white LED under different operating voltage
    . Proof-of-concept demonstration of white LED by blending green and red Pe-NCs on a commercial blue LED chip (a) Schematically depicts the packing method of white LED; (b) EL spectra of three typical devices exhibiting (1) green-white, (2) white, and (3) red-white; (c) Photographs of the white LED under different operating voltage
    The stability of white-light LED (a) The luminance stability of white-light LED placed in the air measured at the voltage of 2.7 V; (b) The working stability of the white-light LED after continuous operating for 2 h
    . The stability of white-light LED (a) The luminance stability of white-light LED placed in the air measured at the voltage of 2.7 V; (b) The working stability of the white-light LED after continuous operating for 2 h
    CsPbX3Emission peak/nmFWHM/nmCsPbX3Emission peak/nmFWHM/nm
    CsPbCl341723CsPbIBr255141
    CsPbCl2.14Br0.8643023CsPbI2Br60547
    CsPbCl2Br44727CsPbI2.14Br0.8664246
    CsPbClBr248338CsPbI368040
    CsPbBr353233
    Table 1. Comprehensive comparisons for the representative perovskite NCs
    SampleSynthetic methodsFWHM/nmColor/nmRef.
    CsPbX3(X=Cl, Br, I)All-solid-state ball milling23-47417-680This work
    CsPbX3(X=Cl, Br, I)Supersaturated recrystallization12-39400-650[1]
    CsPbX3(CsPb(Br/Cl)3 -CsPbI3)Droplet-based microfluidic platform20-45470-690[2]
    CsPbX3(X=Cl, Br, I)Fast Anion-Exchange12-40410-700[3]
    Table 2. Comparison of FWHM of CsPbX3 with typical solution synthesis
    Yu-Hui DONG, Shu-Yu ZENG, Bo-Ning HAN, Jie XUE, Ji-Zhong SONG, Hai-Bo ZENG, [in Chinese], [in Chinese], [in Chinese], [in Chinese], [in Chinese], [in Chinese]. BN/CsPbX3 Composite Nanocrystals: Synthesis and Applications in White LED[J]. Journal of Inorganic Materials, 2019, 34(1): 72
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