The research group prepared the high-performance slag nanocrystal glass ceramics by utilizing the valuable elements of the wastes in the Chinese Bayan Obo which are characterized by their symbiotic or associated existence.In this paper,inductively coupled plasma emission spectroscopy (ICP),X-ray diffraction (XRD),Raman spectroscopy (Raman) and scanning electron microscopy (SEM) are all used in the depth analysis for the composition and structure of the samples.The experiment results of ICP,XRD and SEM showed that the principal crystalline phase of the slag nanocrystal glass ceramics containing rare earth elements is diopside,its grain size ranges from 45 to 100 nm,the elements showed in the SEM scan are basically in consistent with the component　analysis of ICP.Raman analysis indicated that its amorphous phase is a three-dimensional network structure composed by the　structural unit　of　silicon-oxy tetrahedron with different non-bridging oxygen bonds.According to the further analysis,we found that the rare earth microelement has significant effect on the network structure.Compared the nanocrystal slag glass ceramic with the glass ceramics of similar ingredients,we found that generally,the Raman band wavenumber for the former is lower than the later.The composition difference between the glass ceramics and the slag nanocrystal with the similar ingredients mainly lies on the rare earth elements and other trace elements.Therefore,we think that the rare earth elements and other trace elements remains in the slag nanocrystal glass ceramics have a significant effect on the network structure of amorphous phase.The research method　of this study provides an approach for the relationship among the composition,structure and performance of the glass ceramics.