• Journal of Inorganic Materials
  • Vol. 39, Issue 12, 1357 (2024)
Xiaoyang GUO1, Xiaolin ZHANG1, Yan JIANG1,*, Yuan TIAN1, and Zhi GENG2
Author Affiliations
  • 11. Key Laboratory of Special Functional Materials Synthesis and Preparation in Liaoning Province, Shenyang University of Chemical Technology, Shenyang 110142, China
  • 22. Shenyang Xinruite Electromechanical Equipment Co. Ltd., Shenyang 110015, China
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    DOI: 10.15541/jim20240249 Cite this Article
    Xiaoyang GUO, Xiaolin ZHANG, Yan JIANG, Yuan TIAN, Zhi GENG. Ti-doped Hf(Zr)B2-SiC Anti-ablation Coatings: Preparation and Ablation Resistance Mechanism [J]. Journal of Inorganic Materials, 2024, 39(12): 1357 Copy Citation Text show less
    Preparation process of the coating sample
    1. Preparation process of the coating sample
    XRD pattern, surface and cross-sectional microstructures and EDS element analysis of HfTiB2-SiC coating after plasma flame ablation for 150 s
    S1. XRD pattern, surface and cross-sectional microstructures and EDS element analysis of HfTiB2-SiC coating after plasma flame ablation for 150 s
    XRD pattern, surface and cross-sectional microstructures, and EDS element analysis of HfTiB2-SiC coating
    2. XRD pattern, surface and cross-sectional microstructures, and EDS element analysis of HfTiB2-SiC coating
    XRD pattern, surface and cross-sectional microstructures, and EDS element analysis of ZrTiB2-SiC coating
    3. XRD pattern, surface and cross-sectional microstructures, and EDS element analysis of ZrTiB2-SiC coating
    XRD pattern, surface and cross-sectional microstructures, and element distribution of HfTiB2-SiC coating sample after ablation for 480 s
    4. XRD pattern, surface and cross-sectional microstructures, and element distribution of HfTiB2-SiC coating sample after ablation for 480 s
    XRD pattern, microstructures and element distributions of the ablation center surface and cross-sectional of ZrTiB2-SiC coating sample after ablation for 480 s
    5. XRD pattern, microstructures and element distributions of the ablation center surface and cross-sectional of ZrTiB2-SiC coating sample after ablation for 480 s
    Gibbs free energy variation curves with temperature for the reaction occurring during coating ablation process
    6. Gibbs free energy variation curves with temperature for the reaction occurring during coating ablation process
    Temperature dependent curves of vapor pressure (a) and decomposition pressure (b) for the oxidation products during coating ablation process
    7. Temperature dependent curves of vapor pressure (a) and decomposition pressure (b) for the oxidation products during coating ablation process
    Schematic diagram of composite coating ablation process
    8. Schematic diagram of composite coating ablation process
    ElementSpot 1/%
    B30.42
    C59.20
    Si0.66
    Ti2.00
    Hf7.72
    Table 1. Element atomic fraction of Spot 1 in Fig. 2(c)
    ElementSpot 1/%
    B57.66
    C30.13
    Si0
    Ti2.87
    Zr9.35
    Table 2. Element atomic fraction of Spot 1 in Fig. 3(c)
    ElementSpot 1/%Spot 2/%Spot 3/%
    O64.1564.4260.46
    Si3.7033.0416.30
    Ti0.240.550.37
    Hf31.911.9922.87
    Table 3. Eelement atomic fraction of Spots 1-3 in Fig. 4(c)
    ElementSpot 1/%Spot 2/%Spot 3/%
    O64.2072.8657.10
    Si1.7513.1429.01
    Ti2.692.565.31
    Zr31.3611.448.58
    Table 4. Element atomic fraction of Spots 1-3 in Fig. 5(d)
    ElementSpot 4/%Spot 6/%
    C17.3812.51
    O42.3859.93
    Si0.5920.94
    Ti2.384.75
    Zr37.271.86
    Table 5. Element atomic fraction of Spots 4 and 6 in Fig. 5(g)
    Xiaoyang GUO, Xiaolin ZHANG, Yan JIANG, Yuan TIAN, Zhi GENG. Ti-doped Hf(Zr)B2-SiC Anti-ablation Coatings: Preparation and Ablation Resistance Mechanism [J]. Journal of Inorganic Materials, 2024, 39(12): 1357
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